A one-dimensional nano-metric-thin cell (NC) filled with potassium metal has been built and used to study optical atomic transitions in external magnetic fields. These studies benefit from the remarkable features of the NC allowing one to use $lambda
/2$- and $lambda$-methods for effective investigations of individual transitions of the K D_1 line. The methods are based on strong narrowing of the absorption spectrum of the atomic column of thickness L equal to $lambda/2$ and to $lambda$(with $lambda = 770un{nm}$ being the resonant laser radiation wavelength). In particular, for a $pi$-polarized radiation excitation the $lambda$-method allows us to resolve eight atomic transitions (in two groups of four atomic transitions) and to reveal two remarkable transitions that we call Guiding Transitions (GT). The probabilities of all other transitions inside the group (as well as the frequency slope versus magnetic field) tend to the probability and to the slope of GT. Note that for circular polarization there is one group of four transitions and GT do not exist. Among eight transitions there are also two transitions (forbidden for $B$ = 0) with the probabilities undergoing strong modification under the influence of magnetic fields. Practically the complete hyperfine Paschen-Back regime is observed at relatively low ($sim 1un{kG}$) magnetic fields. Note that for K $D_2$ line GT are absent. Theoretical models describe the experiment very well.
An efficient $lambda/2$-method ($lambda$ is the resonant wavelength of laser radiation) based on nanometric-thickness cell filled with rubidium is implemented to study the splitting of hyperfine transitions of $^{85}$Rb and $^{87}$Rb $D_2$ lines in a
n external magnetic field in the range of $B =3$~kG -- 7~kG. It is experimentally demonstrated that at $B > 3$~kG from 38 (22) Zeeman transitions allowed at low $B$-field in $^{85}$Rb ($^{87}$Rb) spectra in the case of $sigma^+$ polarized laser radiation there remain only 12 (8) which is caused by decoupling of the total electronic momentum $textbf{J}$ and the nuclear spin momentum $textbf{I}$ (hyperfine Paschen-Back regime). Note that at $B > 4.5$~kG in the absorption spectrum these $20$ atomic transitions are regrouped in two completely separate groups of $10$ atomic transitions each. Their frequency positions and fixed (within each group) frequency slopes, as well as the probability characteristics are determined. A unique behavior of the atomic transitions of $^{85}$Rb and $^{87}$Rb labeled $19$ and $20$ (for low magnetic field they could be presented as transitions $F_g=3, m_F=+3 rightarrow F_e=4, m_F=+4$ and $F_g=2, m_F=+2 rightarrow F_e=3, m_F=+3$, correspondingly) is stressed. The experiment agrees well with the theory. Comparison of the behavior of atomic transitions for $D_2$ line compared with that of $D_1$ line is presented. Possible applications are described.
The existence of cross-over resonances makes saturated-absorption spectra very complicated when external magnetic field B is applied. It is demonstrated for the first time that the use of micrometric-thin cells (MTC, $Lapprox40,mu$m) allows applicati
on of SA for quantitative studies of frequency splittings and shifts of the Rb atomic transitions in a wide range of external magnetic fields, from 0.2 up to 6 kG (20-600 mT). We compare the SA spectra obtained with the MTC with those obtained with other techniques, and present applications for optical magnetometry with micrometer spatial resolution and a broadly tunable optical frequency reference.
Magnetic field-induced giant modification of probabilities for seven components of 6S1/2 (Fg=3) - 6P3/2 (Fe=5) transition of Cs D2 line forbidden by selection rules is observed experimentally for the first time. For the case of excitation with circul
arly-polarized laser radiation, the probability of Fg=3,mF=-3 - Fe=5,mF=-2 transition becomes the largest among 25 transitions of Fg=3 - Fe=2,3,4,5 group in a wide range of magnetic field 200 - 3200 G. Moreover, the modification is the largest among D2 lines of alkali metals. A half-wave-thick cell (length along the beam propagation axis L=426 nm) filled with Cs has been used in order to achieve sub-Doppler resolution which allows for separating the large number of atomic transitions that appear in the absorption spectrum when an external magnetic field is applied. For B > 3 kG the group of seven transitions Fg=3 - Fe=5 is completely resolved and is located at the high frequency wing of Fg=3 - Fe=2,3,4 transitions. The applied theoretical model very well describes the experimental curves.
We analyze the problem of the helix-coil transition in explicit solvents analytically by using spin-based models incorporating two different mechanisms of solvent action: explicit solvent action through the formation of solvent-polymer hydrogen bonds
that can compete with the intrinsic intra-polymer hydrogen bonded configurations (competing interactions) and implicit solvent action, where the solvent-polymer interactions tune biopolymer configurations by changing the activity of the solvent (non-competing interactions). The overall spin Hamiltonian is comprised of three terms: the background emph{in vacuo} Hamiltonian of the Generalized Model of Polypeptide Chain type and two additive terms that account for the two above mechanisms of solvent action. We show that on this level the solvent degrees of freedom can be {sl explicitly} and {sl exactly} traced over, the ensuing effective partition function combining all the solvent effects in a unified framework. In this way we are able to address helix-coil transitions for polypeptides, proteins, and DNA, with different buffers and different external constraints. Our spin-based effective Hamiltonian is applicable for treatment of such diverse phenomena as cold denaturation, effects of osmotic pressure on the cold and warm denaturation, complicated temperature dependence of the hydrophobic effect as well as providing a conceptual base for understanding the behavior of Intrinsically Disordered Proteins and their analogues.
The problem of the helix-coil transition of biopolymers in explicit solvents, like water, with the ability for hydrogen bonding with solvent is addressed analytically using a suitably modified version of the Generalized Model of Polypeptide Chains. B
esides the regular helix-coil transition, an additional coil-helix or reentrant transition is also found at lower temperatures. The reentrant transition arises due to competition between polymer-polymer and polymer-water hydrogen bonds. The balance between the two types of hydrogen bonding can be shifted to either direction through changes not only in temperature, but also by pressure, mechanical force, osmotic stress or other external influences. Both polypeptides and polynucleotides are considered within a unified formalism. Our approach provides an explanation of the experimental difficulty of observing the reentrant transition with pressure; and underscores the advantage of pulling experiments for studies of DNA. Results are discussed and compared with those reported in a number of recent publications with which a significant level of agreement is obtained.
This paper has been withdrawn by the authors due to the violation of ATLAS experiment publication policy.
