We exploit inverse Raman scattering and solvated electron absorption to perform a quantitative characterization of the energy loss and ionization dynamics in water with tightly focused near-infrared femtosecond pulses. A comparison between experiment
al data and numerical simulations suggests that the ionization energy of water is 8 eV, rather than the commonly used value of 6.5 eV. We also introduce an equation for the Raman gain valid for ultra-short pulses that validates our experimental procedure.
We report measurements that show extreme events in the statistics of resonant radiation emitted from spatiotemporal light bullets. We trace the origin of these extreme events back to instabilities leading to steep gradients in the temporal profile of
the intense light bullet that occur during the initial collapse dynamics. Numerical simulations reproduce the extreme valued statistics of the resonant radiation which are found to be intrinsically linked to the simultaneous occurrence of both temporal and spatial self-focusing dynamics. Small fluctuations in both the input energy and in the spatial phase curvature explain the observed extreme behaviour.
