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Characterization of YbNi$_4$(P$_{1-{it x}}$As$_{it x}$)$_2$, $x = 0, 0.2$ single crystals grown by Czochralski method

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 Added by Kristin Kliemt
 Publication date 2016
  fields Physics
and research's language is English




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We have investigated large single crystals of YbNi$_4$P$_2$ that were grown from a levitating melt by the Czochralski method. The new samples facilitate the determination of the absolute values of the electrical resistivity. Phase pure polycrystalline samples of the non-magnetic reference LuNi$_4$P$_2$ were prepared and the electrical resistivity was measured. Furthermore we have grown a single crystal of the As substituted compound YbNi$_4$(P$_{1-{it x}}$As$_{it x}$)$_2$, $x = 0.2$ and investigated the homogenity of the As distribution.



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The tetragonal YbNi$_4$P$_2$ is one of the rare examples of compounds that allow the investigation of a ferromagnetic quantum critical point. We report in detail on two different methods which have been used to grow YbNi$_4$P$_2$ single crystals from a self-flux. The first, a modified Bridgman method, using a closed crucible system yields needle-shaped single crystals oriented along the $[001]$-direction. The second method, the Czochralski growth from a levitating melt, yields large single crystals which can be cut in any desired orientation. With this crucible-free method, samples without flux inclusions and a resistivity ratio at 1.8 K of RR$_{1.8rm K}= 17$ have been grown.
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