Context. Tens of light hydrides and small molecules have now been detected over several hundreds sight lines sampling the diffuse interstellar medium (ISM) in both the Solar neighbourhood and the inner Galactic disk. They provide unprecedented statis
tics on the first steps of chemistry in the diffuse gas. Aims. These new data confirm the limitations of the traditional chemical pathways driven by the UV photons and the cosmic rays (CR) and the need for additional energy sources, such as turbulent dissipation, to open highly endoenergetic formation routes. The goal of the present paper is to further investigate the link between specific species and the properties of the turbulent cascade in particular its space-time intermittency. Methods. We have analysed ten different atomic and molecular species in the framework of the updated model of turbulent dissipation regions (TDR). We study the influence on the abundances of these species of parameters specific to chemistry (density, UV field, and CR ionisation rate) and those linked to turbulence (the average turbulent dissipation rate, the dissipation timescale, and the ion neutral velocity drift in the regions of dissipation). Results. The most sensitive tracers of turbulent dissipation are the abundances of CH+ and SH+, and the column densities of the J = 3, 4, 5 rotational levels of H2 . The abundances of CO, HCO+, and the intensity of the 158 $mu$m [CII] emission line are significantly enhanced by turbulent dissipation. The vast diversity of chemical pathways allows the independent determinations of free parameters never estimated before: an upper limit to the average turbulent dissipation rate, $overline{varepsilon}$ < 10$^{-23}$ erg cm$^{-3}$ s$^{-1}$ for $n_H$=20 cm$^{-3}$, from the CH+ abundance; an upper limit to the ion-neutral velocity drift, $u_{in}$ < 3.5 km s$^{-1}$, from the SH+ to CH+ abundance ratio; and a range of dissipation timescales, 100 < $tau_V$ < 1000 yr, from the CO to HCO+ abundance ratio. For the first time, we reproduce the large abundances of CO observed on diffuse lines of sight, and we show that CO may be abundant even in regions with UV-shieldings as low as $5 times 10^{-3}$ mag. The best range of parameters also reproduces the abundance ratios of OH, C2H, and H2O to HCO+ and are consistent with the known properties of the turbulent cascade in the Galactic diffuse ISM. Conclusions. Our results disclose an unexpected link between the dissipation of turbulence and the emergence of molecular richness in the diffuse ISM. Some species, such as CH+ or SH+, turn out to be unique tracers of the energy trail in the ISM. In spite of some degeneracy, the properties of the turbulent cascade, down to dissipation, can be captured through specific molecular abundances.
We examine the chemical and emission properties of mildly irradiated (G0=1) magnetised shocks in diffuse media (nH=10^2 to 10^4 /cm3) at low to moderate velocities (from 3 to 40 km/s). Results: The formation of some molecules relies on endoergic reac
tions. In J-shocks, their abundances are enhanced by several orders of magnitude for shock velocities as low as 7 km/s. Otherwise most chemical properties of J-type shocks vary over less than an order of magnitude between velocities from about 7 to about 30 km/s, where H2 dissociation sets in. C-type shocks display a more gradual molecular enhancement as the shock velocity increases. We quantify the energy flux budget (fluxes of kinetic, radiated and magnetic energies) with emphasis on the main cooling lines of the cold interstellar medium. Their sensitivity to shock velocity is such that it allows observations to constrain statistical distributions of shock velocities. We fit various probability distribution functions (PDFs) of shock velocities to spectroscopic observations of the galaxy-wide shock in Stephans Quintet (SQ) and of a Galactic line of sight sampling diffuse molecular gas in Chamaeleon. In both cases, low velocities bear the greatest statistical weight and the PDF is consistent with a bimodal distribution. In the very low velocity shocks (below 5 km/s), dissipation is due to ion-neutral friction which powers H2 low energy transitions and atomic lines. In moderate velocity shocks (20 km/s and above), the dissipation is due to viscous heating and accounts for most of the molecular emission. In our interpretation a significant fraction of the gas on the line of sight is shocked (from 4% to 66%). For example, C+ emission may trace shocks in UV irradiated gas where C+ is the dominant carbon species.
Aims. Excitation of far-infrared and submillimetric molecular lines may originate from nonreactive collisions, chemical formation, or far infrared, near-infrared, and optical fluorescences. As a template, we investigate the impact of each of these pr
ocesses on the excitation of the methylidyne cation CH+ and on the intensities of its rotational transitions recently detected in emission in dense photodissociation regions (PDRs) and in planetary nebulae. Methods. We have developed a nonlocal thermodynamic equilibrium (non-LTE) excitation model that includes the entire energy structure of CH+, i.e. taking into account the pumping of its vibrational and bound and unbound electronic states by near-infrared and optical photons. The model includes the theoretical cross-sections of nonreactive collisions with H, H2, He, and e-, and a Boltzmann distribution is used to describe the probability of populating the excited levels of CH+ during its chemical formation by hydrogenation of C+. To confirm our results we also performed an extensive analytical study, which we use to predict the main excitation process of several diatomic molecules, namely HF, HCl, SiO, CS, and CO. Results. At densities nH = 10^4 cm-3, the excitation of the rotational levels of CH+ is dominated by the radiative pumping of its electronic, vibrational, and rotational states if the intensities of the radiation field at sim 0.4, sim 4, and sim 300 mum are stronger than 10^5, 10^8, and 10^4 times those of the local interstellar radiation field (ISRF). Below these values, the chemical pumping is the dominant source of excitation of the J > 1 levels, even at high kinetic temperatures (sim 1000 K). The far-infrared emission lines of CH+ observed in the Orion Bar and the NGC 7027 PDRs are consistent with the predictions of our excitation model assuming an incident far-ultraviolet (FUV) radiation field of sim 3 times 10^4 (in Draines unit) and densities of sim 5 times 10^4 and sim 2 times 10^5 cm-3. In the case of NGC 7027, the estimate of the density is 10 to 100 times lower than those deduced by traditional excitation codes. Applying our model to other X1Sigma+ ground state diatomic molecules, we find that HF, and SiO and HCl are the species the most sensitive to the radiative pumping of their vibrational and bound electronic states. In both cases, the minimal near-infrared and optical/UV radiation field intensities required to modify their rotational level populations are sim 10^3 times those of the local ISRF at densities nH = 10^4 cm-3. All these results point towards interstellar and circumstellar media with densities lower than previously established and cast doubts on the clumpiness of well-studied molecular clouds.
Aims. The HIFI instrument onboard Herschel has allowed high spectral resolution and sensitive observations of ground-state transi- tions of three molecular ions: the methylidyne cation CH+, its isotopologue 13CH+, and sulfanylium SH+. Because of thei
r unique chemical properties, a comparative analysis of these cations provides essential clues to the link between the chemistry and dynamics of the diffuse interstellar medium. Methods. The CH+, 13CH+, and SH+ lines are observed in absorption towards the distant high-mass star-forming regions (SFRs) DR21(OH), G34.3+0.1, W31C, W33A, W49N, and W51, and towards two sources close to the Galactic centre, SgrB2(N) and SgrA*+50. All sight lines sample the diffuse interstellar matter along pathlengths of several kiloparsecs across the Galactic Plane. In order to compare the velocity structure of each species, the observed line profiles were deconvolved from the hyperfine structure of the SH+ transition and the CH+, 13CH+, and SH+ spectra were independently decomposed into Gaussian velocity components. To analyse the chemical composition of the foreground gas, all spectra were divided, in a second step, into velocity intervals over which the CH+, 13CH+, and SH+ column densities and abundances were derived. Results. SH+ is detected along all observed lines of sight, with a velocity structure close to that of CH+ and 13CH+. The linewidth distributions of the CH+, SH+, and 13CH+ Gaussian components are found to be similar. These distributions have the same mean (<deltau{psion}> ~ 4.2 km s-1) and standard deviation (sigma(deltau{psion}) ~ 1.5 km s-1). This mean value is also close to that of the linewidth distribution of the CH+ visible transitions detected in the solar neighbourhood. We show that the lack of absorption components narrower than 2 km s-1 is not an artefact caused by noise: the CH+, 13CH+, and SH+ line profiles are therefore statistically broader than those of most species detected in absorption in diffuse interstellar gas (e. g. HCO+, CH, or CN). The SH+/CH+ column density ratio observed in the components located away from the Galactic centre spans two orders of magnitude and correlates with the CH+ abundance. Conversely, the ratio observed in the components close to the Galactic centre varies over less than one order of magnitude with no apparent correlation with the CH+ abundance. The observed dynamical and chemical properties of SH+ and CH+ are proposed to trace the ubiquitous process of turbulent dissipation, in shocks or shears, in the diffuse ISM and the specific environment of the Galactic centre regions.
Aims. The comparative study of several molecular species at the origin of the gas phase chemistry in the diffuse interstellar medium (ISM) is a key input in unraveling the coupled chemical and dynamical evolution of the ISM. Methods. The lowest rotat
ional lines of HCO+, HCN, HNC, and CN were observed at the IRAM-30m telescope in absorption against the lambda 3 mm and lambda 1.3 mm continuum emission of massive star-forming regions in the Galactic plane. The absorption lines probe the gas over kiloparsecs along these lines of sight. The excitation temperatures of HCO+ are inferred from the comparison of the absorptions in the two lowest transitions. The spectra of all molecular species on the same line of sight are decomposed into Gaussian velocity components. Most appear in all the spectra of a given line of sight. For each component, we derived the central opacity, the velocity dispersion, and computed the molecular column density. We compared our results to the predictions of UV-dominated chemical models of photodissociation regions (PDR models) and to those of non-equilibrium models in which the chemistry is driven by the dissipation of turbulent energy (TDR models). Results. The molecular column densities of all the velocity components span up to two orders of magnitude. Those of CN, HCN, and HNC are linearly correlated with each other with mean ratios N(HCN)/N(HNC) = 4.8 $pm$ 1.3 and N(CN)/N(HNC) = 34 $pm$ 12, and more loosely correlated with those of HCO+, N(HNC)/N(HCO+) = 0.5 $pm$ 0.3, N(HCN)/N(HCO+) = 1.9 $pm$ 0.9, and N(CN)/N(HCO+) = 18 $pm$ 9. These ratios are similar to those inferred from observations of high Galactic latitude lines of sight, suggesting that the gas sampled by absorption lines in the Galactic plane has the same chemical properties as that in the Solar neighbourhood. The FWHM of the Gaussian velocity components span the range 0.3 to 3 km s-1 and those of the HCO+ lines are found to be 30% broader than those of CN-bearing molecules. The PDR models fail to reproduce simultaneously the observed abundances of the CN-bearing species and HCO+, even for high-density material (100 cm-3 < nH < 104 cm-3). The TDR models, in turn, are able to reproduce the observed abundances and abundance ratios of all the analysed molecules for the moderate gas densities (30 cm-3 < nH < 200 cm-3) and the turbulent energy observed in the diffuse interstellar medium. Conclusions. Intermittent turbulent dissipation appears to be a promising driver of the gas phase chemistry of the diffuse and translucent gas throughout the Galaxy. The details of the dissipation mechanisms still need to be investigated.
Supersonic turbulence is a large reservoir of suprathermal energy in the interstellar medium. Its dissipation, because it is intermittent in space and time, can deeply modify the chemistry of the gas. We further explore a hybrid method to compute the
chemical and thermal evolution of a magnetized dissipative structure, under the energetic constraints provided by the observed properties of turbulence in the cold neutral medium. For the first time, we model a random line of sight by taking into account the relative duration of the bursts with respect to the thermal and chemical relaxation timescales of the gas. The key parameter is the turbulent rate of strain a due to the ambient turbulence. With the gas density, it controls the size of the dissipative structures, therefore the strength of the burst. For a large range of rates of strain and densities, the models of turbulent dissipation regions (TDR) reproduce the CH+ column densities observed in the diffuse medium and their correlation with highly excited H2. They do so without producing an excess of CH. As a natural consequence, they reproduce the abundance ratios of HCO+/OH and HCO+/H2O, and their dynamic range of about one order of magnitude observed in diffuse gas. Large C2H and CO abundances, also related to those of HCO+, are another outcome of the TDR models that compare well with observed values. The abundances and column densities computed for CN, HCN and HNC are one order of magnitude above PDR model predictions, although still significantly smaller than observed values.
