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We report on laboratory measurements of molecular hydrogen formation and recombination on an olivine slab as a function of surface temperature under conditions relevant to those encountered in the interstellar medium. On the basis of our experimental evidence, we recognize that there are two main regimes of H coverage that are of astrophysical importance; for each of them we provide an expression giving the production rate of molecular hydrogen in interstellar clouds.
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Experimental results on the formation of molecular hydrogen on amorphous silicate surfaces are presented and analyzed using a rate equation model. The energy barriers for the relevant diffusion and desorption processes are obtained. They turn out to be significantly higher than those obtained for polycrystalline silicates, demonstrating the importance of grain morphology. Using these barriers we evaluate the efficiency of molecular hydrogen formation on amorphous silicate grains under interstellar conditions. It is found that unlike polycrystalline silicates, amorphous silicate grains are efficient catalysts of H_2 formation in diffuse interstellar clouds.
Recent experimental results about the formation of molecular hydrogen on astrophysically relevant surfaces under conditions close to those encountered in the interstellar medium are analyzed using rate equations. The parameters of the rate equation model are fitted to temperature-programmed desorption curves obtained in the laboratory. These parameters are the activation energy barriers for atomic hydrogen diffusion and desorption, the barrier for molecular hydrogen desorption, and the probability of spontaneous desorption of a hydrogen molecule upon recombination. The model is a generalization of the Polanyi-Wigner equation and provides a description of both first and second order kinetic processes within a single model. Using the values of the parameters that fit best the experimental results, the efficiency of hydrogen recombination on olivine and amorphous carbon surfaces is obtained for a range of hydrogen flux and surface temperature pertinent to a wide range of interstellar conditions.
We present experimental data on H2 formation processes on gas-phase polycyclic aromatic hydrocarbon (PAH) cations. This process was studied by exposing coronene radical cations, confined in a radio-frequency ion trap, to gas phase H atoms. Sequential attachment of up to 23 hydrogen atoms has been observed. Exposure to atomic D instead of H allows one to distinguish attachment from competing abstraction reactions, as the latter now leave a unique fingerprint in the measured mass spectra. Modeling of the experimental results using realistic cross sections and barriers for attachment and abstraction yield a 1:2 ratio of abstraction to attachment cross sections. The strong contribution of abstraction indicates that H2 formation on interstellar PAH cations is an order of magnitude more relevant than previously thought.
Does star formation proceed in the same way in large spirals such as the Milky Way and in smaller chemically younger galaxies? Earlier work suggests a more rapid transformation of H$_2$ into stars in these objects but (1) a doubt remains about the validity of the H$_2$ mass estimates and (2) there is currently no explanation for why star formation should be more efficient. M~33, a local group spiral with a mass $sim 10$% and a metallicity half that of the Galaxy, represents a first step towards the metal poor Dwarf Galaxies. We have searched for molecular clouds in the outer disk of M~33 and present here a set of detections of both $^{12}$CO and $^{13}$CO, including the only detections (for both lines) beyond the R$_{25}$ radius in a subsolar metallicity galaxy. The spatial resolution enables mass estimates for the clouds and thus a measure of the $N({rm H}_2) / I_{rm CO}$ ratio, which in turn enables a more reliable calculation of the H$_2$ mass. Our estimate for the outer disk of M~33 is $N({rm H}_2) / I_{rm CO(1-0)} sim 5 times 10^{20} ,{rm cm^{-2}/(K{rm km s^{-1}})}$ with an estimated uncertainty of a factor $le 2$. While the $^{12/13}$CO line ratios do not provide a reliable measure of $N({rm H}_2) / I_{rm CO}$, the values we find are slightly greater than Galactic and corroborate a somewhat higher $N({rm H}_2) / I_{rm CO}$ value. Comparing the CO observations with other tracers of the interstellar medium, no reliable means of predicting where CO would be detected was identified. In particular, CO detections were often not directly on local HI or FIR or H$alpha$ peaks, although generally in regions with FIR emission and high HI column density. The results presented here provide support for the quicker transformation of H$_2$ into stars in M~33 than in large local universe spirals.
The study of the formation of molecular hydrogen on low temperature surfaces is of interest both because it allows to explore elementary steps in the heterogeneous catalysis of a simple molecule and because of the applications in astrochemistry. Here we report results of experiments of molecular hydrogen formation on amorphous silicate surfaces using temperature-programmed desorption (TPD). In these experiments beams of H and D atoms are irradiated on the surface of an amorphous silicate sample. The desorption rate of HD molecules is monitored using a mass spectrometer during a subsequent TPD run. The results are analyzed using rate equations and the activation energies of the processes leading to molecular hydrogen formation are obtained from the TPD data. We show that a model based on a single isotope provides the correct results for the activation energies for diffusion and desorption of H atoms. These results can thus be used to evaluate the formation rate of H_2 on dust grains under the actual conditions present in interstellar clouds.
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