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Interfacial profiles and interfacial tensions of phase-separated binary mixtures of Bose-Einstein condensates are studied theoretically. The two condensates are characterized by their respective healing lengths $xi_1$ and $xi_2$ and by the inter-spec ies repulsive interaction $K$. An exact solution to the Gross-Pitaevskii (GP) equations is obtained for the special case $xi_2/xi_1 = 1/2$ and $K = 3/2$. Furthermore, applying a double-parabola approximation (DPA) to the energy density featured in GP theory allows us to define a DPA model, which is much simpler to handle than GP theory but nevertheless still captures the main physics. In particular, a compact analytic expression for the interfacial tension is derived that is useful for all $xi_1, xi_2$ and $K$. An application to wetting phenomena is presented for condensates adsorbed at an optical wall. The wetting phase boundary obtained within the DPA model nearly coincides with the exact one in GP theory.
393 - Chang-You Lin , Michael Widom , 2013
We investigate generalized potentials for a mean-field density functional theory of a three-phase contact line. Compared to the symmetrical potential introduced in our previous article [1], the three minima of these potentials form a small triangle l ocated arbitrarily within the Gibbs triangle, which is more realistic for ternary fluid systems. We multiply linear functions that vanish at edges and vertices of the small triangle, yielding potentials in the form of quartic polynomials. We find that a subset of such potentials has simple analytic far-field solutions, and is a linear transformation of our original potential. By scaling, we can relate their solutions to those of our original potential. For special cases, the lengths of the sides of the small triangle are proportional to the corresponding interfacial tensions. For the case of equal interfacial tensions, we calculate a line tension that is proportional to the area of the small triangle.
126 - Chang-You Lin , Michael Widom , 2011
A three-phase contact line in a three-phase fluid system is modeled by a mean-field density functional theory. We use a variational approach to find the Euler-Lagrange equations. Analytic solutions are obtained in the two-phase regions at large dista nces from the contact line. We employ a triangular grid and use a successive over-relaxation method to find numerical solutions in the entire domain for the special case of equal interfacial tensions for the two-phase interfaces. We use the Kerins-Boiteux formula to obtain a line tension associated with the contact line. This line tension turns out to be negative. We associate line adsorption with the change of line tension as the governing potentials change.
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