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Register a new userNitrogen superfractionation in dense cloud cores
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We report new calculations of interstellar 15N fractionation. Previously, we have shown that large enhancements of 15N/14N can occur in cold, dense gas where CO is frozen out, but that the existence of an NH + N channel in the dissociative recombination of N2H+ severely curtails the fractionation. In the light of recent experimental evidence that this channel is in fact negligible, we have reassessed the 15N chemistry in dense cloud cores. We consider the effects of temperatures below 10 K, and of the presence of large amounts of atomic nitrogen. We also show how the temporal evolution of gas-phase isotope ratios is preserved as spatial heterogeneity in ammonia ice mantles, as monolayers deposited at different times have different isotopic compositions. We demonstrate that the upper layers of this ice may have 15N/14N ratios an order of magnitude larger than the underlying elemental value. Converting our ratios to delta-values, we obtain delta(15N) > 3,000 per mil in the uppermost layer, with values as high as 10,000 per mil in some models. We suggest that this material is the precursor to the 15N `hotspots recently discovered in meteorites and IDPs
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Molecular clouds are a fundamental ingredient of galaxies: they are the channels that transform the diffuse gas into stars. The detailed process of how they do it is not completely understood. We review the current knowledge of molecular clouds and their substructure from scales $sim~$1~kpc down to the filament and core scale. We first review the mechanisms of cloud formation from the warm diffuse interstellar medium down to the cold and dense molecular clouds, the process of molecule formation and the role of the thermal and gravitational instabilities. We also discuss the main physical mechanisms through which clouds gather their mass, and note that all of them may have a role at various stages of the process. In order to understand the dynamics of clouds we then give a critical review of the widely used virial theorem, and its relation to the measurable properties of molecular clouds. Since these properties are the tools we have for understanding the dynamical state of clouds, we critically analyse them. We finally discuss the ubiquitous filamentary structure of molecular clouds and its connection to prestellar cores and star formation.
We present a survey of the ortho-H2D+(1_{1,0}-1_{1,1}) line toward a sample of 10 starless cores and 6 protostellar cores, carried out at the Caltech Submillimeter Observatory. The high diagnostic power of this line is revealed for the study of the chemistry, and the evolutionary and dynamical status of low-mass dense cores. The line is detected in 7 starless cores and in 4 protostellar cores. N(ortho-H2D+) ranges between 2 and 40x10^{12} cm^{-2} in starless cores and between 2 and 9x10^{12} cm^{-2} in protostellar cores. The brightest lines are detected toward the densest and most centrally concentrated starless cores, where the CO depletion factor and the deuterium fractionation are also largest. The large scatter observed in plots of N(ortho-H2D+) vs. the observed deuterium fractionation and vs. the CO depletion factor is likely to be due to variations in the ortho-to-para (o/p) ratio of H2D+ from >0.5 for T_{kin} < 10 K gas in pre-stellar cores to ~0.03 (consistent with T_{kin} ~15 K for protostellar cores). The two Ophiuchus cores in our sample also require a relatively low o/p ratio (~0.3). Other parameters, including the cosmic-ray ionization rate, the CO depletion factor (or, more in general, the depletion factor of neutral species), the volume density, the fraction of dust grains and PAHs also largely affect the ortho-H2D+ abundance. The most deuterated and H2D+-rich objects (L429, L1544, L694-2 and L183) are reproduced by chemical models of centrally concentrated (central densties ~10^{6} cm^{-3}) cores with chemical ages between 10^4 and 10^6 yr. Upper limits of the para-H3O+ (1_1- -2_1+) and para-D2H+ (1_{1,0}-1_{0,1}) lines are also given. (Abridged)
Context The Vela Molecular Ridge is one of the nearest (700 pc) giant molecular cloud (GMC) complexes hosting intermediate-mass (up to early B, late O stars) star formation, and is located in the outer Galaxy, inside the Galactic plane. Vela C is one of the GMCs making up the Vela Molecular Ridge, and exhibits both sub-regions of robust and sub-regions of more quiescent star formation activity, with both low- and intermediate(high)-mass star formation in progress. Aims We aim to study the individual and global properties of dense dust cores in Vela C, and aim to search for spatial variations in these properties which could be related to different environmental properties and/or evolutionary stages in the various sub-regions of Vela C. Methods We mapped the submillimetre (345 GHz) emission from vela C with LABOCA (beam size 19.2, spatial resolution ~0.07 pc at 700 pc) at the APEX telescope. We used the clump-finding algorithm CuTEx to identify the compact submillimetre sources. We also used SIMBA (250 GHz) observations, and Herschel and WISE ancillary data. The association with WISE red sources allowed the protostellar and starless cores to be separated, whereas the Herschel dataset allowed the dust temperature to be derived for a fraction of cores. The protostellar and starless core mass functions (CMFs) were constructed following two different approaches, achieving a mass completeness limit of 3.7 Msun. Results We retrieved 549 submillimetre cores, 316 of which are starless and mostly gravitationally bound (therefore prestellar in nature). Both the protostellar and the starless CMFs are consistent with the shape of a Salpeter initial mass function in the high-mass part of the distribution. Clustering of cores at scales of 1--6 pc is also found, hinting at fractionation of magnetised, turbulent gas.
The deuterium fraction [N$_2$D$^+$]/[N$_2$H$^+$], may provide information about the ages of dense, cold gas structures, important to compare with dynamical models of cloud core formation and evolution. Here we introduce a complete chemical network with species containing up to three atoms, with the exception of the Oxygen chemistry, where reactions involving H$_3$O$^+$ and its deuterated forms have been added, significantly improving the consistency with comprehensive chemical networks. Deuterium chemistry and spin states of H$_2$ and H$_3^+$ isotopologues are included in this primarily gas-phase chemical model. We investigate dependence of deuterium chemistry on model parameters: density ($n_{rm H}$), temperature, cosmic ray ionization rate, and gas-phase depletion factor of heavy elements ($f_{rm D}$). We also explore the effects of time-dependent freeze-out of gas-phase species and dynamical evolution of density at various rates relative to free-fall collapse. For a broad range of model parameters, the timescales to reach large values of $D_{rm frac}^{rm N_2H^+} gtrsim 0.1$, observed in some low- and high-mass starless cores, are relatively long compared to the local free-fall timescale. These conclusions are unaffected by introducing time-dependent freeze-out and considering models with evolving density, unless the initial $f_{rm D} gtrsim$ 10. For fiducial model parameters, achieving $D_{rm frac}^{rm N_2H^+} gtrsim 0.1$ requires collapse to be proceeding at rates at least several times slower than that of free-fall collapse, perhaps indicating a dynamically important role for magnetic fields in the support of starless cores and thus the regulation of star formation.
The molecular clouds Lupus 1, 3 and 4 were mapped with the Mopra telescope at 3 and 12 mm. Emission lines from high density molecular tracers were detected, i.e. NH$_3$ (1,1), NH$_3$ (2,2), N$_2$H$^+$ (1-0), HC$_3$N (3-2), HC$_3$N (10-9), CS (2-1), CH$_3$OH (2$_0-1_0$)A$^+$ and CH$_3$OH (2$_{-1}-1_{-1}$)E. Velocity gradients of more than 1 km s$^{-1}$ are present in Lupus 1 and 3 and multiple gas components are present in these clouds along some lines of sight. Lupus 1 is the cloud richest in high density cores, 8 cores were detected in it, 5 cores were detected in Lupus 3 and only 2 in Lupus 4. The intensity of the three species HC$_3$N, NH$_3$ and N$_2$H$^+$ changes significantly in the various cores: cores that are brighter in HC$_3$N are fainter or undetected in NH$_3$ and N$_2$H$^+$ and vice versa. We found that the column density ratios HC$_3$N/N$_2$H$^+$ and HC$_3$N/NH$_3$ change by one order of magnitude between the cores, indicating that also the chemical abundance of these species is different. The time dependent chemical code that we used to model our cores shows that the HC$_3$N/N$_2$H$^+$ and HC$_3$N/NH$_3$ ratios decrease with time therefore the observed column density of these species can be used as an indicator of the chemical evolution of dense cores. On this base we classified 5 out of 8 cores in Lupus 1 and 1 out of 5 cores in Lupus 3 as very young protostars or prestellar cores. Comparing the millimetre cores population with the population of the more evolved young stellar objects identified in the Spitzer surveys, we conclude that in Lupus 3 the bulk of the star formation activity has already passed and only a moderate number of stars are still forming. On the contrary, in Lupus 1 star formation is on-going and several dense cores are still in the pre--/proto--stellar phase. Lupus 4 is at an intermediate stage, with a smaller number of individual objects.
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