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Register a new userHCN/HNC intensity ratio: a new chemical thermometer for the molecular ISM
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Context. The gas kinetic temperature (TK) determines the physical and chemical evolution of the Interestellar Medium (ISM). However, obtaining reliable TK estimates usually requires expensive observations including the combination of multi-line analysis and dedicated radiative transfer calculations. Aims. This work explores the use of HCN and HNC observations, and particularly its I(HCN)/I(HNC) intensity ratio of their J=1-0 lines, as direct probe of the gas kinetic temperature in the molecular ISM. Methods. We obtained a new set of large-scale observations of both HCN and HNC (1-0) lines along the Integral Shape Filament (ISF) in Orion. In combination with ancillary gas and dust temperature measurements, we find a systematic temperature dependence of the observed I(HCN)/I(HNC) intensity ratio across our maps. Additional comparisons with chemical models demonstrate that these observed I(HCN)/I(HNC) variations are driven by the effective destruction and isomerization mechanisms of HNC under low energy barriers. Results. The observed variations of I(HCN)/I(HNC) with TK can be described with a two-part linear function. This empirical calibration is then used to create a temperature map of the entire ISF. Comparisons with similar dust temperature measurements in this cloud, as well as in other regions and galactic surveys, validate this simple technique to obtain direct estimates of the gas kinetic temperature in a wide range of physical conditions and scales with an optimal working range between 15 K and 40 K. Conclusions. Both observations and models demonstrate the strong sensitivity of the I(HCN)/I(HNC) ratio to the gas kinetic temperature. Since these lines are easily obtained in observations of local and extragalactic sources, our results highlight the potential use of this observable as new chemical thermometer for the ISM.
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HNC and HCN, typically used as dense gas tracers in molecular clouds, are a pair of isomers that have great potential as a temperature probe because of temperature dependent, isomer-specific formation and destruction pathways. Previous observations of the HNC/HCN abundance ratio show that the ratio decreases with increasing temperature, something that standard astrochemical models cannot reproduce. We have undertaken a detailed parameter study on which environmental characteristics and chemical reactions affect the HNC/HCN ratio and can thus contribute to the observed dependence. Using existing gas and gas-grain models updated with new reactions and reaction barriers, we find that in static models the H + HNC gas-phase reaction regulates the HNC/HCN ratio under all conditions, except for very early times. We quantitively constrain the combinations of H abundance and H + HNC reaction barrier that can explain the observed HNC/HCN temperature dependence and discuss the implications in light of new quantum chemical calculations. In warm-up models, gas-grain chemistry contributes significantly to the predicted HNC/HCN ratio and understanding the dynamics of star formation is therefore key to model the HNC/HCN system.
We report a new analysis protocol for HCN hyperfine data, based on the PYSPECKIT package, and results of using this new protocol to analyse a sample area of seven massive molecular clumps from the Census of High- and Medium-mass Protostars (CHaMP) survey, in order to derive maps of column density for this species. There is a strong correlation between the HCN integrated intensity, IHCN, and previously reported IHCO+ in the clumps, but IN2H+ is not well correlated with either of these other two dense gas tracers. The four fitted parameters from PYSPECKIT in this region fall in the range of VLSR = 8-10 km/s, {sigma} V = 1.2-2.2 km/s, Tex = 4-15 K, and {tau} = 0.2-2.5. These parameters allow us to derive a column density map of these clouds, without limiting assumptions about the excitation or opacity. A more traditional (linear) method of converting IHCN to total mass column gives much lower clump masses than our results based on the hyperfine analysis. This is primarily due to areas in the sample region of low I, low Tex, and high {tau} . We conclude that there may be more dense gas in these massive clumps not engaged in massive star formation than previously recognized. If this result holds for other clouds in the CHaMP sample, it would have dramatic consequences for the calibration of the Kennicutt-Schmidt star formation laws, including a large increase in the gas depletion time-scale in such regions.
Using the HCN and HNC J=1--0 line observations, the abundance ratio of HCN/HNC has been estimated for different evolutionary stages of massive star formation: Infrared dark clouds (IRDCs), High-mass protostellar object (HMPOs), and Ultra-compact HII regions (UCHIIs). IRDCs were divided into `quiescent IRDC cores and `active IRDC cores, depending on star formation activity. The HCN/HNC ratio is known to be higher at active and high temperature regions related to ongoing star formation, compared to cold and quiescent regions. Our observations toward 8 quiescent IRDC cores, 16 active IRDC cores, 23 HMPOs, and 31 UCHIIs show consistent results; the ratio is 0.97~($pm~0.10$), 2.65~($pm~0.88$), 4.17~($pm~1.03$) and 8.96~($pm~3.32$) in these respective evolutionary stages, increasing from quiescent IRDC cores to UCHIIs. The change of the HCN/HNC abundance ratio, therefore, seems directly associated with the evolutionary stages of star formation, which have different temperatures. One suggested explanation for this trend is the conversion of HNC to HCN, which occurs effectively at higher temperatures. To test the explanation, we performed a simple chemical model calculation. In order to fit the observed results, the energy barrier of the conversion must be much lower than the value provided by theoretical calculations.
Aims. The comparative study of several molecular species at the origin of the gas phase chemistry in the diffuse interstellar medium (ISM) is a key input in unraveling the coupled chemical and dynamical evolution of the ISM. Methods. The lowest rotational lines of HCO+, HCN, HNC, and CN were observed at the IRAM-30m telescope in absorption against the lambda 3 mm and lambda 1.3 mm continuum emission of massive star-forming regions in the Galactic plane. The absorption lines probe the gas over kiloparsecs along these lines of sight. The excitation temperatures of HCO+ are inferred from the comparison of the absorptions in the two lowest transitions. The spectra of all molecular species on the same line of sight are decomposed into Gaussian velocity components. Most appear in all the spectra of a given line of sight. For each component, we derived the central opacity, the velocity dispersion, and computed the molecular column density. We compared our results to the predictions of UV-dominated chemical models of photodissociation regions (PDR models) and to those of non-equilibrium models in which the chemistry is driven by the dissipation of turbulent energy (TDR models). Results. The molecular column densities of all the velocity components span up to two orders of magnitude. Those of CN, HCN, and HNC are linearly correlated with each other with mean ratios N(HCN)/N(HNC) = 4.8 $pm$ 1.3 and N(CN)/N(HNC) = 34 $pm$ 12, and more loosely correlated with those of HCO+, N(HNC)/N(HCO+) = 0.5 $pm$ 0.3, N(HCN)/N(HCO+) = 1.9 $pm$ 0.9, and N(CN)/N(HCO+) = 18 $pm$ 9. These ratios are similar to those inferred from observations of high Galactic latitude lines of sight, suggesting that the gas sampled by absorption lines in the Galactic plane has the same chemical properties as that in the Solar neighbourhood. The FWHM of the Gaussian velocity components span the range 0.3 to 3 km s-1 and those of the HCO+ lines are found to be 30% broader than those of CN-bearing molecules. The PDR models fail to reproduce simultaneously the observed abundances of the CN-bearing species and HCO+, even for high-density material (100 cm-3 < nH < 104 cm-3). The TDR models, in turn, are able to reproduce the observed abundances and abundance ratios of all the analysed molecules for the moderate gas densities (30 cm-3 < nH < 200 cm-3) and the turbulent energy observed in the diffuse interstellar medium. Conclusions. Intermittent turbulent dissipation appears to be a promising driver of the gas phase chemistry of the diffuse and translucent gas throughout the Galaxy. The details of the dissipation mechanisms still need to be investigated.
HCN and its isomer HNC play an important role in molecular cloud chemistry and the formation of more complex molecules. We investigate here the impact of protostellar shocks on the HCN and HNC abundances from high-sensitivity IRAM 30m observations of the prototypical shock region L1157-B1 and the envelope of the associated Class 0 protostar, as a proxy for the pre-shock gas. The isotopologues H$^{12}$CN, HN$^{12}$C, H$^{13}$CN, HN$^{13}$C, HC$^{15}$N, H$^{15}$NC, DCN and DNC were all detected towards both regions. Abundances and excitation conditions were obtained from radiative transfer analysis of molecular line emission under the assumption of Local Thermodynamical Equilibrium. In the pre-shock gas, the abundances of the HCN and HNC isotopologues are similar to those encountered in dark clouds, with a HCN/HNC abundance ratio $approx 1$ for all isotopologues. A strong D-enrichment (D/H$approx 0.06$) is measured in the pre-shock gas. There is no evidence of $^{15}$N fractionation neither in the quiescent nor in the shocked gas. At the passage of the shock, the HCN and HNC abundances increase in the gas phase in different manners so that the HCN/HNC relative abundance ratio increases by a factor 20. The gas-grain chemical and shock model UCLCHEM allows us to reproduce the observed trends for a C-type shock with pre-shock density $n$(H)= $10^5$cm$^{-3}$ and shock velocity $V_s= 40$km/s. We conclude that the HCN/HNC variations across the shock are mainly caused by the sputtering of the grain mantle material in relation with the history of the grain ices.
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