Fatigue failure in ferroelectrics has been intensively investigated in the past few decades. Most of the mechanisms discussed for ferroelectric fatigue have been built on the hypothesis of variation in charged defects, which however are rarely eviden
ced by experimental observation. Here, using a combination of complex impedance spectra techniques, piezoresponse force microscopy and first-principles theory, we examine the microscopic evolution and redistribution of charged defects during the electrical cycling in BiFeO3 thin films. The dynamic formation and melting behaviors of oxygen vacancy (VO) order are identified during the fatigue process. It reveals that the isolated VO tend to self-order along grain boundaries to form a planar-aligned structure, which blocks the domain reversals. Upon further electrical cycling, migration of VO within vacancy clusters is accommodated with a lower energy barrier (~0.2 eV) and facilitates the formation of nearby-electrode layer incorporated with highly concentrated VO. The interplay between the macroscopic fatigue and microscopic evolution of charged defects clearly demonstrates the role of ordered VO cluster in the fatigue failure of BiFeO3 thin films.
Ultra Violet Imaging Telescope on ASTROSAT Satellite mission is a suite of Far Ultra Violet (FUV 130 to 180 nm), Near Ultra Violet (NUV 200 to 300 nm) and Visible band (VIS 320 to 550nm) imagers. ASTROSAT is the first multi wavelength mission of INDI
A. UVIT will image the selected regions of the sky simultaneously in three channels and observe young stars, galaxies, bright UV Sources. FOV in each of the 3 channels is about 28 arc-minute. Targeted angular resolution in the resulting UV images is better than 1.8 arc-second (better than 2.0 arc-second for the visible channel). Two identical co-aligned telescopes (T1, T2) of Ritchey-Chretien configuration (Primary mirror of 375 mm diameter) collect celestial radiation and feed to the detector system via a selectable filter on a filter wheel mechanism; gratings are available in filter wheels of FUV and NUV channels for slit-less low resolution spectroscopy. The detector system for each of the 3 channels is generically identical. One of the telescopes images in the FUV channel, while the other images in NUV and VIS channels. Images from VIS channel are also used for measuring drift for reconstruction of images on ground through shift and add algorithm, and to reconstruct absolute aspect of the images. Adequate baffling has been provided for reducing scattered background from the Sun, earth albedo and other bright objects. One time open-able mechanical cover on each telescope also works as a Sun-shield after deployment. We are presenting here the overall (mechanical, optical and electrical) design of the payload.
Secure communication between two nodes in a network depends on reliable key management systems that generate and distribute keys between communicating nodes and a secure routing protocol that establishes a route between them. But due to lack of centr
al server and infrastructure in Mobile Ad hoc Networks (MANETs), this is major problem to manage the keys in the network. Dynamically changes in networks topology causes weak trust relationship among the nodes in the network. In MANETs a mobile node operates as not only end terminal but also as an intermediate router. Therefore, a multi-hop scenario occurs for communication in MANETs; where there may be one or more malicious nodes in between source and destination. A routing protocol is said to be secure that detects the detrimental effects of malicious node(s in the path from source to destination). In this paper, we proposed a key management scheme and a secure routing protocol that secures on demand routing protocol such as DSR and AODV. We assume that MANETs is divided into groups having a group leader in each group. Group leader has responsibility of key management in its group. Proposed key management scheme is a decentralized scheme that does not require any Trusted Third Party (TTP) for key management. In proposed key management system, both a new node and group leader authenticates each other mutually before joining the network. While proposed secure routing protocol allows both communicating parties as well as intermediate nodes to authenticate other nodes and maintains message integrity
We have studied the polarization fatigue of La and Mg co-substituted BiFeO3 thin film, where a polarization peak is observed during the fatigue process. The origin of such anomalous behavior is analyzed on the basis of the defect evolution using temp
erature-dependent impedance spectroscopy. It shows that the motion of oxygen vacancies (VO..) is associated with a lower energy barrier, accompanied by the injection of electrons into the film during the fatigue process. A qualitative model is proposed to explain the fatigue behavior, which involves the modification of the Schottky barrier upon the accumulation of VO.. at the metal-dielectric interface.
The conductive characteristics of Bi0.9La0.1Fe0.96Mg0.04O3(BLFM) thin film are investigated at various temperatures and a negative differential resistance (NDR) is observed in the thin film, where a leakage current peak occurs upon application of a d
ownward electric field above 80 oC. The origin of the NDR behavior is shown to be related to the ionic defect of oxygen vacancies (VO..) present in the film. On the basis of analyzing the leakage mechanism and surface potential behavior, the NDR behavior can be understood by considering the competition between the polarized distribution and neutralization of VO...
Using spectroscopic ellipsometry, the refractive index and absorption versus wavelength of the ferroelectric antiferromagnet Bismuth Ferrite, BiFeO_3 is reported. The material has a direct band-gap at 442 nm wavelength (2.81 eV). Using optical second
harmonic generation, the nonlinear optical coefficients were determined to be d_15/d_22 = 0.20 +/- 0.01, d_31/d_22 = 0.35 +/- 0.02, d_33/d_22 = -11.4 +/- 0.20 and |d_22| = 298.4 +/- 6.1 pm/V at a fundamental wavelength of 800 nm.
