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Register a new userOptimal protocols for minimal work processes in underdamped stochastic thermodynamics
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For systems in an externally controllable time-dependent potential, the optimal protocol minimizes the mean work spent in a finite-time transition between two given equilibrium states. For overdamped dynamics which ignores inertia effects, the optimal protocol has been found to involve jumps of the control parameter at the beginning and end of the process. Including the inertia term, we show that this feature not only persists but that even delta peak-like changes of the control parameter at both boundaries make the process optimal. These results are obtained by analyzing two simple paradigmatic cases: First, a Brownian particle dragged by a harmonic optical trap through a viscous fluid and, second, a Brownian particle subject to an optical trap with time-dependent stiffness. These insights could be used to improve free energy calculations via either thermodynamic integration or fast growth methods using Jarzynskis equality.
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Asking for the optimal protocol of an external control parameter that minimizes the mean work required to drive a nano-scale system from one equilibrium state to another in finite time, Schmiedl and Seifert ({it Phys. Rev. Lett.} {bf 98}, 108301 (2007)) found the Euler-Lagrange equation to be a non-local integro-differential equation of correlation functions. For two linear examples, we show how this integro-differential equation can be solved analytically. For non-linear physical systems we show how the optimal protocol can be found numerically and demonstrate that there may exist several distinct optimal protocols simultaneously, and we present optimal protocols that have one, two, and three jumps, respectively.
The thermodynamic uncertainty relation (TUR) for underdamped dynamics has intriguing problems while its counterpart for overdamped dynamics has recently been derived. Even for the case of steady states, a proper way to match underdamped and overdamped TURs has not been found. We derive the TUR for underdamped systems subject to general time-dependent protocols, that covers steady states, by using the Cram{e}r-Rao inequality. We show the resultant TUR to give rise to the inequality of the product of the variance and entropy production. We prove it to approach to the known overdamped result for large viscosity limit. We present three examples to confirm our rigorous result.
Starting from the stochastic thermodynamics description of two coupled underdamped Brownian particles, we showcase and compare three different coarse-graining schemes leading to an effective thermodynamic description for the first of the two particles: marginalization over one particle, bipartite structure with information flows and the Hamiltonian of mean force formalism. In the limit of time-scale separation where the second particle with a fast relaxation time scale locally equilibrates with respect to the coordinates of the first slowly relaxing particle, the effective thermodynamics resulting from the first and third approach are shown to capture the full thermodynamics and to coincide with each other. In the bipartite approach, the slow part does not, in general, allow for an exact thermodynamic description as the entropic exchange between the particles is ignored. Physically, the second particle effectively becomes part of the heat reservoir. In the limit where the second particle becomes heavy and thus deterministic, the effective thermodynamics of the first two coarse-graining methods coincides with the full one. The Hamiltonian of mean force formalism however is shown to be incompatible with that limit. Physically, the second particle becomes a work source. These theoretical results are illustrated using an exactly solvable harmonic model.
We revisit the Ornstein-Uhlenbeck (OU) process as the fundamental mathematical description of linear irreversible phenomena, with fluctuations, near an equilibrium. By identifying the underlying circulating dynamics in a stationary process as the natural generalization of classical conservative mechanics, a bridge between a family of OU processes with equilibrium fluctuations and thermodynamics is established through the celebrated Helmholtz theorem. The Helmholtz theorem provides an emergent macroscopic equation of state of the entire system, which exhibits a universal ideal thermodynamic behavior. Fluctuating macroscopic quantities are studied from the stochastic thermodynamic point of view and a non-equilibrium work relation is obtained in the macroscopic picture, which may facilitate experimental study and application of the equalities due to Jarzynski, Crooks, and Hatano and Sasa.
We show that the fraction of time a thermodynamic current spends above its average value follows the arcsine law, a prominent result obtained by Levy for Brownian motion. Stochastic currents with long streaks above or below their average are much more likely than those that spend similar fractions of time above and below their average. Our result is confirmed with experimental data from a Brownian Carnot engine. We also conjecture that two other random times associated with currents obey the arcsine law: the time a current reaches its maximum value and the last time a current crosses its average value. These results apply to, inter alia, molecular motors, quantum dots and colloidal systems.
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