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Register a new userPhase-feld theory of multi-component incompressible Cahn-Hilliard liquids
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In this paper a generalization of the Cahn-Hilliard theory of binary liquids is presented for multi-component incompressible liquid mixtures. First, a thermodynamically consistent convection-diffusion type dynamics is derived on the basis of the Lagrange multiplier formalism. Next, a generalization of the binary Cahn-Hilliard free energy functional is presented for arbitrary number of components, offering the utilization of independent pairwise equilibrium interfacial properties. We show that the equilibrium two-component interfaces minimize the functional, and demonstrate, that the energy penalization for multi-component states increases strictly monotonously as a function of the number of components being present. We validate the model via equilibrium contact angle calculations in ternary and quaternary (4-component) systems. Simulations addressing liquid flow assisted spinodal decomposition in these systems are also presented.
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During phase transitions certain properties of a material change, such as composition field and lattice-symmetry distortions. These changes are typically coupled, and affect the microstructures that form in materials. Here, we propose a 2D theoretical framework that couples a Cahn-Hilliard (CH) model describing the composition field of a material system, with a phase field crystal (PFC) model describing its underlying microscopic configurations. We couple the two continuum models via coordinate transformation coefficients. We introduce the transformation coefficients in the PFC method, to describe affine lattice deformations. These transformation coefficients are modeled as functions of the composition field. Using this coupled approach, we explore the effects of coarse-grained lattice symmetry and distortions on a phase transition process. In this paper, we demonstrate the working of the CH-PFC model through three representative examples: First, we describe base cases with hexagonal and square lattice symmetries for two composition fields. Next, we illustrate how the CH-PFC method interpolates lattice symmetry across a diffuse composition phase boundary. Finally, we compute a Cahn-Hilliard type of diffusion and model the accompanying changes to lattice symmetry during a phase transition process.
Pair interactions between active particles need not follow Newtons third law. In this work we propose a continuum model of pattern formation due to non-reciprocal interaction between multiple species of scalar active matter. The classical Cahn-Hilliard model is minimally modified by supplementing the equilibrium Ginzburg-Landau dynamics with particle number conserving currents which cannot be derived from a free energy, reflecting the microscopic departure from action-reaction symmetry. The strength of the asymmetry in the interaction determines whether the steady state exhibits a macroscopic phase separation or a traveling density wave displaying global polar order. The latter structure, which is equivalent to an active self-propelled smectic phase, coarsens via annihilation of defects, whereas the former structure undergoes Ostwald ripening. The emergence of traveling density waves, which is a clear signature of broken time-reversal symmetry in this active system, is a generic feature of any multi-component mixture with microscopic non-reciprocal interactions.
The Cahn--Hilliard equation is a classic model of phase separation in binary mixtures that exhibits spontaneous coarsening of the phases. We study the Cahn--Hilliard equation with an imposed advection term in order to model the stirring and eventual mixing of the phases. The main result is that if the imposed advection is sufficiently mixing then no phase separation occurs, and the solution instead converges exponentially to a homogeneous mixed state. The mixing effectiveness of the imposed drift is quantified in terms of the dissipation time of the associated advection-hyperdiffusion equation, and we produce examples of velocity fields with a small dissipation time. We also study the relationship between this quantity and the dissipation time of the standard advection-diffusion equation.
We extend the early time ordering theory of Cahn, Hilliard, and Cook (CHC) so that our generalized theory applies to solid-to-solid transitions. Our theory involves spatial symmetry breaking (the initial phase contains a symmetry not present in the final phase). The predictions of our generalization differ from those of the CHC theory in two important ways: exponential growth does not begin immediately following the quench, and the objects that grow exponentially are not necessarily Fourier modes. Our theory is consistent with simulation results for the long-range antiferromagnetic Ising model.
The phase separation of an isothermal incompressible binary fluid in a porous medium can be described by the so-called Brinkman equation coupled with a convective Cahn-Hilliard (CH) equation. The former governs the average fluid velocity $mathbf{u}$, while the latter rules evolution of $varphi$, the difference of the (relative) concentrations of the two phases. The two equations are known as the Cahn-Hilliard-Brinkman (CHB) system. In particular, the Brinkman equation is a Stokes-like equation with a forcing term (Korteweg force) which is proportional to $mu ablavarphi$, where $mu$ is the chemical potential. When the viscosity vanishes, then the system becomes the Cahn-Hilliard-Hele-Shaw (CHHS) system. Both systems have been studied from the theoretical and the numerical viewpoints. However, theoretical results on the CHHS system are still rather incomplete. For instance, uniqueness of weak solutions is unknown even in 2D. Here we replace the usual CH equation with its physically more relevant nonlocal version. This choice allows us to prove more about the corresponding nonlocal CHHS system. More precisely, we first study well-posedness for the CHB system, endowed with no-slip and no-flux boundary conditions. Then, existence of a weak solution to the CHHS system is obtained as a limit of solutions to the CHB system. Stronger assumptions on the initial datum allow us to prove uniqueness for the CHHS system. Further regularity properties are obtained by assuming additional, though reasonable, assumptions on the interaction kernel. By exploiting these properties, we provide an estimate for the difference between the solution to the CHB system and the one to the CHHS system with respect to viscosity.
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