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Infrared absorption spectra of SrTiO$_3$ have been measured under above-band-gap photoexcitations to study the properties of photogenerated carriers, which should play important roles in previously reported photoinduced phenomena in SrTiO$_3$. A broad absorption band appears over the entire mid-infrared region under photoexcitation. Detailed energy, temperature, and excitation power dependences of the photoinduced absorption are reported. This photo-induced absorption is attributed to the intragap excitations of the photogenerated carriers. The data show the existence of a high density of in-gap states for the photocarriers, which extends over a wide energy range starting from the conduction and valence band edges.
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Long after its discovery superconductivity in alkali fullerides A$_3$C$_{60}$ still challenges conventional wisdom. The freshest inroad in such ever-surprising physics is the behaviour under intense infrared (IR) excitation. Signatures attributable to a transient superconducting state extending up to temperatures ten times higher than the equilibrium $T_csim$ 20 K have been discovered in K$_3$C$_{60}$ after ultra-short pulsed IR irradiation -- an effect which still appears as remarkable as mysterious. Motivated by the observation that the phenomenon is observed in a broad pumping frequency range that coincides with the mid-infrared electronic absorption peak still of unclear origin, rather than to TO phonons as has been proposed, we advance here a radically new mechanism. First, we argue that this broad absorption peak represents a super-exciton involving the promotion of one electron from the $t_{1u}$ half-filled state to a higher-energy empty $t_{1g}$ state, dramatically lowered in energy by the large dipole-dipole interaction acting in conjunction with Jahn Teller effect within the enormously degenerate manifold of $big(t_{1u}big)^2big(t_{1g}big)^1$ states. Both long-lived and entropy-rich because they are triplets, the IR-induced excitons act as a sort of cooling mechanism that permits transient superconductive signals to persist up to much larger temperatures.
Infrared observations probe the warm gas in the inner regions of planet-forming disks around young sun-like, T Tauri stars. In these systems, H$_2$O, OH, CO, CO$_2$, C$_2$H$_2$, and HCN have been widely observed. However, the potentially abundant carbon carrier CH$_4$ remains largely unconstrained. The James Webb Space Telescope (JWST) will be able to characterize mid-infrared fluxes of CH$_4$ along with several other carriers of carbon and oxygen. In anticipation of the JWST mission, we model the physical and chemical structure of a T Tauri disk to predict the abundances and mid-infrared fluxes of observable molecules. A range of compositional scenarios are explored involving the destruction of refractory carbon materials and alterations to the total elemental (volatile and refractory) C/O ratio. Photon-driven chemistry in the inner disk surface layers largely destroys the initial carbon and oxygen carriers. This causes models with the same physical structure and C/O ratio to have similar steady state surface compositions, regardless of the initial chemical abundances. Initial disk compositions are better preserved in the shielded inner disk midplane. The degree of similarity between the surface and midplane compositions in the inner disk will depend on the characteristics of vertical mixing at these radii. Our modeled fluxes of observable molecules respond sensitively to changes in the disk gas temperature, inner radius, and the total elemental C/O ratio. As a result, mid-infrared observations of disks will be useful probes of these fundamental disk parameters, including the C/O ratio, which can be compared to values determined for planetary atmospheres.
We have found that there is more than one type of conducting carriers generated in LaAlO3/SrTiO3 heterostructures by comparing the sheet carrier density and mobility from optical transmission spectroscopy with those from dc-transport measurements. When multiple types of carriers exist, optical characterization dominantly reflects the contribution from the high-density carriers whereas dc-transport measurements may exaggerate the contribution of the high-mobility carriers even though they are present at low-density. Since the low-temperature mobilities determined by dc-transport in the LaAlO3/SrTiO3 heterostructures are much higher than those extracted by optical method, we attribute the origin of high-mobility transport to the low-density conducting carriers.
Plasmons in graphene nanostructures show great promise for mid-infrared applications ranging from a few to tens of microns. However, mid-infrared plasmonic resonances in graphene nanostructures are usually weak and narrow-banded, limiting their potential in light manipulation and detection. Here we investigate the coupling among graphene plasmonic nanostructures and further show that by engineering the coupling, enhancement of light-graphene interaction strength and broadening of spectral width can be achieved simultaneously. Leveraging the concept of coupling, we demonstrate a hybrid 2-layer graphene nanoribbon array which shows 5 to 7% extinction within the entire 8 to 14 {mu}m (~700 to 1250 cm-1) wavelength range, covering one of the important atmosphere infrared transmission windows. Such coupled hybrid graphene plasmonic nanostructures may find applications in infrared sensing and free-space communications.
The spatial collection efficiency portrays the driving forces and loss mechanisms in photovoltaic and photoelectrochemical devices. It is defined as the fraction of photogenerated charge carriers created at a specific point within the device that contribute to the photocurrent. In stratified planar structures, the spatial collection efficiency can be extracted out of photocurrent action spectra measurements empirically, with few a priori assumptions. Although this method was applied to photovoltaic cells made of well-understood materials, it has never been used to study unconventional materials such as metal-oxide semiconductors that are often employed in photoelectrochemical cells. This perspective shows the opportunities that this method has to offer for investigating new materials and devices with unknown properties. The relative simplicity of the method, and its applicability to operando performance characterization, makes it an important tool for analysis and design of new photovoltaic and photoelectrochemical materials and devices.
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