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Register a new userFormation of molecular hydrogen on amorphous silicate surfaces
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Experimental results on the formation of molecular hydrogen on amorphous silicate surfaces are presented and analyzed using a rate equation model. The energy barriers for the relevant diffusion and desorption processes are obtained. They turn out to be significantly higher than those obtained for polycrystalline silicates, demonstrating the importance of grain morphology. Using these barriers we evaluate the efficiency of molecular hydrogen formation on amorphous silicate grains under interstellar conditions. It is found that unlike polycrystalline silicates, amorphous silicate grains are efficient catalysts of H_2 formation in diffuse interstellar clouds.
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Recent experimental results about the formation of molecular hydrogen on astrophysically relevant surfaces under conditions close to those encountered in the interstellar medium are analyzed using rate equations. The parameters of the rate equation model are fitted to temperature-programmed desorption curves obtained in the laboratory. These parameters are the activation energy barriers for atomic hydrogen diffusion and desorption, the barrier for molecular hydrogen desorption, and the probability of spontaneous desorption of a hydrogen molecule upon recombination. The model is a generalization of the Polanyi-Wigner equation and provides a description of both first and second order kinetic processes within a single model. Using the values of the parameters that fit best the experimental results, the efficiency of hydrogen recombination on olivine and amorphous carbon surfaces is obtained for a range of hydrogen flux and surface temperature pertinent to a wide range of interstellar conditions.
The study of the formation of molecular hydrogen on low temperature surfaces is of interest both because it allows to explore elementary steps in the heterogeneous catalysis of a simple molecule and because of the applications in astrochemistry. Here we report results of experiments of molecular hydrogen formation on amorphous silicate surfaces using temperature-programmed desorption (TPD). In these experiments beams of H and D atoms are irradiated on the surface of an amorphous silicate sample. The desorption rate of HD molecules is monitored using a mass spectrometer during a subsequent TPD run. The results are analyzed using rate equations and the activation energies of the processes leading to molecular hydrogen formation are obtained from the TPD data. We show that a model based on a single isotope provides the correct results for the activation energies for diffusion and desorption of H atoms. These results can thus be used to evaluate the formation rate of H_2 on dust grains under the actual conditions present in interstellar clouds.
We report on laboratory measurements of molecular hydrogen formation and recombination on an olivine slab as a function of surface temperature under conditions relevant to those encountered in the interstellar medium. On the basis of our experimental evidence, we recognize that there are two main regimes of H coverage that are of astrophysical importance; for each of them we provide an expression giving the production rate of molecular hydrogen in interstellar clouds.
We report on the first results of experiments to measure the recombination rate of hydrogen on surfaces of astrophysical interest. Our measurements give lower values for the recombination efficiency (sticking probability S x probability of recombination upon H-H encounter $gamma$) than model-based estimates. We propose that our results can be reconciled with average estimates of the recombination rate (1/2 n(H) n(g) v(H)A S $gamma$) from astronomical observations, if the actual surface of an average grain is rougher, and its area bigger, than the one considered in models.
We compute the rate of diffusive nuclear burning for hydrogen on the surface of a magnetar (Soft Gamma-Ray Repeater or Anomalous X-Ray Pulsar). We find that hydrogen at the photosphere will be burned on an extremely rapid timescale of hours to years, depending on composition of the underlying material. Improving on our previous studies, we explore the effect of a maximally thick inert helium layer, previously thought to slow down the burning rate. Since hydrogen diffuses faster in helium than through heavier elements, we find this helium buffer actually increases the burning rate for magnetars. We compute simple analytic scalings of the burning rate with temperature and magnetic field for a range of core temperature. We conclude that magnetar photospheres are very unlikely to contain hydrogen. This motivates theoretical work on heavy element atmospheres that are needed to measure effective temperature from the observed thermal emission and constrains models of AXPs that rely on magnetar cooling through thick light element envelopes.
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