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Register a new userPath integral approach to the calculation of the characteristic function of work
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Work statistics characterizes important features of a non-equilibrium thermodynamic process. But the calculation of the work statistics in an arbitrary non-equilibrium process is usually a cumbersome task. In this work, we study the work statistics in quantum systems by employing Feynmans path-integral approach. We derive the analytical work distributions of two prototype quantum systems. The results are proved to be equivalent to the results obtained based on Schr{o}dingers formalism. We also calculate the work distributions in their classical counterparts by employing the path-integral approach. Our study demonstrates the effectiveness of the path-integral approach to the calculation of work statistics in both quantum and classical thermodynamics, and brings important insights to the understanding of the trajectory work in quantum systems.
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We study conformations of the Gaussian polymer chains in d-dimensional space in the presence of an external field with the harmonic potential. We apply a path integral approach to derive an explicit expression for the probability distribution function of the gyration radius. We calculate this function using Monte Carlo simulations and show that our numerical and theoretical results are in a good agreement for different values of the external field.
For a system of bosons that interact through a class of general memory kernels, a recurrence relation for the partition function is derived within the path-integral formalism. This approach provides a generalization to previously known treatments in the literature of harmonically coupled systems of identical particles. As an example the result is applied to the specific heat of a simplified model of an open quantum system of bosons, harmonically coupled to a reservoir of distinguishable fictitious masses.
The local quench of a Fermi gas, giving rise to the Fermi edge singularity and the Anderson orthogonality catastrophe, is a rare example of an analytically tractable out of equilibrium problem in condensed matter. It describes the universal physics which occurs when a localized scattering potential is suddenly introduced in a Fermi sea leading to a brutal disturbance of the quantum state. It has recently been proposed that the effect could be efficiently simulated in a controlled manner using the tunability of ultra-cold atoms. In this work, we analyze the quench problem in a gas of trapped ultra-cold fermions from a thermodynamic perspective using the full statistics of the so called work distribution. The statistics of work are shown to provide an accurate insight into the fundamental physics of the process.
We develop an approach of calculating the many-body path integral based on the linked cluster expansion method. First, we derive a linked cluster expansion and we give the diagrammatic rules for calculating the free-energy and the pair distribution function $g(r)$ as a systematic power series expansion in the particle density. We also generalize the hypernetted-chain (HNC) equation for $g(r)$, known from its application to classical statistical mechanics, to a set of quantum HNC equations (QHNC) for the quantum case. The calculated $g(r)$ for distinguishable particles interacting with a Lennard-Jones potential in various attempted schemes of approximation of the diagrammatic series compares very well with the results of path integral Monte Carlo simulation even for densities as high as the equilibrium density of the strongly correlated liquid $^4$He. Our method is applicable to a wide range of problems of current general interest and may be extended to the case of identical particles and, in particular, to the case of the many-fermion problem.
Recent work by Teifel and Mahler [Eur. Phys. J. B 75, 275 (2010)] raises legitimate concerns regarding the validity of quantum nonequilibrium work relations in processes involving moving hard walls. We study this issue in the context of the rapidly expanding one-dimensional quantum piston. Utilizing exact solutions of the time-dependent Schru007fodinger equation, we find that the evolution of the wave function can be decomposed into static and dynamic components, which have simple semiclassical interpretations in terms of particle-piston collisions. We show that nonequilibrium work relations remains valid at any finite piston speed, provided both components are included, and we study explicitly the work distribution for this model system.
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