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Register a new userMechanism of spin crossover in LaCoO3 resolved by shape magnetostriction in pulsed magnetic fields
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In the scientific description of unconventional transport properties of oxides (spin-dependent transport, superconductivity etc.), the spin-state degree of freedom plays a fundamental role. Because of this, temperature- or magnetic field-induced spin-state transitions are in the focus of solid-state physics. Cobaltites, e.g. LaCoO3, are prominent examples showing these spin transitions. However, the microscopic nature of the spontaneous spin crossover in LaCoO3 is still controversial. Here we report magnetostriction measurements on LaCoO3 in magnetic fields up to 70 T to study the sharp, field-induced transition at Hc ~ 60 T. Measurements of both longitudinal and transversal magnetostriction allow us to separate magnetovolume and magnetodistortive changes. We find a large increase in volume, but only a very small increase in tetragonal distortion at Hc. The results, supported by electronic energy calculations by the configuration interaction cluster method, provide compelling evidence that above Hc LaCoO3 adopts a correlated low spin/high spin state.
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We present a high resolution method for measuring magnetostriction in millisecond pulsed magnetic fields at cryogenic temperatures with a sensitivity of $1.11times10^{-11}/sqrt{rm Hz}$. The sample is bonded to a thin piezoelectric plate, such that when the samples length changes, it strains the piezoelectric and induces a voltage change. This method is more sensitive than a fiber-Bragg grating method. It measures two axes simultaneously instead of one. The gauge is small and versatile, functioning in DC and millisecond pulsed magnetic fields. We demonstrate its use by measuring the magnetostriction of Ca$_3$Co$_{1.03}$Mn$_{0.97}$O$_6$ single crystals in pulsed magnetic fields. By comparing our data to new and previously published results from a fiber-Bragg grating magnetostriction setup, we confirm that this method detects magnetostriction effects. We also demonstrate the small size and versatility of this technique by measuring angle dependence with respect to the applied magnetic field in a rotator probe in 65 T millisecond pulsed magnetic fields.
Single shot x-ray diffraction (XRD) experiments have been performed with a x-ray free electron laser (XFEL) under pulsed high magnetic fields up to 16 T generated with a nondestructive minicoil. The antiferromagnetic insulator phase in a perovskite manganaite, Pr$_{0.6}$Ca$_{0.4}$MnO$_{3}$, is collapsed at a magnetic field of $approx 8$ T with an emergence of the ferromagnetic metallic phase, which is observed via the accompanying lattice changes in a series of the single shot XRD. The feasibility of the single shot XRD experiment under ultrahigh magnetic fields beyond 100 T is discussed, which is generated with a portable destructive pulse magnet.
In spin-density-functional theory for noncollinear magnetic materials, the Kohn-Sham system features exchange-correlation (xc) scalar potentials and magnetic fields. The significance of the xc magnetic fields is not very well explored; in particular, they can give rise to local torques on the magnetization, which are absent in standard local and semilocal approximations. We obtain exact benchmark solutions for two electrons on four-site extended Hubbard lattices over a wide range of interaction strengths, and compare exact xc potentials and magnetic fields with approximations obtained from orbital-dependent xc functionals. The xc magnetic fields turn out to play an increasingly important role as systems becomes more and more correlated and the electrons begin to localize; the effects of the xc torques, however, remain relatively minor. The approximate xc functionals perform overall quite well, but tend to favor symmetry-broken solutions for strong interactions.
We report on a new high resolution apparatus for measuring magnetostriction suitable for use at cryogenic temperatures in pulsed high magnetic fields which we have developed at the Hochfeld-Magnetlabor Dresden. Optical fibre strain gauges based on Fibre Bragg Gratings are used to measure the strain in small (~1mm) samples. We describe the implementation of a fast measurement system capable of resolving strains in the order of $10^{-7}$ with a full bandwidth of 47kHz, and demonstrate its use on single crystal samples of GdSb and GdSi.
We here report magnetostriction measurements under pulsed megagauss fields using a high-speed 100 MHz strain monitoring system devised using fiber Bragg grating (FBG) technique with optical filter method. The optical filter method is a detection scheme of the strain of FBG, where the changing Bragg wavelength of the FBG reflection is converted to the intensity of reflected light to enable the 100 MHz measurement. In order to show the usefulness and reliability of the method, we report the measurements for solid oxygen, spin-controlled crystal, and volborthite, a deformed Kagom{e} quantum spin lattice, using static magnetic fields up to 7 T and non-destructive millisecond pulse magnets up to 50 T. Then, we show the application of the method for the magnetostriction measurements of CaV$_{4}$O$_{9}$, a two-dimensional antiferromagnet with spin-halves, and LaCoO$_{3}$, an anomalous spin-crossover oxide, in the megagauss fields.
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