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We measure the ratio $gamma$ of the momentum-transfer to the vibrational quenching cross section for the X ($^1Sigma^+$), $ u=1$, $mathrm{J=0}$ state of molecular thorium monoxide (ThO) in collisions with atomic $^3$He between 800 mK and 2.4 K. We ob serve indirect evidence for ThO--He van der Waals complex formation, which has been predicted by theory. We determine the 3-body recombination rate constant $Gamma_3$ at 2.4 K, and establish that the binding energy E$_b >$ 4 K.
We measure inelastic collisional cross sections for the ground $^3$F$_2$ state and the excited $^3$P$_0$ state of atomic thorium in cold collisions with $^3$He. We determine for Th ($^3$F$_2$) at 800 mK the ratio $gamma approx 500$ of the momentum-tr ansfer to Zeeman relaxation cross sections for collisions with $^3$He. For Th ($^3$P$_0$), we study electronic inelastic processes and find no quenching even after $10^6$ collisions. We also determine the radiative lifetime of Th ($^3$P$_0$) to be $tau > 130$ ms. This great stability of the metastable state opens up the possibility for further study, including trapping.
Noble gas permeabilities and diffusivities of Kapton, butyl, nylon, and Silver Shield are measured at temperatures between 22C and 115C. The breakthrough times and solubilities at 22C are also determined. The relationship of the room temperature perm eabilities to the noble gas atomic radii is used to estimate radon permeability for each material studied. For the noble gases tested, Kapton and Silver Shield have the lowest permeabilities and diffusivities, followed by nylon and butyl, respectively.
Spin relaxation due to atom-atom collisions is measured for magnetically trapped erbium and thulium atoms at a temperature near 500 mK. The rate constants for Er-Er and Tm-Tm collisions are 3.0 times 10^-10 cm^3 s^-1 and 1.1 times 10^-10 cm^3 s^-1, r espectively, 2-3 orders of magnitude larger than those observed for highly magnetic S-state atoms. This is strong evidence for an additional, dominant, spin relaxation mechanism, electrostatic anisotropy, in collisions between these submerged-shell L > 0 atoms. These large spin relaxation rates imply that evaporative cooling of these atoms in a magnetic trap will be highly inefficient.
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