Context. Tens of light hydrides and small molecules have now been detected over several hundreds sight lines sampling the diffuse interstellar medium (ISM) in both the Solar neighbourhood and the inner Galactic disk. They provide unprecedented statis
tics on the first steps of chemistry in the diffuse gas. Aims. These new data confirm the limitations of the traditional chemical pathways driven by the UV photons and the cosmic rays (CR) and the need for additional energy sources, such as turbulent dissipation, to open highly endoenergetic formation routes. The goal of the present paper is to further investigate the link between specific species and the properties of the turbulent cascade in particular its space-time intermittency. Methods. We have analysed ten different atomic and molecular species in the framework of the updated model of turbulent dissipation regions (TDR). We study the influence on the abundances of these species of parameters specific to chemistry (density, UV field, and CR ionisation rate) and those linked to turbulence (the average turbulent dissipation rate, the dissipation timescale, and the ion neutral velocity drift in the regions of dissipation). Results. The most sensitive tracers of turbulent dissipation are the abundances of CH+ and SH+, and the column densities of the J = 3, 4, 5 rotational levels of H2 . The abundances of CO, HCO+, and the intensity of the 158 $mu$m [CII] emission line are significantly enhanced by turbulent dissipation. The vast diversity of chemical pathways allows the independent determinations of free parameters never estimated before: an upper limit to the average turbulent dissipation rate, $overline{varepsilon}$ < 10$^{-23}$ erg cm$^{-3}$ s$^{-1}$ for $n_H$=20 cm$^{-3}$, from the CH+ abundance; an upper limit to the ion-neutral velocity drift, $u_{in}$ < 3.5 km s$^{-1}$, from the SH+ to CH+ abundance ratio; and a range of dissipation timescales, 100 < $tau_V$ < 1000 yr, from the CO to HCO+ abundance ratio. For the first time, we reproduce the large abundances of CO observed on diffuse lines of sight, and we show that CO may be abundant even in regions with UV-shieldings as low as $5 times 10^{-3}$ mag. The best range of parameters also reproduces the abundance ratios of OH, C2H, and H2O to HCO+ and are consistent with the known properties of the turbulent cascade in the Galactic diffuse ISM. Conclusions. Our results disclose an unexpected link between the dissipation of turbulence and the emergence of molecular richness in the diffuse ISM. Some species, such as CH+ or SH+, turn out to be unique tracers of the energy trail in the ISM. In spite of some degeneracy, the properties of the turbulent cascade, down to dissipation, can be captured through specific molecular abundances.
Aims. The comparative study of several molecular species at the origin of the gas phase chemistry in the diffuse interstellar medium (ISM) is a key input in unraveling the coupled chemical and dynamical evolution of the ISM. Methods. The lowest rotat
ional lines of HCO+, HCN, HNC, and CN were observed at the IRAM-30m telescope in absorption against the lambda 3 mm and lambda 1.3 mm continuum emission of massive star-forming regions in the Galactic plane. The absorption lines probe the gas over kiloparsecs along these lines of sight. The excitation temperatures of HCO+ are inferred from the comparison of the absorptions in the two lowest transitions. The spectra of all molecular species on the same line of sight are decomposed into Gaussian velocity components. Most appear in all the spectra of a given line of sight. For each component, we derived the central opacity, the velocity dispersion, and computed the molecular column density. We compared our results to the predictions of UV-dominated chemical models of photodissociation regions (PDR models) and to those of non-equilibrium models in which the chemistry is driven by the dissipation of turbulent energy (TDR models). Results. The molecular column densities of all the velocity components span up to two orders of magnitude. Those of CN, HCN, and HNC are linearly correlated with each other with mean ratios N(HCN)/N(HNC) = 4.8 $pm$ 1.3 and N(CN)/N(HNC) = 34 $pm$ 12, and more loosely correlated with those of HCO+, N(HNC)/N(HCO+) = 0.5 $pm$ 0.3, N(HCN)/N(HCO+) = 1.9 $pm$ 0.9, and N(CN)/N(HCO+) = 18 $pm$ 9. These ratios are similar to those inferred from observations of high Galactic latitude lines of sight, suggesting that the gas sampled by absorption lines in the Galactic plane has the same chemical properties as that in the Solar neighbourhood. The FWHM of the Gaussian velocity components span the range 0.3 to 3 km s-1 and those of the HCO+ lines are found to be 30% broader than those of CN-bearing molecules. The PDR models fail to reproduce simultaneously the observed abundances of the CN-bearing species and HCO+, even for high-density material (100 cm-3 < nH < 104 cm-3). The TDR models, in turn, are able to reproduce the observed abundances and abundance ratios of all the analysed molecules for the moderate gas densities (30 cm-3 < nH < 200 cm-3) and the turbulent energy observed in the diffuse interstellar medium. Conclusions. Intermittent turbulent dissipation appears to be a promising driver of the gas phase chemistry of the diffuse and translucent gas throughout the Galaxy. The details of the dissipation mechanisms still need to be investigated.
Guided by the duality of turbulence (random versus coherent we seek coherent structures in the turbulent velocity field of molecular clouds, anticipating their importance in cloud evolution. We analyse a large map (40 by 20) obtained with the HERA mu
ltibeam receiver (IRAM-30m telescope) in a high latitude cloud of the Polaris Flare at an unprecedented spatial (11) and spectral (0.05 km/s) resolutions in the 12CO(2-1) line. We find that two parsec-scale components of velocities differing by ~2 km/s, share a narrow interface ($<0.15$ pc) that appears as an elongated structure of intense velocity-shear, ~15 to 30 km/s/pc. The locus of the extrema of line--centroid-velocity increments (E-CVI) in that field follows this intense-shear structure as well as that of the 12CO(2-1) high-velocity line wings. The tiny spatial overlap in projection of the two parsec-scale components implies that they are sheets of CO emission and that discontinuities in the gas properties (CO enrichment and/or increase of gas density) occur at the position of the intense velocity shear. These results disclose spatial and kinematic coherence between scales as small as 0.03 pc and parsec scales. They confirm that the departure from Gaussianity of the probability density functions of E-CVIs is a powerful statistical tracer of the intermittency of turbulence. They disclose a link between large scale turbulence, its intermittent dissipation rate and low-mass dense core formation.
Supersonic turbulence is a large reservoir of suprathermal energy in the interstellar medium. Its dissipation, because it is intermittent in space and time, can deeply modify the chemistry of the gas. We further explore a hybrid method to compute the
chemical and thermal evolution of a magnetized dissipative structure, under the energetic constraints provided by the observed properties of turbulence in the cold neutral medium. For the first time, we model a random line of sight by taking into account the relative duration of the bursts with respect to the thermal and chemical relaxation timescales of the gas. The key parameter is the turbulent rate of strain a due to the ambient turbulence. With the gas density, it controls the size of the dissipative structures, therefore the strength of the burst. For a large range of rates of strain and densities, the models of turbulent dissipation regions (TDR) reproduce the CH+ column densities observed in the diffuse medium and their correlation with highly excited H2. They do so without producing an excess of CH. As a natural consequence, they reproduce the abundance ratios of HCO+/OH and HCO+/H2O, and their dynamic range of about one order of magnitude observed in diffuse gas. Large C2H and CO abundances, also related to those of HCO+, are another outcome of the TDR models that compare well with observed values. The abundances and column densities computed for CN, HCN and HNC are one order of magnitude above PDR model predictions, although still significantly smaller than observed values.
We further characterize the structures tentatively identified on thermal and chemical grounds as the sites of dissipation of turbulence in molecular clouds (Papers I and II). Our study is based on two-point statistics of line centroid velocities (CV)
, computed from three large 12CO maps of two fields. Probability density functions (PDF) of the CO line centroid velocity increments (CVI) over lags varying by an order of magnitude and structure functions of the line CV, up to the 6th order, are computed. We show that the line CV bear the three signatures of intermittency in a turbulent velocity field: (1) the non-Gaussian tails in the CVI PDF grow as the lag decreases, (2) the departure from Kolmogorov scaling of the high-order structure functions is more pronounced in the more turbulent field, (3) the positions contributing to the CVI PDF tails delineate narrow filamentary structures (thickness ~ 0.02 pc), uncorrelated to dense gas structures and spatially coherent with thicker ones (~0.18 pc) observed on larger scales. The confrontation with theoretical predictions leads us to identify these small-scale filamentary structures with extrema of velocity-shears associated with gas warmer than the bulk. Last, their average direction is parallel (or close) to that of the local magnetic field projection. Turbulence in these translucent fields exhibits the statistical and structural signatures of small-scale and inertial-range intermittency. The more turbulent field on the 30 pc-scale is also the more intermittent on small scales. The small-scale intermittent structures coincide with those formerly identified as sites of enhanced dissipation. They are organized into parsec-scale coherent structures, coupling a broad range of scales.
