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Supersonic turbulence is a large reservoir of suprathermal energy in the interstellar medium. Its dissipation, because it is intermittent in space and time, can deeply modify the chemistry of the gas. We further explore a hybrid method to compute the chemical and thermal evolution of a magnetized dissipative structure, under the energetic constraints provided by the observed properties of turbulence in the cold neutral medium. For the first time, we model a random line of sight by taking into account the relative duration of the bursts with respect to the thermal and chemical relaxation timescales of the gas. The key parameter is the turbulent rate of strain a due to the ambient turbulence. With the gas density, it controls the size of the dissipative structures, therefore the strength of the burst. For a large range of rates of strain and densities, the models of turbulent dissipation regions (TDR) reproduce the CH+ column densities observed in the diffuse medium and their correlation with highly excited H2. They do so without producing an excess of CH. As a natural consequence, they reproduce the abundance ratios of HCO+/OH and HCO+/H2O, and their dynamic range of about one order of magnitude observed in diffuse gas. Large C2H and CO abundances, also related to those of HCO+, are another outcome of the TDR models that compare well with observed values. The abundances and column densities computed for CN, HCN and HNC are one order of magnitude above PDR model predictions, although still significantly smaller than observed values.
Whether ice in cold cosmic environments is physically separated from the silicate dust or mixed with individual silicate moieties is not known. However, different grain models give very different compositions and temperatures of grains. The aim of th
Context: The interstellar medium (ISM) on all scales is full of structures that can be used as tracers of processes that feed turbulence. Aims: We used HI survey data to derive global properties of the angular power distribution of the local ISM. Met
Emission of fullerenes in their infrared vibrational bands has been detected in space near hot stars. The proposed attribution of the diffuse interstellar bands at 9577 and 9632 AA to electronic transitions of the buckminsterfullerene cation (i.e. C$
With the use of the data from archives, we studied the correlations between the equivalent widths of four diffuse interstellar bands (4430$r{A}$, 5780$r{A}$, 5797$r{A}$, 6284$r{A}$) and properties of the target stars (colour excess values, distances
Grain growth by accretion of gas-phase metals is a common assumption in models of dust evolution, but in dense gas, where the timescale is short enough for accretion to be effective, material is accreted in the form of ice mantles rather than adding