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Isosbestic points in the spectral function of correlated electrons

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 Added by Marcus Kollar
 Publication date 2006
  fields Physics
and research's language is English




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We investigate the properties of the spectral function A(omega,U) of correlated electrons within the Hubbard model and dynamical mean-field theory. Curves of A(omega,U) vs. omega for different values of the interaction U are found to intersect near the band-edges of the non-interacting system. For a wide range of U the crossing points are located within a sharply confined region. The precise location of these isosbestic points depends on details of the non-interacting band structure. Isosbestic points of dynamic quantities therefore provide valuable insights into microscopic energy scales of correlated systems.



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We analyze the sharpness of crossing (isosbestic) points of a family of curves which are observed in many quantities described by a function f(x,p), where x is a variable (e.g., the frequency) and p a parameter (e.g., the temperature). We show that if a narrow crossing region is observed near x* for a range of parameters p, then f(x,p) can be approximated by a perturbative expression in p for a wide range of x. This allows us, e.g., to extract the temperature dependence of several experimentally obtained quantities, such as the Raman response of HgBa2CuO4+delta, photoemission spectra of thin VO2 films, and the reflectivity of CaCu3Ti4O12, all of which exhibit narrow crossing regions near certain frequencies. We also explain the sharpness of isosbestic points in the optical conductivity of the Falicov-Kimball model and the spectral function of the Hubbard model.
68 - K. Byczuk , M. Kollar , K. Held 2006
The properties of condensed matter are determined by single-particle and collective excitations and their interactions. These quantum-mechanical excitations are characterized by an energy E and a momentum hbar k which are related through their dispersion E_k. The coupling of two excitations may lead to abrupt changes (kinks) in the slope of the dispersion. Such kinks thus carry important information about interactions in a many-body system. For example, kinks detected at 40-70 meV below the Fermi level in the electronic dispersion of high-temperature superconductors are taken as evidence for phonon or spin-fluctuation based pairing mechanisms. Kinks in the electronic dispersion at binding energies ranging from 30 to 800 meV are also found in various other metals posing questions about their origins. Here we report a novel, purely electronic mechanism yielding kinks in the electron dispersions. It applies to strongly correlated metals whose spectral function shows well separated Hubbard subbands and central peak as, for example, in transition metal-oxides. The position of the kinks and the energy range of validity of Fermi-liquid (FL) theory is determined solely by the FL renormalization factor and the bare, uncorrelated band structure. Angle-resolved photoemission spectroscopy (ARPES) experiments at binding energies outside the FL regime can thus provide new, previously unexpected information about strongly correlated electronic systems.
In this work we examine the time-resolved, instantaneous current response for the spinless Falicov-Kimball model at half-filling, on both sides of the Mott-Hubbard metal-insulator transition, driven by a strong electric field pump pulse. The results are obtained using an exact, nonequilibrium, many-body impurity solution specifically designed to treat the out-of-equilibrium evolution of electrons in time-dependent fields. We provide a brief introduction to the method and its computational details. We find that the current develops Bloch oscillations, similar to the case of DC driving fields, with an additional amplitude modulation, characterized by beats and induced by correlation effects. Correlations primarily manifest themselves through an overall reduction in magnitude and shift in the onset time of the current response with increasing interaction strength.
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