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No-pumping theorem for many particle stochastic pumps

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 Added by Shahaf Asban SA
 Publication date 2013
  fields Physics
and research's language is English




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Stochastic pumps are models of artificial molecular machines which are driven by periodic time variation of parameters, such as site and barrier energies. The no-pumping theorem states that no directed motion is generated by variation of only site or barrier energies [S. Rahav, J. Horowitz, and C. Jarzynski, Phys. Rev. Lett., 101, 140602 (2008)]. We study stochastic pumps of several interacting particles and demonstrate that the net current of particles satisfy an additional no- pumping theorem.



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We analyze the operation of a molecular machine driven by the non-adiabatic variation of external parameters. We derive a formula for the integrated flow from one configuration to another, obtain a no-pumping theorem for cyclic processes with thermally activated transitions, and show that in the adiabatic limit the pumped current is given by a geometric expression.
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The no-pumping theorem states that seemingly natural driving cycles of stochastic machines fail to generate directed motion. Initially derived for single particle systems, the no-pumping theorem was recently extended to many-particle systems with zero-range interactions. Interestingly, it is known that the theorem is violated by systems with exclusion interactions. These two paradigmatic interactions differ by two qualitative aspects: the range of interactions, and the dependence of branching fractions on the state of the system. In this work two different models are studied in order to identify the qualitative property of the interaction that leads to breakdown of no-pumping. A model with finite-range interaction is shown analytically to satisfy no-pumping. In contrast, a model in which the interaction affects the probabilities of reaching different sites, given that a particle is making a transition, is shown numerically to violate the no-pumping theorem. The results suggest that systems with interactions that lead to state-dependent branching fractions do not satisfy the no-pumping theorem.
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