No Arabic abstract
We have analysed the ISO-SWS spectrum of Jupiter in the 12-16 micron range, where several hydrocarbons exhibit rovibrational bands. Using temperature information from the methane and hydrogen emissions, we derive the mixing ratios (q) of acetylene and ethane at two independent pressure levels. For acetylene, we find $q=(8.9^{+1.1}_{-0.6})times10^{-7}$ at 0.3 mbar and $q=(1.1^{+0.2}_{-0.1})times10^{-7}$ at 4 mbar, giving a slope $-dln q / dln P=0.8pm0.1$, while for ethane $q=(1.0pm0.2)times10^{-5}$ at 1 mbar and $q=(2.6^{+0.5}_{-0.6})times10^{-6}$ at 10 mbar, giving $-dln q / dln P=0.6pm0.2$. The ethane slope is consistent with the predictions of Gladstone et al. (1996), but that predicted for acetylene is larger than we observe. This disagreement is best explained by an overestimation of the acetylene production rate compared to that of ethane in the Gladstone et al. (1996) model. At 15.8 micron, methylacetylene is detected for the first time at low jovian latitudes, and a stratospheric column density of $(1.5pm0.4)times10^{15}$ molecule.cm-2 is inferred. We also derive an upper limit for the diacetylene column density of $7times10^{13}$ molecule.cm-2.
Oxygen atom addition and insertion reactions may provide a pathway to chemical complexity in ices that are too cold for radicals to diffuse and react. We have studied the ice-phase reactions of photo-produced oxygen atoms with C2 hydrocarbons under ISM-like conditions. The main products of oxygen atom reactions with ethane are ethanol and acetaldehyde; with ethylene are ethylene oxide and acetaldehyde; and with acetylene is ketene. The derived branching ratio from ethane to ethanol is ~0.74 and from ethylene to ethylene oxide is ~0.47. For all three hydrocarbons there is evidence of an effectively barrierless reaction with O(^1D) to form oxygen-bearing organic products; in the case of ethylene, there may be an additional barriered contribution of the ground-state O(^3P) atom. Thus, oxygen atom reactions with saturated and unsaturated hydrocarbons are a promising pathway to chemical complexity even at very low temperatures where the diffusion of radical species is thermally inaccessible.
Infrared spectroscopy is a powerful tool to probe the inventory of solid state and molecular species in circumstellar ejecta. Here we analyse the infrared spectrum of the Asymptotic Giant Branch star W Hya, obtained by the Short and Long Wavelength Spectrometers on board of the Infrared Satellite Observatory. These spectra show evidence for the presence of amorphous silicates, aluminum oxide, and magnesium-iron oxide grains. We have modelled the spectral energy distribution using laboratory measured optical properties of these compounds and derive a total dust mass loss rate of 3E-10 Msol/yr. We find no satisfactory fit to the 13 micron dust emission feature and the identification of its carrier is still an open issue. We have also modelled the molecular absorption bands due to H2O, OH, CO, CO2, SiO, and SO2 and estimated the excitation temperatures for different bands which range from 300 to 3000K. It is clear that different molecules giving rise to these absorption bands originate from different gas layers. We present and analyse high resolution Fabry-Perot spectra of the three CO2 bands in the 15 micron region. In these data, the bands are resolved into individual Q-lines in emission, which allows the direct determination of the excitation temperature and column density of the emitting gas. This reveals the presence of a warm (about 450K) extended layer of CO2, somewhere between the photosphere and the dust formation zone. The gas in this layer is cooler than the 1000K CO2 gas responsible for the low-resolution absorption bands at 4.25 and 15 micron. The rotational and vibrational excitation temperatures derived from the individual Q-branch lines of CO2 are different (450K and 150K, respectively) so that the CO2 level population is not in LTE.
The flybys of Jupiter by the Voyager spacecraft in 1979, and over two decades later by Cassini in 2000, have provided us with unique datasets from two different epochs, allowing the investigation of seasonal change in the atmosphere. In this paper we model zonal averages of thermal infrared spectra from the two instruments, Voyager 1 IRIS and Cassini CIRS, to retrieve the vertical and meridional profiles of temperature, and the abundances of the two minor hydrocarbons, acetylene (C2H2) and ethane (C2H6). The spatial variation of these gases is controlled by both chemistry and dynamics, and therefore their observed distribution gives us an insight into both processes. We find that the two gases paint quite different pictures of seasonal change. Whilst the 2-D cross-section of C2H6 abundance is slightly increased and more symmetric in 2000 (northern summer solstice) compared to 1979 (northern fall equinox), the major trend of equator to pole increase remains. For C2H2 on the other hand, the Voyager epoch exhibits almost no latitudinal variation, whilst the Cassini era shows a marked decrease polewards in both hemispheres. At the present time, these experimental findings are in advance of interpretation, as there are no published models of 2-D Jovian seasonal chemical variation available for comparison.
A detailed spectroscopic study of the ISO-SWS data of the red giant Alpha Tau is presented, which enables not only the accurate determination of the stellar parameters of Alpha Tau, but also serves as a critical review of the ISO-SWS calibration. This study is situated in a broader context of an iterative process in which both accurate observations of stellar templates and cool star atmosphere models are involved to improve the ISO-SWS calibration process as well as the theoretical modelling of stellar atmospheres. Therefore a sample of cool stars, covering the whole A0 -- M8 spectral classification, has been observed in order to disentangle calibration problems and problems in generating the theoretical models and corresponding synthetic spectrum. By using stellar parameters found in the literature large discrepancies were seen between the ISO-SWS data and the generated synthetic spectrum of Alpha Tau. A study of the influence of various stellar parameters on the theoretical models and synthetic spectra, in conjunction with the Kolmogorov-Smirnov test to evaluate objectively the goodness-of-fit, enables us to pin down the stellar parameters with a high accuracy: Teff = 3850 +/- 70 K, log g = 1.50 +/- 0.15, M = 2.3 +/- 0.8 Msun, z = -0.15 +/- 0.20 dex, microturbulence = 1.7 +/- 0.3 km/s, 12C/13C= 10 +/- 1, abundance of C = 8.35 +/- 0.20 dex, abundance of N= 8.35 +/- 0.25 dex, abundance of O = 8.83 +/- 0.15 dex and the angular diameter is 20.77 +/- 0.83 mas. These atmospheric parameters were then compared with the results provided by other authors using other methods and/or spectra.
We present new ISO-SWS data for a sample of 27 starburst galaxies, and with these data examine the issues of formation and evolution of the most massive stars in starburst galaxies. Using starburst models which incorporate time evolution, new stellar atmosphere models for massive stars, and a starburst model geometry derived from observations of the prototypical starburst M82, we model the integrated mid-infrared line ratio [NeIII](15.6 microns)/[NeII](12.8 microns). This line ratio is sensitive to the hardness of the stellar energy distribution and therefore to the most massive stars present. We conclude from our models, with consideration of recent determinations of the stellar census in local, high-mass star forming regions, that the [NeIII]/[NeII] ratios we measure are consistent with the formation of massive (~50-100 solar mass) stars in most starbursts. In this framework, the low nebular excitation inferred from the measured line ratios can be attributed to aging effects. By including estimates of the ratio of infrared-to-Lyman continuum luminosity for the galaxies in our sample, we further find that most starbursts are relatively short-lived (1-10 million years), only a few O-star lifetimes. We discuss a possible cause of such short events: the effectiveness of stellar winds and supernovae in destroying the starburst environment.