Subscribe to the gold package and get unlimited access to Shamra Academy
Register a new userRelationship between the thermopower and entropy of strongly correlated electron systems
101
0
0.0
(
0
)
Authors
V. Zlatic
Ask ChatGPT about the research
No Arabic abstract
A number of recent experiments report the low-temperature thermopower $alpha$ and specific heat coefficients $gamma=C_V/T$ of strongly correlated electron systems. Describing the charge and heat transport in a thermoelectric by transport equations, and assuming that the charge current and the heat current densities are proportional to the number density of the charge carriers, we obtain a simple mean-field relationship between $alpha$ and the entropy density $cal S$ of the charge carriers. We discuss corrections to this mean-field formula and use results obtained for the periodic Anderson and the Falicov-Kimball models to explain the concentration (chemical pressure) and temperature dependence of $alpha/gamma T$ in EuCu$_2$(Ge$_{1-x}$Si$_x$)$_2$, CePt$_{1-x}$Ni$_x$, and YbIn$_{1-x}$Ag${_x}$Cu$_4$ intermetallic compounds. % We also show, using the poor mans mapping which approximates the periodic Anderson lattice by the single impurity Anderson model, that the seemingly complicated behavior of $alpha(T)$ can be explained in simple terms and that the temperature dependence of $alpha(T)$ at each doping level is consistent with the magnetic character of 4{it f} ions.
rate research
Read More
The search for semiconductors with high thermoelectric figure of merit has been greatly aided by theoretical modeling of electron and phonon transport, both in bulk materials and in nanocomposites. Recent experiments have studied thermoelectric transport in ``strongly correlated materials derived by doping Mott insulators, whose insulating behavior without doping results from electron-electron repulsion, rather than from band structure as in semiconductors. Here a unified theory of electrical and thermal transport in the atomic and ``Heikes limit is applied to understand recent transport experiments on sodium cobaltate and other doped Mott insulators at room temperature and above. For optimal electron filling, a broad class of narrow-bandwidth correlated materials are shown to have power factors (the electronic portion of the thermoelectric figure of merit) as high at and above room temperature as in the best semiconductors.
Temperature dependence of thermopower in the multiorbital Hubbard model is studied by using the dynamical mean-field theory with the non-crossing approximation impurity solver. It is found that the Coulomb interaction, the Hund coupling, and the crystal filed splitting bring about non-monotonic temperature dependence of the thermopower, including its sign reversal. The implication of our theoretical results to some materials is discussed.
We reexamine the Yang-Yang-Takahashi method of deriving the thermodynamic Bethe ansatz equations which describe strongly correlated electron systems of fundamental physical interest, such as the Hubbard, $s-d$ exchange (Kondo) and Anderson models. It is shown that these equations contain some additional terms which may play an important role in the physics of the systems.
We introduce a new mathematical object, the fermionant ${mathrm{Ferm}}_N(G)$, of type $N$ of an $n times n$ matrix $G$. It represents certain $n$-point functions involving $N$ species of free fermions. When N=1, the fermionant reduces to the determinant. The partition function of the repulsive Hubbard model, of geometrically frustrated quantum antiferromagnets, and of Kondo lattice models can be expressed as fermionants of type N=2, which naturally incorporates infinite on-site repulsion. A computation of the fermionant in polynomial time would solve many interesting fermion sign problems.
Recent progress in neutron spin-echo spectroscopy by means of longitudinal Modulation of IntEnsity with Zero Effort (MIEZE) is reviewed. Key technical characteristics are summarized which highlight that the parameter range accessible in momentum and energy, as well as its limitations, are extremely well understood and controlled. Typical experimental data comprising quasi-elastic and inelastic scattering are presented, featuring magneto-elastic coupling and crystal field excitations in Ho2Ti2O7, the skyrmion lattice to paramagnetic transition under applied magnetic field in MnSi, ferromagnetic criticality and spin waves in Fe. In addition bench marking studies of the molecular dynamics in H2O are reported. Taken together, the advantages of MIEZE spectroscopy in studies at small and intermediate momentum transfers comprise an exceptionally wide dynamic range of over seven orders of magnitude, the capability to perform straight forward studies on depolarizing samples or under depolarizing sample environments, as well as on incoherently scattering materials.
Log in to be able to interact and post comments
comments
Fetching comments
Sign in to be able to follow your search criteria
