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We determine the first independent part of the g^6 coefficient in the weak coupling expansion of the QCD pressure at high temperatures, the one proportional to the maximal power of the number of quark flavors N_f. In addition to introducing and devel oping computational methods that can be used in evaluating other parts of the expansion, our calculation provides a result that becomes dominant in the limit of large N_f and a fixed effective coupling g_{eff}^2 = g^2 N_f/2.
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