In a previous paper (Phase Transitions, 80(9), 987, 2007) we discussed the smectic and nematic textures of some mesomorphic oxadiazole compounds with terminal Cl-substituent. Optical microscope investigations showed a very interesting behaviour of sm
ectic and nematic phases; the smectic phase has fan-shaped and toric textures and the nematic phase has spherulitic domains, which disappear as the sample is further heated, the texture changing into a smooth one. Here, we investigate four oxadiazole compounds with the same structure but terminal Br-substituent. The behaviour of the smectic and nematic phases is like that observed in the compounds with Cl. The focus of the paper is on the growth of toric domains from the nematic melt and on the role of defects in the domain structure.
When a family of non symmetrical heterocycled compounds is investigated, a variety of mesophases can be observed with rather different features. Here we report the behaviour of seven different members among a family of such materials, that consists o
f mesomorphic oxadiazole compounds. In two of these compounds, the optical microscope investigation shows very interesting behaviours. In their smectic phases, fan-shaped and toric textures, sometimes with periodic instability, are observed. Moreover, the nematic phase displays a texture transition. Texture transitions have been previously observed only inside the nematic phase of some compounds belonging to the families of the oxybenzoic and cyclohexane acids. In these two oxadiazole compounds we can observe what we define as a toric nematic phase, heating the samples from the smectic phase. The toric nematic texture disappears as the sample is further heated, changing into a smooth texture.
