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Register a new userHCN/HNC chemistry in shocks: a study of L1157-B1 with ASAI
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HCN and its isomer HNC play an important role in molecular cloud chemistry and the formation of more complex molecules. We investigate here the impact of protostellar shocks on the HCN and HNC abundances from high-sensitivity IRAM 30m observations of the prototypical shock region L1157-B1 and the envelope of the associated Class 0 protostar, as a proxy for the pre-shock gas. The isotopologues H$^{12}$CN, HN$^{12}$C, H$^{13}$CN, HN$^{13}$C, HC$^{15}$N, H$^{15}$NC, DCN and DNC were all detected towards both regions. Abundances and excitation conditions were obtained from radiative transfer analysis of molecular line emission under the assumption of Local Thermodynamical Equilibrium. In the pre-shock gas, the abundances of the HCN and HNC isotopologues are similar to those encountered in dark clouds, with a HCN/HNC abundance ratio $approx 1$ for all isotopologues. A strong D-enrichment (D/H$approx 0.06$) is measured in the pre-shock gas. There is no evidence of $^{15}$N fractionation neither in the quiescent nor in the shocked gas. At the passage of the shock, the HCN and HNC abundances increase in the gas phase in different manners so that the HCN/HNC relative abundance ratio increases by a factor 20. The gas-grain chemical and shock model UCLCHEM allows us to reproduce the observed trends for a C-type shock with pre-shock density $n$(H)= $10^5$cm$^{-3}$ and shock velocity $V_s= 40$km/s. We conclude that the HCN/HNC variations across the shock are mainly caused by the sputtering of the grain mantle material in relation with the history of the grain ices.
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We present here a systematic search for cyanopolyynes in the shock region L1157-B1 and its associated protostar L1157-mm in the framework of the Large Program Astrochemical Surveys At IRAM (ASAI), dedicated to chemical surveys of solar-type star forming regions with the IRAM 30m telescope. Observations of the millimeter windows between 72 and 272 GHz permitted the detection of HC$_3$N and its $^{13}$C isotopologues, and HC$_5$N (for the first time in a protostellar shock region). In the shock, analysis of the line profiles shows that the emission arises from the outflow cavities associated with L1157-B1 and L1157-B2. Molecular abundances and excitation conditions were obtained from analysis of the Spectral Line Energy Distributions under the assumption of Local Thermodynamical Equilibrium or using a radiative transfer code in the Large Velocity Gradient approximation. Towards L1157mm, the HC$_3$N emission arises from the cold envelope ($T_{rot}=10$ K) and a higher-excitation region ($T_{rot}$= $31$ K) of smaller extent around the protostar. We did not find any evidence of $^{13}$C or D fractionation enrichment towards L1157-B1. We obtain a relative abundance ratio HC$_3$N/HC$_5$N of 3.3 in the shocked gas. We find an increase by a factor of 30 of the HC$_3$N abundance between the envelope of L1157-mm and the shock region itself. Altogether, these results are consistent with a scenario in which the bulk of HC$_3$N was produced by means of gas phase reactions in the passage of the shock. This scenario is supported by the predictions of a parametric shock code coupled with the chemical model UCL_CHEM.
L1157-B1 is one of the outflow shocked regions along the blue-shifted outflow driven by the Class 0 protostar L1157-mm, and is an ideal laboratory to study the material ejected from the grains in very short timescales, i.e. its chemical composition is representative of the composition of the grains. We imaged $^{28}$SiO, $^{29}$SiO and $^{30}$SiO J = 2-1 emission towards L1157-B1 and B0 with the NOrthern Extended Millimeter Array (NOEMA) interferometer as part of the Seeds of Life in Space (SOLIS) large project. We present here a study of the isotopic fractionation of SiO towards L1157-B1. Furthermore, we use the high spectral resolution observations on the main isotopologue, $^{28}$SiO, to study the jet impact on the dense gas. We present here also single-dish observations obtained with the IRAM 30m telescope and Herschel-HIFI. We carried out a non-LTE analysis using a Large Velocity Gradient (LVG) code to model the single-dish observations. From our observations we can show that (i) the (2-1) transition of the main isotopologue is optically thick in L1157-B1 even at high velocities, and (ii) the [$^{29}$SiO/$^{30}$SiO] ratio is constant across the source, and consistent with the solar value of 1.5. We report the first isotopic fractionation maps of SiO in a shocked region and show the absence of a mass dependent fractionation in $^{29}$Si and $^{30}$Si across L1157-B1. A high-velocity bullet in $^{28}$SiO has been identified, showing the signature of a jet impacting on the dense gas. With the dataset presented in this paper, both interferometric and single-dish, we were able to study in great detail the gas shocked at the B1a position and its surrounding gas.
Interstellar molecules with a peptide link -NH-C(=O)-, like formamide (NH$_2$CHO), acetamide (NH$_2$COCH$_3$) and isocyanic acid (HNCO) are particularly interesting for their potential role in pre-biotic chemistry. We have studied their emission in the protostellar shock regions L1157-B1 and L1157-B2, with the IRAM 30m telescope, as part of the ASAI Large Program. Analysis of the line profiles shows that the emission arises from the outflow cavities associated with B1 and B2. Molecular abundance of $approx~(0.4-1.1)times 10^{-8}$ and $(3.3-8.8)times 10^{-8}$ are derived for formamide and isocyanic acid, respectively, from a simple rotational diagram analysis. Conversely, NH$_2$COCH$_3$ was not detected down to a relative abundance of a few $leq 10^{-10}$. B1 and B2 appear to be among the richest Galactic sources of HNCO and NH$_2$CHO molecules. A tight linear correlation between their abundances is observed, suggesting that the two species are chemically related. Comparison with astrochemical models favours molecule formation on ice grain mantles, with NH$_2$CHO generated from hydrogenation of HNCO.
HNC and HCN, typically used as dense gas tracers in molecular clouds, are a pair of isomers that have great potential as a temperature probe because of temperature dependent, isomer-specific formation and destruction pathways. Previous observations of the HNC/HCN abundance ratio show that the ratio decreases with increasing temperature, something that standard astrochemical models cannot reproduce. We have undertaken a detailed parameter study on which environmental characteristics and chemical reactions affect the HNC/HCN ratio and can thus contribute to the observed dependence. Using existing gas and gas-grain models updated with new reactions and reaction barriers, we find that in static models the H + HNC gas-phase reaction regulates the HNC/HCN ratio under all conditions, except for very early times. We quantitively constrain the combinations of H abundance and H + HNC reaction barrier that can explain the observed HNC/HCN temperature dependence and discuss the implications in light of new quantum chemical calculations. In warm-up models, gas-grain chemistry contributes significantly to the predicted HNC/HCN ratio and understanding the dynamics of star formation is therefore key to model the HNC/HCN system.
Aims. The comparative study of several molecular species at the origin of the gas phase chemistry in the diffuse interstellar medium (ISM) is a key input in unraveling the coupled chemical and dynamical evolution of the ISM. Methods. The lowest rotational lines of HCO+, HCN, HNC, and CN were observed at the IRAM-30m telescope in absorption against the lambda 3 mm and lambda 1.3 mm continuum emission of massive star-forming regions in the Galactic plane. The absorption lines probe the gas over kiloparsecs along these lines of sight. The excitation temperatures of HCO+ are inferred from the comparison of the absorptions in the two lowest transitions. The spectra of all molecular species on the same line of sight are decomposed into Gaussian velocity components. Most appear in all the spectra of a given line of sight. For each component, we derived the central opacity, the velocity dispersion, and computed the molecular column density. We compared our results to the predictions of UV-dominated chemical models of photodissociation regions (PDR models) and to those of non-equilibrium models in which the chemistry is driven by the dissipation of turbulent energy (TDR models). Results. The molecular column densities of all the velocity components span up to two orders of magnitude. Those of CN, HCN, and HNC are linearly correlated with each other with mean ratios N(HCN)/N(HNC) = 4.8 $pm$ 1.3 and N(CN)/N(HNC) = 34 $pm$ 12, and more loosely correlated with those of HCO+, N(HNC)/N(HCO+) = 0.5 $pm$ 0.3, N(HCN)/N(HCO+) = 1.9 $pm$ 0.9, and N(CN)/N(HCO+) = 18 $pm$ 9. These ratios are similar to those inferred from observations of high Galactic latitude lines of sight, suggesting that the gas sampled by absorption lines in the Galactic plane has the same chemical properties as that in the Solar neighbourhood. The FWHM of the Gaussian velocity components span the range 0.3 to 3 km s-1 and those of the HCO+ lines are found to be 30% broader than those of CN-bearing molecules. The PDR models fail to reproduce simultaneously the observed abundances of the CN-bearing species and HCO+, even for high-density material (100 cm-3 < nH < 104 cm-3). The TDR models, in turn, are able to reproduce the observed abundances and abundance ratios of all the analysed molecules for the moderate gas densities (30 cm-3 < nH < 200 cm-3) and the turbulent energy observed in the diffuse interstellar medium. Conclusions. Intermittent turbulent dissipation appears to be a promising driver of the gas phase chemistry of the diffuse and translucent gas throughout the Galaxy. The details of the dissipation mechanisms still need to be investigated.
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