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Register a new userRole of intermetallic phases in initiation and propagation of intergranular corrosion of an Al-Li-Cu-Mg alloy
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Intermetallic phases in a recently developed Al-Li-Cu-Mg alloy have been investigated to understand their roles in the initiation and propagation processes of intergranular corrosion. Corrosion initiation involves trenching formation in the Al matrix adjacent to the large particles of Al7Cu2(Fe, Mn) phases. These phases containing Li are electrochemically active and susceptible to self-dissolution via a de-alloying mechanism during corrosion process. The subsurface particles of Al7Cu2(Fe, Mn) and Al20Cu2Mn3 phases act as the internal cathodes for continuous corrosion propagation along the particle-matrix interface and the associated grain boundaries. Corrosion propagation along the particle-matrix interface was facilitated by the anodic dissolution of the surrounding Al matrix due to the micro-galvanic interaction with the cathodic intermetallic phases. In addition, T1 (Al2CuLi) precipitates and the isolated particles of Al7Cu2(Fe, Mn) and Al20Cu2Mn3 phases were dissolved along the path of corrosion propagation. The dissolved metal ions were redeposited through the network of crevice.
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Thick-section plates made from a recently developed Al-Cu-Mg-Li alloy have been evaluated to understand the influence of microstructure on the anisotropy of tensile strengths after natural and artificial ageing treatment. Pancake-shaped grains with a coarse substructure and strong crystallographic texture with a beta-fibre orientation at the mid-thickness position are observed. In addition, an inhomogeneous distribution of T1 precipitates through the plate thickness has been revealed with the volume fraction of intragranular precipitates ~ 40% higher at the plate centre than the thickness position. Altogether these microstructural features contribute to the in-plane anisotropy of tensile strengths that is ~ 5% higher at the mid-thickness position than the 1/4 thickness position. The variation of ageing-induced T1 precipitates through the plate thickness further contributes to the through-thickness anisotropy that is ~ 3% higher in T8 temper as compared to T3 temper.
The scaling behavior of the Portevin-Le Chatelier (PLC) effect was studied by deforming Al-2.5%Mg alloy for a wide range of strain rates. To reveal the exact scaling nature, the time series data of true stress vs. time, obtained during deformation, were analyzed by two complementary methods: the finite variance scaling method and the diffusion entropy analysis. From these analyses we could establish that in the entire span of strain rates, PLC effect showed Levy walk property.
The complexity of the Portevin-Le Chatelier effect in Al-2.5%Mg polycrystalline samples subjected to uniaxial tensile tests is quantified. Multiscale entropy analysis is carried out on the stress time series data observed during jerky flow to quantify the complexity of the distinct spatiotemporal dynamical regimes. It is shown that for the static type C band, the entropy is very low for all the scales compared to the hopping type B and the propagating type A bands. The results are interpreted considering the time and length scales relevant to the effect.
Irradiation Assisted Stress Corrosion Cracking (IASCC) is a material degradation phenomenon affecting austenitic stainless steels used in nuclear Pressurized Water Reactors (PWR), leading to the initiation and propagation of intergranular cracks. Such phenomenon belongs to the broader class of InterGranular Stress Corrosion Cracking (IGSCC). A micromechanical analysis of IGSCC of an irradiated austenitic stainless steel is performed in this study to assess local cracking conditions. A 304L proton irradiated sample tested in PWR environment and showing intergranular cracking is investigated. Serial sectioning, Electron BackScatter Diffraction (EBSD) and a two-step misalignment procedure are performed to reconstruct the 3D microstructure over an extended volume, to assess statistically cracking criteria. A methodology is also developed to compute Grain Boundary (GB) normal orientations based on the EBSD measurements. The statistical analysis shows that cracking occurs preferentially for GB normals aligned with the mechanical loading axis, but also for low values of the Luster-Morris slip transmission parameter. Micromechanical simulations based on the reconstructed 3D microstructure, FFT-based solver and crystal plasticity constitutive equations modified to account for slip transmission at grain boundaries are finally performed. These simulations rationalize the correlation obtained experimentally into a single stress-based criterion. The actual strengths and weaknesses of such micromechanical approach are discussed.
Despite decades of research, metallic corrosion remains a long-standing challenge in many engineering applications. Specifically, designing a material that can resist corrosion both in abiotic as well as biotic environments remains elusive. Here we design a lightweight sulfur-selenium (S-Se) alloy with high stiffness and ductility that can serve as a universal corrosion-resistant coating with protection efficiency of ~99.9% for steel in a wide range of diverse environments. S-Se coated mild steel shows a corrosion rate that is 6-7 orders of magnitude lower than bare metal in abiotic (simulated seawater and sodium sulfate solution) and biotic (sulfate-reducing bacterial medium) environments. The coating is strongly adhesive and mechanically robust. We attribute the high corrosion resistance of the alloy in diverse environments to its semi-crystalline, non-porous, anti-microbial, and viscoelastic nature with superior mechanical performance, enabling it to successfully block a variety of diffusing species.
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