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Register a new userComposition gradients and their effects on superconductivity in Al-doped MgB2
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(Abridged abstract) Alloyed MgB2 differs from pure forms in that diffusion is needed to distribute the alloying elements homogeneously. Williamson-Hall analyses of x-ray diffraction peaks showed that Mg1-xAlxB2 samples made by a typical reaction A had higher crystalline strain than when thoroughly annealed by reaction B. The strain and other analyses indicate that reaction A produced substantial Al gradients across the individual grains while reaction B did not. The gredients skew the apparent superconducting behavior: properties appeared to be distinct when plotted vs. x (e.g. two Tc(x) curves), but all of the data merged when analyzed in terms of the unit cell volume v (e.g. one Tc(v) curve). Since v is derived from x-ray diffraction, it captures the average Al content actually present inside the grains and better reflects the behavior intrinsic to the addition of Al. These analyses show that it is important to coordinate structural and property characterizations to remove artifacts of composition gradients and uncover the intrinsic trends. Because the standard characterizations of the superconducting properties above gave no clear indication that the two sample sets had different homogeneity, the structural information was vital to make a correct assessment of the effects of Al doping on superconductivity.
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We consider the realistic case of a superconductor with a nonzero density of elastic scatterers, so that the normal state conductivity is finite. The quantum superconductor-metal (QSM) transition can then be tuned by varying either the attractive electron-electron interaction, the quenched disorder, or the applied magnetic field. We explore the consistency of the associated scaling relations, Tc ~ 1/lamda(0) ~ gap(0) ~ 1/gsi(0) ~ Hc2(0)^-0.5 and Tc(H) ~ 1/Lamda(0,H) ~ gap(0,h) ~ (Hc2(0)-H)^ 1/2, valid for all dimensions D > 2, with experimental data, in Al, C doped MgB2 and overdoped cuprates.
Two sets of MgB2 samples doped with up to 5 at. % of Al were prepared in different laboratories using different procedures. Decreases in the a and c lattice parameters were observed with Al doping confirming Al substitution onto the Mg site. The critical temperature (Tc) remained largely unchanged with Al doping. For 1 - 2.5 at.% doping, at 20K the in-field critical current densities (Jcs) were enhanced, particularly at lower fields. At 5K, in-field Jc was markedly improved, e.g. at 5T Jc was enhanced by a factor of 20 for a doping level of 1 at.% Al. The improved Jcs correlate with increased sample resistivity indicative of an increase in the upper critical field, Hc2, through alloying.
High-pressure superconductivity in a rare-earth doped Ca0.86Pr0.14Fe2As2 single crystalline sample has been studied up to 12 GPa and temperatures down to 11 K using designer diamond anvil cell under a quasi-hydrostatic pressure medium. The electrical resistance measurements were complemented by high pressure and low temperature x-ray diffraction studies at a synchrotron source. The electrical resistance measurements show an intriguing observation of superconductivity under pressure, with Tc as high as ~51 K at 1.9 GPa, presenting the highest Tc reported in the intermetallic class of 1-2-2 iron-based superconductors. The resistive transition observed suggests a possible existence of two superconducting phases at low pressures of 0.5 GPa: one phase starting at Tc1 ~48 K, and the other starting at Tc2~16 K. The two superconducting transitions show distinct variations with increasing pressure. High pressure low temperature structural studies indicate that the superconducting phase is a collapsed tetragonal ThCr2Si2-type (122) crystal structure. Our high pressure studies indicate that high Tc state attributed to non-bulk superconductivity in rare-earth doped 1-2-2 iron-based superconductors is stable under compression over a broad pressure range.
In powder-in-tube (PIT) Nb3Sn composites, the A15 phase forms between a central tin-rich core and a coaxial Nb tube, thus causing the tin content and superconducting properties to vary with radius across the A15 layer. Since this geometry is also ideal for magnetic characterization of the superconducting properties with the field parallel to the tube axis, a system of concentric shells with varying tin content was used to simulate the superconducting properties, the overall severity of the Sn composition gradient being defined by an index N. Using well-known scaling relationships and property trends developed in an earlier experimental study, the critical current density for each shell was calculated, and from this the magnetic moment of each shell was found. By summing these moments, experimentally measured properties such as pinning-force curves and Kramer plots could be simulated. We found that different tin profiles have only a minor effect on the shape of Kramer plots, but a pronounced effect on the irreversibility fields defined by the extrapolation of Kramer plots. In fact, these extrapolated values H_K are very close to a weighted average of the superconducting properties across the layer for all N. The difference between H_K and the upper critical field commonly seen in experiments is a direct consequence of the different ways measurements probe the simulated Sn gradients. Sn gradients were found to be significantly deleterious to the critical current density Jc, since reductions to both the elementary pinning force and the flux pinning scaling field H_K compound the reduction in Jc. The simulations show that significant gains in Jc of Nb3Sn strands might be realized by circumventing strong compositional gradients of tin.
In this Letter, the study of the effect of Al substitution on the upper critical field, Bc2, in AlxMg1-xB2 samples is presented. We find a straightforward correlation between Bc2 and the sigma-band gap, Delta_sigma, evaluated by point-contact measurements. Up to x=0.2 Bc2 can be well described within a clean limit model and its decrease with x is directly related to the suppression of Delta_sigma. For larger doping we observed the crossover to the dirty regime driven mostly by the strong decrease of Delta_sigma rather than by the increase of the sigma-band scattering rate
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