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Register a new userUpper limits for undetected trace species in the stratosphere of Titan
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In this paper we describe a first quantitative search for several molecules in Titans stratosphere in Cassini CIRS infrared spectra. These are: ammonia (NH3), methanol (CH3OH), formaldehyde (H2CO), and acetonitrile (CH3CN), all of which are predicted by photochemical models but only the last of which observed, and not in the infrared. We find non-detections in all cases, but derive upper limits on the abundances from low-noise observations at 25{deg}S and 75{deg}N. Comparing these constraints to model predictions, we conclude that CIRS is highly unlikely to see NH3 or CH3OH emissions. However, CH3CN and H2CO are closer to CIRS detectability, and we suggest ways in which the sensitivity threshold may be lowered towards this goal.
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Aims: We investigate the composition of Titans stratosphere from new medium-resolution far-infrared observations performed with the full range of Herschels Photodetector Array Camera and Spectrometer (PACS) (51-220 $mu$m at a resolution $lambda$/$Delta lambda$ ranging from 950 to 5500 depending on wavelength and grating order). Methods: Using PACS, we obtained the spectral emission of several features of the Titans stratosphere. We used a line-by-line radiative transfer code and the least-squares fitting technique to infer the abundances of the trace constituents. Results: Numerous spectral features attributable to CH$_4$, CO, HCN, and H$_2$O are present. From the flux density spectrum measured and by a detailed comparison with synthetic spectra, we constrain the stratospheric abundance of CH4, which is assumed to be constant with altitude, to be 1.29 $pm$ 0.03%. Similarly, we constrain the abundance of CO to be 50 $pm$ 2 ppm, and the HCN vertical distribution consistent with an increase from 40 ppb at $sim$100 km to 4 ppm at $sim$200 km, which is an altitude region where the HCN signatures are sensitive. Measurements of three H$_2$O rotational lines confirm the H$_2$O distribution profile recently obtained with Herschel. Furthermore, we determine the isotopic ratios $^{12}$C/$^{13}$C in CO and HCN to be 124 $pm$ 58, and 66 $pm$ 35, respectively. Comparisons between our results and the values derived with other instruments show that our results are consistent with the vertical distributions and isotopic ratios in previous studies, except for the HCN distribution obtained with Cassini/CIRS, which does not agree with the PACS lines at the 1-sigma confidence interval.
In this chapter we describe the remote sensing measurement of nitrogen-bearing species in Titans atmosphere by the Composite Infrared Spectrometer (CIRS) on the Cassini spacecraft. This instrument, which detects the thermal infrared spectrum from 10-1500 cm-1 (1000-7 microns) is sensitive to vibrational emissions of gases and condensates in Titans stratosphere and lower mesosphere, permitting the measurement of ambient temperature and the abundances of gases and particulates. Three N-bearing species are firmly detected: HCN, HC3N and C2N2, and their vertical and latitudinal distributions have been mapped. In addition, ices of HC3N and possibly C4N2 are also seen in the far-infrared spectrum at high latitudes during the northern winter. The HC(15)N isotopologue has been measured, permitting the inference of the 14N/15N ratio in this species, which differs markedly (lower) than in the bulk nitrogen reservoir (N2). We also describe the search in the CIRS spectrum, and inferred upper limits, for NH3 and CH3CN. CIRS is now observing seasonal transition on Titan and the gas abundance distributions are changing accordingly, acting as tracers of the changing atmospheric circulation. The prospects for further CIRS science in the remaining five years of the Cassini mission are discussed.
The Cassini/Composite InfraRed Spectrometer (CIRS) instrument has been observing the middle atmosphere of Titan over almost half a Saturnian year. We used the CIRS dataset processed through the up-to-date calibration pipeline to characterize seasonal changes of temperature and abundance profiles in the middle atmosphere of Titan, from mid-northern winter to early northern summer all around the satellite. We used limb spectra from 590 to 1500 cm$^{-1}$ at 0.5-cm$^{-1}$ spectral resolution, which allows us to probe different altitudes. We averaged the limb spectra recorded during each flyby on a fixed altitude grid to increase the signal-to-noise ratio. These thermal infrared data were analyzed by means of a radiative transfer code coupled with an inversion algorithm, in order to retrieve vertical temperature and abundance profiles. These profiles cover an altitude range of approximately 100 to 600 km, at 10- or 40-km vertical resolution (depending on the observation). Strong changes in temperature and composition occur in both polar regions where a vortex is in place during the winter. At this season, we observe a global enrichment in photochemical compounds in the mesosphere and stratosphere and a hot stratopause located around 0.01 mbar, both linked to downwelling in a pole-to-pole circulation cell. After the northern spring equinox, between December 2009 and April 2010, a stronger enhancement of photochemical compounds occurred at the north pole above the 0.01-mbar region, likely due to combined photochemical and dynamical effects. During the southern autumn in 2015, above the South pole, we also observed a strong enrichment in photochemical compounds that contributed to the cooling of the stratosphere above 0.2 mbar. Close to the northern spring equinox, in December 2009, the thermal profile at 74{deg}N exhibits an oscillation that we interpret in terms of an inertia-gravity wave.
Radio halos are diffuse, extended sources of radio emission detected primarily in massive, merging galaxy clusters. In smaller and/or relaxed clusters, where no halos are detected, one can instead place upper limits to a possible radio emission. Detections and upper limits are both crucial to constrain theoretical models for the generation of radio halos. The upper limits are model dependent for radio interferometers and thus the process of obtaining these is tedious to perform manually. In this paper, we present a Python based tool to automate this process of estimating the upper limits. The tool allows users to create radio halos with defined parameters like physical size, redshift and brightness model. A family of radio halo models with a range of flux densities, decided based on the rms noise of the image, is then injected into the parent visibility file and imaged. The halo injected image and the original image are then compared to check for the radio halo detection using a threshold on the detected excess flux density. Injections separated by finer differences in the flux densities are carried out once the coarse range where the upper limit is likely to be located has been identified. The code recommends an upper limit and provides a range of images for manual inspection. The user may then decide on the upper limit. We discuss the advantages and limitations of this tool. A wider usage of this tool in the context of the ongoing and upcoming all sky surveys with the LOFAR and SKA is proposed with the aim of constraining the physics of radio halo formation. The tool is publicly available at https://github.com/lijotgeorge/UL-CALC.
We have searched for the presence of simple P and S-bearing molecules in Titans atmosphere, by looking for the characteristic signatures of phosphine and hydrogen sulfide in infrared spectra obtained by Cassini CIRS. As a result we have placed the first upper limits on the stratospheric abundances, which are 1 ppb (PH3) and 330 ppb (H2S), at the 2-sigma significance level.
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