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Register a new userThe HCN/HNC abundance ratio toward different evolutionary phases of massive star formation
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Using the HCN and HNC J=1--0 line observations, the abundance ratio of HCN/HNC has been estimated for different evolutionary stages of massive star formation: Infrared dark clouds (IRDCs), High-mass protostellar object (HMPOs), and Ultra-compact HII regions (UCHIIs). IRDCs were divided into `quiescent IRDC cores and `active IRDC cores, depending on star formation activity. The HCN/HNC ratio is known to be higher at active and high temperature regions related to ongoing star formation, compared to cold and quiescent regions. Our observations toward 8 quiescent IRDC cores, 16 active IRDC cores, 23 HMPOs, and 31 UCHIIs show consistent results; the ratio is 0.97~($pm~0.10$), 2.65~($pm~0.88$), 4.17~($pm~1.03$) and 8.96~($pm~3.32$) in these respective evolutionary stages, increasing from quiescent IRDC cores to UCHIIs. The change of the HCN/HNC abundance ratio, therefore, seems directly associated with the evolutionary stages of star formation, which have different temperatures. One suggested explanation for this trend is the conversion of HNC to HCN, which occurs effectively at higher temperatures. To test the explanation, we performed a simple chemical model calculation. In order to fit the observed results, the energy barrier of the conversion must be much lower than the value provided by theoretical calculations.
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We analyzed both HCN J=1-0 and HNC J=1-0 line profiles to study the inflow motions in different evolutionary stages of massive star formation: 54 infrared dark clouds (IRDCs), 69 high-mass protostellar object (HMPOs), and 54 ultra-compact HII regions (UCHIIs). The inflow asymmetry in HCN spectra seems to be prevalent throughout all the three evolutionary phases, with IRDCs showing the largest excess in blue profile. In the case of HNC spectra, the prevalence of blue sources does not appear, excepting for IRDCs. We suggest that this line is not appropriate to trace inflow motion in evolved stages of massive star formation because the abundance of HNC decreases at high temperatures. This result spotlights the importance of considering chemistry in the dynamics study of massive star-forming regions. The fact that the IRDCs show the highest blue excess in both transitions indicates that the most active inflow occurs in the early phase of star formation, i.e., the IRDC phase rather than in the later phases. However, mass is still inflowing onto some UCHIIs. We also found that the absorption dips of the HNC spectra in 6 out of 7 blue sources are red-shifted relative to their systemic velocities. These red-shifted absorption dips may indicate global collapse candidates, although mapping observations with better resolution are needed to examine this feature in more detail.
We have observed the HN13C J=1-0 and DNC J=1-0 lines toward 18 massive clumps, including infrared dark clouds (IRDCs) and high-mass protostellar objects (HMPOs), by using the Nobeyama Radio Observatory 45 m telescope. We have found that the HN13C emission is stronger than the DNC emission toward all the observed sources. The averaged DNC/HNC ratio is indeed lower toward the observed high-mass sources (0.009pm0.005) than toward the low-mass starless and star-forming cores (0.06). The kinetic temperature derived from the NH3 (J, K) = (1, 1) and (2, 2) line intensities is higher toward the observed high-mass sources than toward the low-mass cores. However the DNC/HNC ratio of some IRDCs involving the Spitzer 24 {mu}m sources is found to be lower than that of HMPOs, although the kinetic temperature of the IRDCs is lower than that of the HMPOs. This implies that the DNC/HNC ratio does not depend only on the current kinetic temperature. With the aid of chemical model simulations, we discuss how the DNC/HNC ratio decreases after the birth of protostars. We suggest that the DNC/HNC ratio in star-forming cores depends on the physical conditions and history in their starless-core phase, such as its duration time and the gas kinetic temperature.
HNC and HCN, typically used as dense gas tracers in molecular clouds, are a pair of isomers that have great potential as a temperature probe because of temperature dependent, isomer-specific formation and destruction pathways. Previous observations of the HNC/HCN abundance ratio show that the ratio decreases with increasing temperature, something that standard astrochemical models cannot reproduce. We have undertaken a detailed parameter study on which environmental characteristics and chemical reactions affect the HNC/HCN ratio and can thus contribute to the observed dependence. Using existing gas and gas-grain models updated with new reactions and reaction barriers, we find that in static models the H + HNC gas-phase reaction regulates the HNC/HCN ratio under all conditions, except for very early times. We quantitively constrain the combinations of H abundance and H + HNC reaction barrier that can explain the observed HNC/HCN temperature dependence and discuss the implications in light of new quantum chemical calculations. In warm-up models, gas-grain chemistry contributes significantly to the predicted HNC/HCN ratio and understanding the dynamics of star formation is therefore key to model the HNC/HCN system.
We observed three high-mass star-forming regions in the W3 high-mass star formation complex with the Submillimeter Array and IRAM 30 m telescope. These regions, i.e. W3 SMS1 (W3 IRS5), SMS2 (W3 IRS4) and SMS3, are in different evolutionary stages and are located within the same large-scale environment, which allows us to study rotation and outflows as well as chemical properties in an evolutionary sense. While we find multiple mm continuum sources toward all regions, these three sub-regions exhibit different dynamical and chemical properties, which indicates that they are in different evolutionary stages. Even within each subregion, massive cores of different ages are found, e.g. in SMS2, sub-sources from the most evolved UCHII region to potential starless cores exist within 30 000 AU of each other. Outflows and rotational structures are found in SMS1 and SMS2. Evidence for interactions between the molecular cloud and the HII regions is found in the 13CO channel maps, which may indicate triggered star formation.
Aims. The comparative study of several molecular species at the origin of the gas phase chemistry in the diffuse interstellar medium (ISM) is a key input in unraveling the coupled chemical and dynamical evolution of the ISM. Methods. The lowest rotational lines of HCO+, HCN, HNC, and CN were observed at the IRAM-30m telescope in absorption against the lambda 3 mm and lambda 1.3 mm continuum emission of massive star-forming regions in the Galactic plane. The absorption lines probe the gas over kiloparsecs along these lines of sight. The excitation temperatures of HCO+ are inferred from the comparison of the absorptions in the two lowest transitions. The spectra of all molecular species on the same line of sight are decomposed into Gaussian velocity components. Most appear in all the spectra of a given line of sight. For each component, we derived the central opacity, the velocity dispersion, and computed the molecular column density. We compared our results to the predictions of UV-dominated chemical models of photodissociation regions (PDR models) and to those of non-equilibrium models in which the chemistry is driven by the dissipation of turbulent energy (TDR models). Results. The molecular column densities of all the velocity components span up to two orders of magnitude. Those of CN, HCN, and HNC are linearly correlated with each other with mean ratios N(HCN)/N(HNC) = 4.8 $pm$ 1.3 and N(CN)/N(HNC) = 34 $pm$ 12, and more loosely correlated with those of HCO+, N(HNC)/N(HCO+) = 0.5 $pm$ 0.3, N(HCN)/N(HCO+) = 1.9 $pm$ 0.9, and N(CN)/N(HCO+) = 18 $pm$ 9. These ratios are similar to those inferred from observations of high Galactic latitude lines of sight, suggesting that the gas sampled by absorption lines in the Galactic plane has the same chemical properties as that in the Solar neighbourhood. The FWHM of the Gaussian velocity components span the range 0.3 to 3 km s-1 and those of the HCO+ lines are found to be 30% broader than those of CN-bearing molecules. The PDR models fail to reproduce simultaneously the observed abundances of the CN-bearing species and HCO+, even for high-density material (100 cm-3 < nH < 104 cm-3). The TDR models, in turn, are able to reproduce the observed abundances and abundance ratios of all the analysed molecules for the moderate gas densities (30 cm-3 < nH < 200 cm-3) and the turbulent energy observed in the diffuse interstellar medium. Conclusions. Intermittent turbulent dissipation appears to be a promising driver of the gas phase chemistry of the diffuse and translucent gas throughout the Galaxy. The details of the dissipation mechanisms still need to be investigated.
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