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Register a new userSingle-crystal growth of the ternary BaFe$_2$As$_2$ phase using the vertical Bridgman technique
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Ternary Ba-Fe-As system has been studied to determine a primary solidification field of the BaFe$_2$As$_2$ phase. We found that the BaFe$_2$As$_2$ phase most likely melts congruently and primarily solidifies either in the FeAs excess or Ba$_{x}$As$_{100-x}$ excess liquid. Knowing the primary solidification field, we have performed the vertical Bridgman growth using the starting liquid composition of Ba$_{15}$Fe$_{42.5}$As$_{42.5}$. Large single crystals of the typical size 10x4x2 mm$^3$ were obtained and their quality was confirmed by X-ray Laue and neutron diffraction.
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We report a simple, reliable method to grow high quality BaFe$_{2-x}$Co$_x$As$_2$ single crystal samples without using any fluxing agent. The starting materials for the single crystal growth come from well-crystallized polycrystalline samples and the highest growing temperature can be 1493 K. The as-grown crystals have typical dimensions of 4$times3times$0.5 mm$^3$ with c-axis perpendicular to the shining surface. We find that the samples have very large current carrying ability, indicating that the samples have good potential technological applications.
We have performed neutron diffraction measurement on a single crystal of parent compound of iron-based superconductor, BaFe$_2$As$_2$ at 12~K. In order to investigate in-plane anisotropy of magnetic form factor in the antiferromagnetic phase, the detwinned single crystal is used in the measurement. The magnetic structure factor and magnetic form factor are well explained by the spin densities consisting of $3d_{yz}$ electrons with a fraction of about 40~% and the electrons in the other four $3d$ orbitals with each fraction of about 15~%. Such anisotropic magnetic form factor is qualitatively consistent with the anisotropic magnetic behaviors observed in the antiferromagnetic phase of the parent compound of iron-based superconductor.
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