We report results of our study of a newly synthesized honeycomb iridate NaxIrO3 (0.60 < x < 0.80). Single-crystal NaxIrO3 adopts a honeycomb lattice noticeably without distortions and stacking disorder inherently existent in its sister compound Na2Ir
O3. The oxidation state of the Ir ion is a mixed valence state resulting from a majority Ir5+(5d4) ion and a minority Ir6+(5d3) ion. NaxIrO3 is a Mott insulator likely with a predominant pseudospin = 1 state. It exhibits an effective moment of 1.1 Bohr Magneton/Ir and a Curie-Weiss temperature of -19 K but with no discernable long-range order above 1 K. The physical behavior below 1 K features two prominent anomalies at Th = 0.9 K and Tl = 0.12 K in both the heat capacity and AC magnetic susceptibility. Intermediate between Th and Tl lies a pronounced temperature linearity of the heat capacity with a large slope of 77 mJ/mole K2, a feature expected for highly correlated metals but not at all for insulators. These results along with comparison drawn with the honeycomb lattices Na2IrO3 and (Na0.2Li0.8)2IrO3 point to an exotic ground state in a proximity to a possible Kitaev spin liquid.
We propose a traveling wave scheme for broadband microwave isolation using parametric mode conversion in conjunction with adiabatic phase matching technique in a pair of coupled nonlinear transmission lines. This scheme is compatible with the circuit
quantum electrodynamics architecture (cQED) and provides isolation without introducing additional quantum noise. We first present the scheme in a general setting then propose an implementation with Josephson junction transmission lines. Numerical simulation shows more than 20 dB isolation over an octave bandwidth (4-8,GHz) in a 2000 unit cell device with less than 0.05 dB insertion loss dominated by dielectric loss.
With the rapid development of Green Communication Network, the types and quantity of network traffic data are accordingly increasing. Network traffic classification become a non-trivial research task in the area of network management and security, wh
ich not only help to improve the fine-grained network resource allocation, but also enable policy-driven network management. Meanwhile, the combination of SDN and Edge Computing can leverage both SDN at its global visiability of network-wide and Edge Computing at its low latency and good privacy-preserving. However, capturing large labeled datasets is a cumbersome and time-consuming manual labor. Semi-Supervised learning is an appropriate technique to overcome this problem. With that in mind, we proposed a Generative Adversarial Network (GAN)-based Semi-Supervised Learning Encrypted Traffic Classification method called emph{ByteSGAN} embedded in SDN Edge Gateway to achieve the goal of traffic classification in a fine-grained manner to further improve network resource utilization. ByteSGAN can only use a small number of labeled traffic samples and a large number of unlabeled samples to achieve a good performance of traffic classification by modifying the structure and loss function of the regular GAN discriminator network in a semi-supervised learning way. Based on public dataset ISCX2012 VPN-nonVPN, two experimental results show that the ByteSGAN can efficiently improve the performance of traffic classifier and outperform the other supervised learning method like CNN.
Single crystal neutron diffraction, inelastic neutron scattering, bulk magnetization measurements, and first-principles calculations are used to investigate the magnetic properties of the honeycomb lattice $rm Tb_2Ir_3Ga_9$. While the $Rln2$ magnetic
contribution to the low-temperature entropy indicates a $rm J_{eff}=1/2$ moment for the lowest-energy crystal-field doublet, the Tb$^{3+}$ ions form a canted antiferromagnetic structure below 12.5 K. Due to the Dzyalloshinskii-Moriya interactions, the Tb moments in the $ab$ plane are slightly canted towards $b$ by $6^circ$ with a canted moment of 1.22 $mu_{rm B} $ per formula unit. A minimal $xxz$ spin Hamiltonian is used to simultaneously fit the spin-wave frequencies along the high symmetry directions and the field dependence of the magnetization along the three crystallographic axes. Long-range magnetic interactions for both in-plane and out-of-plane couplings up to the second nearest neighbors are needed to account for the observed static and dynamic properties. The $z$ component of the exchange interactions between Tb moments are larger than the $x$ and $y$ components. This compound also exhibits bond-dependent exchange with negligible nearest exchange coupling between moments parallel and perpendicular to the 4$f$ orbitals. Despite the $J_{{rm eff}}=1/2$ moments, the spin Hamiltonian is denominated by a large in-plane anisotropy $K_z sim -1$ meV. DFT calculations confirm the antiferromagnetic ground state and the substantial inter-plane coupling at larger Tb-Tb distances.
Strong nonlinear coupling of superconducting qubits and/or photons is a critical building block for quantum information processing. Due to the perturbative nature of the Josephson nonlinearity, linear coupling is often used in the dispersive regime t
o approximate nonlinear coupling. However, this dispersive coupling is weak and the underlying linear coupling mixes the local modes which, for example, distributes unwanted self-Kerr to photon modes. Here, we use the quarton to yield purely nonlinear coupling between two linearly decoupled transmon qubits. The quartons zero $phi^2$ potential enables a giant gigahertz-level cross-Kerr which is an order of magnitude stronger compared to existing schemes, and the quartons positive $phi^4$ potential can cancel the negative self-Kerr of qubits to linearize them into resonators. This giant cross-Kerr between bare modes of qubit-qubit, qubit-photon, and even photon-photon is ideal for applications such as single microwave photon detection and implementation of bosonic codes.
$rm Sr_2IrO_4$ is an archetypal spin-orbit-coupled Mott insulator and has been extensively studied in part because of a wide range of predicted novel states. Limited experimental characterization of these states thus far brings to light the extraordi
nary susceptibility of the physical properties to the lattice, particularly, the Ir-O-Ir bond angle. Here, we report a newly observed microscopic rotation of the IrO$_6$ octahedra below 50~K measured by single crystal neutron diffraction. This sharp lattice anomaly provides keys to understanding the anomalous low-temperature physics and a direct confirmation of a crucial role that the Ir-O-Ir bond angle plays in determining the ground state. Indeed, as also demonstrated in this study, applied electric current readily weakens the antiferromagnetic order via the straightening of the Ir-O-Ir bond angle, highlighting that even slight change in the local structure can disproportionately affect the physical properties in the spin-orbit-coupled system.
Simultaneous control of structural and physical properties via applied electrical current poses a key, new research topic and technological significance. Studying the spin-orbit-coupled antiferromagnet Ca2RuO4, with 3% Mn doping to weaken the violent
first-order transition at 357 K for more robust measurements, we find that a small applied electrical current couples to the lattice by significantly reducing its orthorhombicity and octahedral rotations, concurrently diminishing the 125 K- antiferromagnetic transition and inducing a new, orbital order below 80 K. Our effort to establish a phase diagram reveals a critical regime near a current density of 0.15 A/cm2 that separates the vanishing antiferromagnetic order and the new orbital order. Further increasing current density (> 1 A/cm2) enhances competitions between relevant interactions in a metastable manner, leading to a peculiar glassy behavior above 80 K. The coupling between the lattice and nonequilibrium driven current is interpreted theoretically in terms of t2g orbital occupancies. The current-controlled lattice is the driving force of the observed novel phenomena.
We have synthesized and studied a new iridate, Ba13Ir6O30, with unusual Ir oxidation states: 2/3 Ir6+(5d3) ions and 1/3 Ir5+(5d4) ions. Its crystal structure features dimers of face-sharing IrO6 octahedra, and IrO6 monomers, that are linked via long,
zigzag Ir-O-Ba-O-Ir pathways. Nevertheless, Ba13Ir6O30 exhibits two transitions at TN1 = 4.7 K and TN2 = 1.6 K. This magnetic order is accompanied by a huge Sommerfeld coefficient 200 mJ/mole K below TN2, signaling a coexisting frustrated/disordered state persisting down to at least 0.05 K. This iridate hosts unusually large Jeff=3/2 degrees of freedom, which is enabled by strong spin-orbit interactions (SOI) in the monomers with Ir6+ ions and a joint effect of molecular orbitals and SOI in the dimers occupied by Ir5+ and Ir6+ ions. Features displayed by the magnetization and heat capacity suggest that the combination of covalency, SOI and large effective spins leads to highly frustrated ferrimagnetic ordering, possibly into a skyrmion crystal, a novelty of this new high-spin iridate.
The dimensionality of the electronic and magnetic structure of a given material is generally predetermined by its crystal structure. Here, using elastic and inelastic neutron scattering combined with magnetization measurements, we find unusual magnet
ic behavior in three-dimensional (3D) Ba2CoO4. In spite of isolated CoO4 tetrahedra, the system exhibits a 3D noncollinear antiferromagnetic order in the ground state with an anomalously large Curie-Weiss temperature of 110 K compared to TN = 26 K. More unexpectedly, spin dynamics displays quasi-2D spin wave dispersion with an unusually large spin gap, and 1D magnetoelastic coupling. Our results indicate that Ba2CoO4 is a unique system for exploring the interplay between isolated polyhedra, low-dimensional magnetism, and novel spin states in oxides.
We used single-crystal x-ray and neutron diffraction to investigate the crystal and magnetic structures of trigonal lattice iridate Ca2Sr2IrO6. The crystal structure is determined to be $Rbar3$ with two distinct Ir sites. The system exhibits long-ran
ge antiferromagnetic order below $T_N = 13.1$ K. The magnetic wave vector is identified as $(0,0.5,1)$ with ferromagnetic coupling along the $a$ axis and antiferromagnetic correlation along the $b$ axis. Spins align dominantly within the basal plane along the [1,2,0] direction and tilt 34$^circ$ towards the $c$ axis. The ordered moment is 0.66(3) $mu_B$/Ir, larger than other iridates where iridium ions form corner- or edge-sharing $rm IrO_6$ octahedral networks. The tilting angle is reduced to $approx19^circ$ when a magnetic field of 4.9 Tesla is applied along the $c$ axis. Density functional theory calculations confirm that the experimentally determined magnetic configuration is the most probable ground state with an insulating gap $sim0.5$~eV.
