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Register a new userLinear response theory of activated surface diffusion with interacting adsorbates
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Activated surface diffusion with interacting adsorbates is analyzed within the Linear Response Theory framework. The so-called interacting single adsorbate model is justified by means of a two-bath model, where one harmonic bath takes into account the interaction with the surface phonons, while the other one describes the surface coverage, this leading to defining a collisional friction. Here, the corresponding theory is applied to simple systems, such as diffusion on flat surfaces and the frustrated translational motion in a harmonic potential. Classical and quantum closed formulas are obtained. Furthermore, a more realistic problem, such as atomic Na diffusion on the corrugated Cu(001) surface, is presented and discussed within the classical context as well as within the framework of Kramers theory. Quantum corrections to the classical results are also analyzed and discussed.
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Surface diffusion of interacting adsorbates is here analyzed within the context of two fundamental phenomena of quantum dynamics, namely the quantum Zeno effect and the anti-Zeno effect. The physical implications of these effects are introduced here in a rather simple and general manner within the framework of non-selective measurements and for two (surface) temperature regimes: high and very low (including zero temperature). The quantum intermediate scattering function describing the adsorbate diffusion process is then evaluated for flat surfaces, since it is fully analytical in this case. Finally, a generalization to corrugated surfaces is also discussed. In this regard, it is found that, considering a Markovian framework and high surface temperatures, the anti-Zeno effect has already been observed, though not recognized as such.
Fluctuation dissipation theorems connect the linear response of a physical system to a perturbation to the steady-state correlation functions. Until now, most of these theorems have been derived for finite-dimensional systems. However, many relevant physical processes are described by systems of infinite dimension in the Gaussian regime. In this work, we find a linear response theory for quantum Gaussian systems subject to time dependent Gaussian channels. In particular, we establish a fluctuation dissipation theorem for the covariance matrix that connects its linear response at any time to the steady state two-time correlations. The theorem covers non-equilibrium scenarios as it does not require the steady state to be at thermal equilibrium. We further show how our results simplify the study of Gaussian systems subject to a time dependent Lindbladian master equation. Finally, we illustrate the usage of our new scheme through some examples. Due to broad generality of the Gaussian formalism, we expect our results to find an application in many physical platforms, such as opto-mechanical systems in the presence of external noise or driven quantum heat devices.
Dynamics of a particle diffusing in a confinement can be seen a sequence of bulk-diffusion-mediated hops on the confinement surface. Here, we investigate the surface hopping propagator that describes the position of the diffusing particle after a prescribed number of encounters with that surface. This quantity plays the central role in diffusion-influenced reactions and determines their most common characteristics such as the propagator, the first-passage time distribution, and the reaction rate. We derive explicit formulas for the surface hopping propagator and related quantities for several Euclidean domains: half-space, circular annuli, circular cylinders, and spherical shells. These results provide the theoretical ground for studying diffusion-mediated surface phenomena. The behavior of the surface hopping propagator is investigated for both immortal and mortal particles.
We extend Kubos Linear Response Theory (LRT) to periodic input signals with arbitrary shapes and obtain exact analytical formulas for the energy dissipated by the system for a variety of signals. These include the square and sawtooth waves, or pulsed signals such as the rectangular, sine and $delta$-pulses. It is shown that for a given input energy, the dissipation may be substantially augmented by exploiting different signal shapes. We also apply our results in the context of magnetic hyperthermia, where small magnetic particles are used as local heating centers in oncological treatments.
We study the response to perturbations in the thermodynamic limit of a network of coupled identical agents undergoing a stochastic evolution which, in general, describes non-equilibrium conditions. All systems are nudged towards the common centre of mass. We derive Kramers-Kronig relations and sum rules for the linear susceptibilities obtained through mean field Fokker-Planck equations and then propose corrections relevant for the macroscopic case, which incorporates in a self-consistent way the effect of the mutual interaction between the systems. Such an interaction creates a memory effect. We are able to derive conditions determining the occurrence of phase transitions specifically due to system-to-system interactions. Such phase transitions exist in the thermodynamic limit and are associated with the divergence of the linear response but are not accompanied by the divergence in the integrated autocorrelation time for a suitably defined observable. We clarify that such endogenous phase transitions are fundamentally different from other pathologies in the linear response that can be framed in the context of critical transitions. Finally, we show how our results can elucidate the properties of the Desai-Zwanzig model and of the Bonilla-Casado-Morillo model, which feature paradigmatic equilibrium and non-equilibrium phase transitions, respectively.
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