A new solar fluorine abundance and a fluorine determination in the two open clusters M 67 and NGC 6404

We present a new determination of the solar fluorine abundance together with abundance measurements of fluorine in two Galactic open clusters. We analyzed a sunspot spectrum, observed by L. Wallace and W. Livingston with the FTS at the McMath/Pierce Solar Telescope situated on Kitt Peak and spectra of four giants in the old cluster M 67 ($sim$4.5 Gyr) and three giants in the young cluster NGC 6404 ($sim$0.5 Gyr), obtained with the CRIRES spectrograph at VLT. Fluorine was measured through synthesis of the available HF lines. We adopted the recent set of experimental molecular parameters of HF delivered by the HITRAN database, and found a new solar fluorine abundance of $A(F) = 4.40pm 0.25$, in good agreement with the M 67 average fluorine abundance of $A(F) = 4.49pm 0.20$. The new solar abundance is in a very good agreement with the meteoritic value. The used modern spectrosynthesis tools, the agreement with the meteoritic value and with the results in open cluster M67, known to be a solar analogue, make our solar determination very robust. At the same time, the fluorine measurement in the above-mentioned open clusters is the first step in the understanding of its evolution during the last $sim$10 Gyr in the Galactic disk. In order to develop this project, a larger sample of open clusters is required, so that it would allow us to trace the evolution of fluorine as a function of time and, in turn, to better understand its origin.

AGB stars and presolar grains

Among presolar materials recovered in meteorites, abundant SiC and Al$_{2}$O$_{3}$ grains of AGB origins were found. They showed records of C, N, O, $^{26}$Al and s-element isotopic ratios that proved invaluable in constraining the nucleosynthesis models for AGB stars cite{zin,gal}. In particular, when these ratios are measured in SiC grains, they clearly reveal their prevalent origin in cool AGB circumstellar envelopes and provide information on both the local physics and the conditions at the nucleosynthesis site (the H- and He-burning layers deep inside the structure). Among the properties ascertained for the main part of the SiC data (the so-called {it mainstream} ones), we mention a large range of $^{14}$N/$^{15}$N ratios, extending below the solar value cite{mar}, and $^{12}$C/$^{13}$C ratios $gtrsim$ 30. Other classes of grains, instead, display low carbon isotopic ratios ($gtrsim 10$) and a huge dispersion for N isotopes, with cases of large $^{15}$N excess. In the same grains, isotopes currently feeded by slow neutron captures reveal the characteristic pattern expected from this process at an efficiency slightly lower than necessary to explain the solar main s-process component. Complementary constraints can be found in oxide grains, especially Al$_{2}$O$_{3}$ crystals. Here, the oxygen isotopes and the content in $^{26}$Al are of a special importance for clarifying the partial mixing processes that are known to affect evolved low-mass stars. Successes in modeling the data, as well as problems in explaining some of the mentioned isotopic ratios through current nucleosynthesis models are briefly outlined.

s-Processing in the Galactic Disk. I. Super-Solar Abundances of Y, Zr, La, Ce in Young Open Clusters

In a recent study, based on homogeneous barium abundance measurements in open clusters, a trend of increasing [Ba/Fe] ratios for decreasing cluster age was reported. We present here further abundance determinations, relative to four other elements hav- ing important s-process contributions, with the aim of investigating whether the growth found for [Ba/Fe] is or not indicative of a general property, shared also by the other heavy elements formed by slow neutron captures. In particular, we derived abundances for yttrium, zirconium, lanthanum and cerium, using equivalent widths measurements and the MOOG code. Our sample includes 19 open clusters of different ages, for which the spectra were obtained at the ESO VLT telescope, using the UVES spectrometer. The growth previously suggested for Ba is confirmed for all the elements analyzed in our study. This fact implies significant changes in our views of the Galactic chemical evolution for elements beyond iron. Our results necessarily require that very low-mass AGB stars (M < 1.5Modot) produce larger amounts of s-process elements (hence acti- vate the 13 C-neutron source more effectively) than previously expected. Their role in producing neutron-rich elements in the Galactic disk has been so far underestimated and their evolution and neutron-capture nucleosynthesis should now be reconsidered.

News from Low Mass Star Nucleosynthesis and Mixing

Light and intermediate nuclei as well as s-process elements have been detected in presolar grains and in evolved red giants. The abundances of some of these nuclei cannot be accounted for by canonical stellar models and require non-convective mixing below the envelope, occurring during the phases of the Red Giant Branch (RGB) and of the Asymptotic Giant Branch (AGB). Similar mechanisms appear to be necessary to account for the formation of the neutron source driving s processing. We present a short review of these phenomena and we comment on the picture that emerges from the set of available data on the evolution and nucleosynthesis in low mass stars. Our conclusions include: i) the need for deep mixing in both RGB and AGB stars; ii) the suggestion that these phenomena occur at a non-negligible velocity, possibly incompatible with diffusive processes; iii) the verification that the abundances of neutron-rich nuclei are presently increasing in the Galaxy, contrary to previous expectations and hence that the s process has new surprises to offer us; iv) the recognition of the growing importance of very low mass stars for Galactic nucleosynthesis.

On the Need for Deep Mixing in AGB Stars of Low Mass

The photospheres of low-mass red giants show CNO isotopic abundances that are not satisfactorily accounted for by canonical stellar models. The same is true for the measurements of these isotopes and of the $^{26}$Al/$^{27}$Al ratio in presolar grains of circumstellar origin. Non-convective mixing, occurring during both Red Giant Branch (RGB) and Asymptotic Giant Branch (AGB) stages is the explanation commonly invoked to account for the above evidence. Recently, the need for such mixing phenomena on the AGB was questioned, and chemical anomalies usually attributed to them were suggested to be formed in earlier phases. We have therefore re-calculated extra-mixing effects in low mass stars for both the RGB and AGB stages, in order to verify the above claims. Our results contradict them; we actually confirm that slow transport below the convective envelope occurs also on the AGB. This is required primarily by the oxygen isotopic mix and the $^{26}$Al content of presolar oxide grains. Other pieces of evidence exist, in particular from the isotopic ratios of carbon stars of type N, or C(N), in the Galaxy and in the LMC, as well as of SiC grains of AGB origin. We further show that, when extra-mixing occurs in the RGB phases of population I stars above about 1.2 $M_{odot}$, this consumes $^3$He in the envelope, probably preventing the occurrence of thermohaline diffusion on the AGB. Therefore, we argue that other extra-mixing mechanisms should be active in those final evolutionary phases.

The solar photospheric nitrogen abundance. Analysis of atomic transitions with 3D and 1D model atmospheres

CONTEXT: In recent years, the solar chemical abundances have been studied in considerable detail because of discrepant values of solar metallicity inferred from different indicators, i.e., on the one hand, the sub-solar photospheric abundances resulting from spectroscopic chemical composition analyses with the aid of 3D hydrodynamical models of the solar atmosphere, and, on the other hand, the high metallicity inferred by helioseismology. AIMS: After investigating the solar oxygen abundance using a CO5BOLD 3D hydrodynamical solar model in previous work, we undertake a similar approach studying the solar abundance of nitrogen, since this element accounts for a significant fraction of the overall solar metallicity, Z. METHOD: We used a selection of atomic spectral lines to determine the solar nitrogen abundance, relying mainly on equivalent width measurements in the literature. We investigate the influence on the abundance analysis, of both deviations from local thermodynamic equilibrium (NLTE effects) and photospheric inhomogeneities (granulation effects). RESULTS: We recommend use of a solar nitrogen abundance of A(N)=7.86+-0.12 whose error bar reflects the line-to-line scatter. CONCLUSION: The solar metallicity implied by the CO5BOLD-based nitrogen and oxygen abundances is in the range 0.0145<= Z <= 0.0167. This result is a step towards reconciling photospheric abundances with helioseismic constraints on Z. Our most suitable estimates are Z=0.0156 and Z/X=0.0213.