We investigate the limits of effectiveness of classical spin simulations for predicting free induction decays (FIDs) measured by solid-state nuclear magnetic resonance (NMR) on systems of quantum nuclear spins. The specific limits considered are asso
ciated with the range of interaction, the size of individual quantum spins and the long-time behavior of the FID signals. We compare FIDs measured or computed for lattices of quantum spins (mainly spins 1/2) with the FIDs computed for the corresponding lattices of classical spins. Several cases of excellent quantitative agreement between quantum and classical FIDs are reported along with the cases of gradually decreasing quality of the agreement. We formulate semi-empirical criteria defining the situations, when classical simulations are expected to accurately reproduce quantum FIDs. Our findings indicate that classical simulations may be a quantitatively accurate tool of first principles calculations for a broad class of macroscopic systems, where individual quantum microscopic degrees of freedom are far from the classical limit.
We show that macroscopic nonintegrable lattices of spins 1/2, which are often considered to be chaotic, do not exhibit the basic property of classical chaotic systems, namely, exponential sensitivity to small perturbations. We compare chaotic lattice
s of classical spins and nonintegrable lattices of spins 1/2 in terms of their magnetization responses to imperfect reversal of spin dynamics known as Loschmidt echo. In the classical case, magnetization exhibits exponential sensitivity to small perturbations of Loschmidt echoes, which is characterized by twice the value of the largest Lyapunov exponent of the system. In the case of spins 1/2, magnetization is only power-law sensitive to small perturbations. Our findings imply that it is impossible to define Lyapunov exponents for lattices of spins 1/2 even in the macroscopic limit. At the same time, the above absence of exponential sensitivity to small perturbations is an encouraging news for the efforts to create quantum simulators. The power-law sensitivity of spin 1/2 lattices to small perturbations is predicted to be measurable in nuclear magnetic resonance experiments.
We consider multiple collisions of quantum wave packets in one dimension. The system under investigation consists of an impenetrable wall and of two hard-core particles with very different masses. The lighter particle bounces between the heavier one
and the wall. Both particles are initially represented by narrow Gaussian wave packets. A complete analytical solution of this problem is presented on the basis of a new method. The idea of the method is to decompose the two-particle wave function into a continuous superposition of terms (channels), such that the multiple collisions within each channel do not lead to subsequent entanglement between the two particles. For each channel, the time evolution of the two-particle wave function is completely determined by the motion of the corresponding classical point-like particles; therefore the whole quantum problem is reduced to a classical calculation. The calculation based on the above method reveals the following unexpected result: The entanglement between the two particles first increases with time due to the collisions, but then it begins to decrease, disappearing completely when the light particle becomes too slow to catch up with the heavy one.
