In this short review we propose a critical assessment of the role of chaos for the thermalization of Hamiltonian systems with high dimensionality. We discuss this problem for both classical and quantum systems. A comparison is made between the two si
tuations: some examples from recent and past literature are presented which support the point of view that chaos is not necessary for thermalization. Finally, we suggest that a close analogy holds between the role played by Kinchins theorem for high-dimensional classical systems and the role played by Von Neumanns theorem for many-body quantum systems.
We provide here an explicit example of Khinchins idea that the validity of equilibrium statistical mechanics in high dimensional systems does not depend on the details of the dynamics. This point of view is supported by extensive numerical simulation
of the one-dimensional Toda chain, an integrable non-linear Hamiltonian system where all Lyapunov exponents are zero by definition. We study the relaxation to equilibrium starting from very atypical initial conditions and focusing on energy equipartion among Fourier modes, as done in the original Fermi-Pasta-Ulam-Tsingou numerical experiment. We find evidence that in the general case, i.e., not in the perturbative regime where Toda and Fourier modes are close to each other, there is a fast reaching of thermal equilibrium in terms of a single temperature. We also find that equilibrium fluctuations, in particular the behaviour of specific heat as function of temperature, are in agreement with analytic predictions drawn from the ordinary Gibbs ensemble, still having no conflict with the established validity of the Generalized Gibbs Ensemble for the Toda model. Our results suggest thus that even an integrable Hamiltonian system reaches thermalization on the constant energy hypersurface, provided that the considered observables do not strongly depend on one or few of the conserved quantities. This suggests that dynamical chaos is irrelevant for thermalization in the large-$N$ limit, where any macroscopic observable reads of as a collective variable with respect to the coordinate which diagonalize the Hamiltonian. The possibility for our results to be relevant for the problem of thermalization in generic quantum systems, i.e., non-integrable ones, is commented at the end.
About 35 years ago Wheeler introduced the motto `law without law to highlight the possibility that (at least a part of) Physics may be understood only following {em regularity principles} and few relevant facts, rather than relying on a treatment in
terms of fundamental theories. Such a proposal can be seen as part of a more general attempt (including the maximum entropy approach) summarized by the slogan `it from bit, which privileges the information as the basic ingredient. Apparently it seems that it is possible to obtain, without the use of physical laws, some important results in an easy way, for instance, the probability distribution of the canonical ensemble. In this paper we will present a general discussion on those ideas of Wheelers that originated the motto `law without law. In particular we will show how the claimed simplicity is only apparent and it is rather easy to produce wrong results. We will show that it is possible to obtain some of the results treated by Wheeler in the realm of the statistical mechanics, using precise assumptions and nontrivial results of probability theory, mainly concerning ergodicity and limit theorems.
Two deterministic models for Brownian motion are investigated by means of numerical simulations and kinetic theory arguments. The first model consists of a heavy hard disk immersed in a rarefied gas of smaller and lighter hard disks acting as a therm
al bath. The second is the same except for the shape of the particles, which is now square. The basic difference of these two systems lies in the interaction: hard core elastic collisions make the dynamics of the disks chaotic whereas that of squares is not. Remarkably, this difference is not reflected in the transport properties of the two systems: simulations show that the diffusion coefficients, velocity correlations and response functions of the heavy impurity are in agreement with kinetic theory for both the chaotic and the non-chaotic model. The relaxation to equilibrium, however, is very sensitive to the kind of interaction. These observations are used to reconsider and discuss some issues connected to chaos, statistical mechanics and diffusion.
