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Register a new userRotational and rotational-vibrational Raman spectroscopy of air to characterize astronomical spectrographs
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Added by
Fr\\'ed\\'eric P.A. Vogt
Publication date
2019
fields
Physics
and research's language is
English
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Raman scattering enables unforeseen uses for the laser guide-star system of the Very Large Telescope. Here, we present the observation of one up-link sodium laser beam acquired with the ESPRESSO spectrograph at a resolution $lambda/Deltalambda sim 140000$. In 900s on-source, we detect the pure rotational Raman lines of $^{16}$O$_2$, $^{14}$N$_2$, and $^{14}$N$^{15}$N (tentatively) up to rotational quantum numbers $J$ of 27, 24, and 9, respectively. We detect the $^{16}$O$_2$ fine-structure lines induced by the interaction of the electronic spin textbf{S} and end-over-end rotational angular momentum textbf{N} in the electronic ground state of this molecule up to $N=9$. The same spectrum also reveals the $ u_{1leftarrow0}$ rotational-vibrational Q-branch for $^{16}$O$_2$ and $^{14}$N$_2$. These observations demonstrate the potential of using laser guide-star systems as accurate calibration sources for characterizing new astronomical spectrographs.
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(Abr.) Laser guide stars employed at astronomical observatories provide artificial wavefront reference sources to help correct (in part) the impact of atmospheric turbulence on astrophysical observations. Following the recent commissioning of the 4 Laser Guide Star Facility (4LGSF) on UT4 at the VLT, we characterize the spectral signature of the uplink beams from the 22W lasers to assess the impact of laser scattering from the 4LGSF on science observations. We use the MUSE optical integral field spectrograph to acquire spectra at a resolution of R~3000 of the uplink laser beams over the wavelength range of 4750AA to 9350AA. We report the first detection of laser-induced Raman scattering by N2, O2, CO2, H2O and (tentatively) CH4 molecules in the atmosphere above the astronomical observatory of Cerro Paranal. In particular, our observations reveal the characteristic spectral signature of laser photons -- but 480AA to 2210AA redder than the original laser wavelength of 5889.959AA -- landing on the 8.2m primary mirror of UT4 after being Raman-scattered on their way up to the sodium layer. Laser-induced Raman scattering is not unique to the observatory of Cerro Paranal, but common to any astronomical telescope employing a laser-guide-star (LGS) system. It is thus essential for any optical spectrograph coupled to a LGS system to handle thoroughly the possibility of a Raman spectral contamination via a proper baffling of the instrument and suitable calibrations procedures. These considerations are particularly applicable for the HARMONI optical spectrograph on the upcoming Extremely Large Telescope. At sites hosting multiple telescopes, laser collision prediction tools also ought to account for the presence of Raman emission from the uplink laser beam(s) to avoid the unintentional contamination of observations acquired with telescopes in the vicinity of a LGS system.
With the aim of utilizing arrayed waveguide gratings for multi-object spectroscopy in the field of astronomy, we outline several ways in which standard telecommunications grade chips should be modified. In particular, by removing the parabolic-horn taper or multimode interference coupler, and injecting with an optical fiber directly, the resolving power was increased threefold from 2400 pm 200 (spectral resolution of 0.63 pm 0.2 nm) to 7000 pm 700 (0.22 pm 0.02 nm) while attaining a throughput of 77 pm 5%. More importantly, the removal of the taper enabled simultaneous off-axis injection from multiple fibers, significantly increasing the number of spectra that can be obtained at once (i.e. the observing efficiency). Here we report that ~ 12 fibers can be injected simultaneously within the free spectral range of our device, with a 20% reduction in resolving power for fibers placed at 0.8 mm off centre.
We report the gas-phase detection and spectroscopic characterization of ethynethiol ($mathrm{HCCSH}$), a metastable isomer of thioketene ($mathrm{H_2C_2S}$) using a combination of Fourier-transform microwave and submillimeter-wave spectroscopies. Several $a$-type transitions of the normal species were initially detected below 40 GHz using a supersonic expansion-electrical discharge source, and subsequent measurement of higher-frequency, $b$-type lines using double resonance provided accurate predictions in the submillimeter region. With these, searches using a millimeter-wave absorption spectrometer equipped with a radio frequency discharge source were conducted in the range 280 - 660 GHz, ultimately yielding nearly 100 transitions up to $^rR_0(36)$ and $^rQ_0(68)$. From the combined data set, all three rotational constants and centrifugal distortion terms up to the sextic order were determined to high accuracy, providing a reliable set of frequency predictions to the lower end of the THz band. Isotopic substitution has enabled both a determination of the molecular structure of $mathrm{HCCSH}$ and, by inference, its formation pathway in our nozzle discharge source via the bimolecular radical-radical recombination reaction $mathrm{SH + C_2H}$, which is calculated to be highly exothermic (-477 kJ/mol) using the HEAT345(Q) thermochemical scheme.
Tidally locked exoplanets likely host global atmospheric circulations with a superrotating equatorial jet, planetary-scale stationary waves and thermally-driven overturning circulation. In this work, we show that each of these features can be separated from the total circulation by using a Helmholtz decomposition, which splits the circulation into rotational (divergence free) and divergent (vorticity free) components. This technique is applied to the simulated circulation of a terrestrial planet and a gaseous hot Jupiter. For both planets, the rotational component comprises the equatorial jet and stationary waves, and the divergent component contains the overturning circulation. Separating out each component allows us to evaluate their spatial structure and relative contribution to the total flow. In contrast with previous work, we show that divergent velocities are not negligible when compared with rotational velocities, and that divergent, overturning circulation takes the form of a single, roughly isotropic cell that ascends on the day-side and descends on the night-side. These conclusions are drawn for both the terrestrial case and the hot Jupiter. To illustrate the utility of the Helmholtz decomposition for studying atmospheric processes, we compute the contribution of each of the circulation components to heat transport from day- to night-side. Surprisingly, we find that the divergent circulation dominates day-night heat transport in the terrestrial case and accounts for around half of the heat transport for the hot Jupiter. The relative contributions of the rotational and divergent components to day-night heat transport are likely sensitive to multiple planetary parameters and atmospheric processes, and merit further study.
Optical spectroscopy techniques such as differential reflectance and transmittance have proven to be very powerful techniques to study 2D materials. However, a thorough description of the experimental setups needed to carry out these measurements is lacking in the literature. We describe a versatile optical microscope setup to carry out differential reflectance and transmittance spectroscopy in 2D materials with a lateral resolution of ~1 micron in the visible and near-infrared part of the spectrum. We demonstrate the potential of the presented setup to determine the number of layers of 2D materials and to characterize their fundamental optical properties such as excitonic resonances. We illustrate its performance by studying mechanically exfoliated and chemical vapor-deposited transition metal dichalcogenide samples.
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