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Register a new userPhase separation in the advective Cahn-Hilliard equation
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The Cahn--Hilliard equation is a classic model of phase separation in binary mixtures that exhibits spontaneous coarsening of the phases. We study the Cahn--Hilliard equation with an imposed advection term in order to model the stirring and eventual mixing of the phases. The main result is that if the imposed advection is sufficiently mixing then no phase separation occurs, and the solution instead converges exponentially to a homogeneous mixed state. The mixing effectiveness of the imposed drift is quantified in terms of the dissipation time of the associated advection-hyperdiffusion equation, and we produce examples of velocity fields with a small dissipation time. We also study the relationship between this quantity and the dissipation time of the standard advection-diffusion equation.
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Experiments with diblock co-polymer melts display undulated bilayers that emanate from defects such as triple junctions and endcaps, cite{batesjain_2004}. Undulated bilayers are characterized by oscillatory perturbations of the bilayer width, which decay on a spatial length scale that is long compared to the bilayer width. We mimic defects within the functionalized Cahn-Hillard free energy by introducing spatially localized inhomogeneities within its parameters. For length parameter $varepsilonll1$, we show that this induces undulated bilayer solutions whose width perturbations decay on an $O!left(varepsilon^{-1/2}right)$ inner length scale that is long in comparison to the $O(1)$ scale that characterizes the bilayer width.
P. Galenko et al. proposed a modified Cahn-Hilliard equation to model rapid spinodal decomposition in non-equilibrium phase separation processes. This equation contains an inertial term which causes the loss of any regularizing effect on the solutions. Here we consider an initial and boundary value problem for this equation in a two-dimensional bounded domain. We prove a number of results related to well-posedness and large time behavior of solutions. In particular, we analyze the existence of bounded absorbing sets in two different phase spaces and, correspondingly, we establish the existence of the global attractor. We also demonstrate the existence of an exponential attractor.
We consider a Cahn-Hilliard equation which is the conserved gradient flow of a nonlocal total free energy functional. This functional is characterized by a Helmholtz free energy density, which can be of logarithmic type. Moreover, the spatial interactions between the different phases are modeled by a singular kernel. As a consequence, the chemical potential $mu$ contains an integral operator acting on the concentration difference $c$, instead of the usual Laplace operator. We analyze the equation on a bounded domain subject to no-flux boundary condition for $mu$ and by assuming constant mobility. We first establish the existence and uniqueness of a weak solution and some regularity properties. These results allow us to define a dissipative dynamical system on a suitable phase-space and we prove that such a system has a (connected) global attractor. Finally, we show that a Neumann-like boundary condition can be recovered for $c$, provided that it is supposed to be regular enough.
We give a detailed study of the infinite-energy solutions of the Cahn-Hilliard equation in the 3D cylindrical domains in uniformly local phase space. In particular, we establish the well-posedness and dissipativity for the case of regular potentials of arbitrary polynomial growth as well as for the case of sufficiently strong singular potentials. For these cases, we prove the further regularity of solutions and the existence of a global attractor. For the cases where we have failed to prove the uniqueness (e.g., for the logarithmic potentials), we establish the existence of the trajectory attractor and study its properties.
The functionalized Cahn-Hilliard (FCH) equation supports planar and circular bilayer interfaces as equilibria which may lose their stability through the pearling bifurcation: a periodic, high-frequency, in-plane modulation of the bilayer thickness. In two spatial dimensions we employ spatial dynamics and a center manifold reduction to reduce the FCH equation to an 8th order ODE system. A normal form analysis and a fixed-point-theorem argument show that the reduced system admits a degenerate 1:1 resonant normal form, from which we deduce that the onset of the pearling bifurcation coincides with the creation of a two-parameter family of pearled equilibria which are periodic in the in-plane direction and exponentially localized in the transverse direction.
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