We revealed novel phase deagram of Fe-pnictide high-Tc superconductor LaFe(As_{1-x}P_{x})O in wide doping level (0.3<x<1) by P-NMR. Systematic 31P-NMR studies revealed the emergence of the antiferromagnetic ordered phase (AFM-2) in 0.4 < x < 0.7 that
intervenes between two superconductivity (SC-1/SC-2) phases. The 31P-NMR Knight shift points to the appearance of the sharp density of states at the Fermi level that is derived from d_{3Z^2?r^2} orbit, which is less relevant with the onset of the SC-2. On the other hand, we remark that the AFM spin fluctuations arising from the interband nesting on the d_{XZ}/d_{YZ} orbits must be a key ingredient for the occurrence of SC around AFM-2.
Systematic P-NMR studies on LaFe(As_{1-x}P_x)(O_{1-y}F_y) with y=0.05 and 0.1 have revealed that the antiferromagnetic spin fluctuations (AFMSFs) at low energies are markedly enhanced around x=0.6 and 0.4, respectively, and as a result, Tc exhibits r
espective peaks at 24 K and 27 K against the P-substitution for As. This result demonstrates that the AFMSFs are responsible for the increase in Tc for LaFe(As_{1-x}P_x)(O_{1-y}F_y) as a primary mediator of the Cooper pairing. From a systematic comparison of AFMSFs with a series of (La_{1-z}Y_z)FeAsO_{delta} compounds in which Tc reaches 50 K for z=0.95, we remark that a moderate development of AFMSFs causes the Tc to increase up to 50 K under the condition that the local lattice parameters of FeAs tetrahedron approaches those of the regular tetrahedron. We propose that the T_c of Fe-pnictides exceeding 50 K is maximized under an intimate collaboration of the AFMSFs and other factors originating from the optimization of the local structure.
