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Spreading in narrow channels

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 Added by Carlo Dotti
 Publication date 2007
  fields Physics
and research's language is English




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We study a lattice model for the spreading of fluid films, which are a few molecular layers thick, in narrow channels with inert lateral walls. We focus on systems connected to two particle reservoirs at different chemical potentials, considering an attractive substrate potential at the bottom, confining side walls, and hard-core repulsive fluid-fluid interactions. Using kinetic Monte Carlo simulations we find a diffusive behavior. The corresponding diffusion coefficient depends on the density and is bounded from below by the free one-dimensional diffusion coefficient, valid for an inert bottom wall. These numerical results are rationalized within the corresponding continuum limit.



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We summarise different results on the diffusion of a tracer particle in lattice gases of hard-core particles with stochastic dynamics, which are confined to narrow channels -- single-files, comb-like structures and quasi-one-dimensional channels with the width equal to several particle diameters. We show that in such geometries a surprisingly rich, sometimes even counter-intuitive, behaviour emerges, which is absent in unbounded systems. We also present a survey of different results obtained for a tracer particle diffusion in unbounded systems, which will permit a reader to have an exhaustively broad picture of the tracer diffusion in crowded environments.
The rectification of a single file of attracting particles subjected to a low frequency ac drive is proposed as a working mechanism for particle shuttling in an asymmetric narrow channel. Increasing the particle attraction results in the file condensing, as signalled by the dramatic enhancement of the net particle current. Magnitude and direction of the current become extremely sensitive to the actual size of the condensate, which can then be made to shuttle between two docking stations, transporting particles in one direction, with an efficiency much larger than conventional diffusive models predict.
Operators in ergodic spin-chains are found to grow according to hydrodynamical equations of motion. The study of such operator spreading has aided our understanding of many-body quantum chaos in spin-chains. Here we initiate the study of operator spreading in quantum maps on a torus, systems which do not have a tensor-product Hilbert space or a notion of spatial locality. Using the perturbed Arnold cat map as an example, we analytically compare and contrast the evolutions of functions on classical phase space and quantum operator evolutions, and identify distinct timescales that characterize the dynamics of operators in quantum chaotic maps. Until an Ehrenfest time, the quantum system exhibits classical chaos, i.e. it mimics the behavior of the corresponding classical system. After an operator scrambling time, the operator looks random in the initial basis, a characteristic feature of quantum chaos. These timescales can be related to the quasi-energy spectrum of the unitary via the spectral form factor. Furthermore, we show examples of emergent classicality in quantum problems far away from the classical limit. Finally, we study operator evolution in non-chaotic and mixed quantum maps using the Chirikov standard map as an example.
We study reaction-diffusion processes on graphs through an extension of the standard reaction-diffusion equation starting from first principles. We focus on reaction spreading, i.e. on the time evolution of the reaction product, M(t). At variance with pure diffusive processes, characterized by the spectral dimension, d_s, for reaction spreading the important quantity is found to be the connectivity dimension, d_l. Numerical data, in agreement with analytical estimates based on the features of n independent random walkers on the graph, show that M(t) ~ t^{d_l}. In the case of Erdos-Renyi random graphs, the reaction-product is characterized by an exponential growth M(t) ~ e^{a t} with a proportional to ln<k>, where <k> is the average degree of the graph.
An increasing number of low carrier density materials exhibit a surprisingly large transport mean free path due to inefficient momentum relaxation. Consequently, charge transport in these systems is markedly non-ohmic but rather ballistic or hydrodynamic, features which can be explored by driving current through narrow channels. Using a kinetic equation approach we theoretically investigate how a non-quantizing magnetic field discerns ballistic and hydrodynamic transport, in particular in the spatial dependence of the transverse electric field, $E_y$: We find that $E_y$ is locally enhanced when the flow exhibits a sharp directional anisotropy in the non-equilibrium density. As a consequence, at weak magnetic fields, the curvature of $E_y$ has opposite signs in the ballistic and hydrodynamic regimes. Moreover, we find a robust signature of the onset of non-local correlations in the form of distinctive peaks of the transverse field, which are accessible by local measurements. Our results demonstrate that a purely hydrodynamic approach is insufficient in the Gurzhi regime once a magnetic field is introduced.
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