No Arabic abstract
Methanol is an important tracer to probe physical and chemical conditions in the interstellar medium of galaxies. Methanol is also the most sensitive target molecule for probing potential space-time variations of the proton-electron mass ratio, mu, a dimensionless constant of nature. We present an extensive ALMA study of the strongest submillimeter absorption lines of methanol [...] in the z=0.89 molecular absorber toward PKS1830-211, the only high-redshift object in which methanol has been detected. Our goals are to constrain the excitation of the methanol lines and to investigate the cosmological invariance of mu based on their relative kinematics. [...] We explore methanol excitation by running the non local thermal equilibrium radiative transfer code RADEX [...] The excitation analysis points to a cool (~10-20 K) and dense (~10^{4-5} cm-3) methanol gas. [...] In addition, we measure an abundance ratio A/E = 1.0 +/- 0.1, an abundance ratio CH3OH/H2 ~ 2 x 10^{-8}, and a 12CH3OH/13CH3OH ratio 62 +/- 3. Our analysis shows that the bulk velocities of the different transitions are primarily correlated with the observing epoch due to morphological changes in the background quasars emission. There is a weaker correlation between bulk velocities and the lower level energies of the transitions, which could be a signature of temperature-velocity gradients in the absorbing gas. As a result, we do not find evidence for variations of mu, and we estimate Dmu/mu = (-1.8 +/- 1.2) x 10^{-7} at 1sigma from our multivariate linear regression. We set a robust upper limit | Dmu/mu | < 3.6 x 10^{-7} (3sigma) for the invariance of mu at a look-back time of half the present age of the Universe. Our analysis highlights that systematics need to be carefully taken into account in future radio molecular absorption studies aimed at testing Dmu/mu below the 10^{-7} horizon. (Abridged)
We report the detection of OH+ and H2O+ in the z=0.89 absorber toward the lensed quasar PKS1830-211. The abundance ratio of OH+ and H2O+ is used to quantify the molecular hydrogen fraction (fH2) and the cosmic-ray ionization rate of atomic hydrogen (zH) along two lines of sight, located at ~2 kpc and ~4 kpc to either side of the absorbers center. The molecular fraction decreases outwards, from ~0.04 to ~0.02, comparable to values measured in the Milky Way at similar galactocentric radii. For zH, we find values of ~2x10^-14 s^-1 and ~3x10^-15 s^-1, respectively, which are slightly higher than in the Milky Way at comparable galactocentric radii, possibly due to a higher average star formation activity in the z=0.89 absorber. The ALMA observations of OH+, H2O+, and other hydrides toward PKS1830-211 reveal the multi-phase composition of the absorbing gas. Taking the column density ratios along the southwest and northeast lines of sight as a proxy of molecular fraction, we classify the species ArH+, OH+, H2Cl+, H2O+, CH, and HF as tracing gases increasingly more molecular. Incidentally, our data allow us to improve the accuracy of H2O+ rest frequencies and thus refine the spectroscopic parameters.
We present the first results of an ALMA spectral survey of strong absorption lines for common interstellar species in the z=0.89 molecular absorber toward the lensed blazar PKS1830-211. The dataset brings essential information on the structure and composition of the absorbing gas in the foreground galaxy. In particular, we find absorption over large velocity intervals (gtrsim 100 km/s) toward both lensed images of the blazar. This suggests either that the galaxy inclination is intermediate and that we sample velocity gradients or streaming motions in the disk plane, that the molecular gas has a large vertical distribution or extraplanar components, or that the absorber is not a simple spiral galaxy but might be a merger system. The number of detected species is now reaching a total of 42 different species plus 14 different rare isotopologues toward the SW image, and 14 species toward the NE line-of-sight. The abundances of CH, H2O, HCO+, HCN, and NH3 relative to H2 are found to be comparable to those in the Galactic diffuse medium. Of all the lines detected so far toward PKS1830-211, the ground-state line of ortho-water has the deepest absorption. We argue that ground-state lines of water have the best potential for detecting diffuse molecular gas in absorption at high redshift.
We report the first extragalactic detection of chloronium (H2Cl+), in the z=0.89 absorber in front of the lensed blazar PKS1830-211. The ion is detected through its 1_11-0_00 line along two independent lines of sight toward the North-East and South-West images of the blazar. The relative abundance of H2Cl+ is significantly higher (by a factor ~7) in the NE line of sight, which has a lower H2/H fraction, indicating that H2Cl+ preferably traces the diffuse gas component. From the ratio of the H2^35Cl+ and H2^37Cl+ absorptions toward the SW image, we measure a 35Cl/37Cl isotopic ratio of 3.1 (-0.2; +0.3) at z=0.89, similar to that observed in the Galaxy and the solar system.
The z=0.89 molecular absorber toward PKS1830-211 provides us with the opportunity to probe the chemical and physical properties of the interstellar medium in the disk of a galaxy at a look-back time of half the present age of the Universe. Recent ALMA observations of hydrides have unveiled the multi-phase composition of this sources interstellar medium along two absorbing sightlines. Here, we report ALMA observations of CH+ and SH+, and of their 13C- and 34S- isotopologues, as potential tracers of energetic processes in the interstellar medium. CH+ and 13CH+ are detected toward both images of PKS1830-211, CH+ showing the deepest and broadest absorption among all species observed so far. The [CH+]/[13CH+] abundance ratio is ~100 in the south-west line of sight. [...] Toward the north-east image, we find an even larger value of [CH+]/[13CH+], 146 +/- 43, although with a large uncertainty. This sightline intercepts the absorber at a larger galactocentric radius than the southwestern one, where material might be less processed in stellar nucleosynthesis. In contrast to CH+ and its 13C isotopologue, SH+ and 34SH+ are only detected on the south-west sightline. These are the first detections of extragalactic SH+ and interstellar 34SH+. The spectroscopic parameters of SH+ are reevaluated and improved rest frequencies of 34SH+ are obtained. The [CH+]/[SH+] column density ratios show a large difference between the two lines of sight: ~25 and >600 toward the SW and NE image, respectively. We are not able to shed light on the formation process of CH+ and SH+ with these data, but the differences in the two sightlines toward PKS1830-211 suggest that their absorptions arise from gas with molecular fraction gtrsim 10%, with SH+ tracing significantly higher molecular fractions than CH+.
We report the first extragalactic detection of CF+, the fluoromethylidynium ion, in the z=0.89 absorber toward PKS1830-211. We estimate an abundance of ~3E-10 relative to H2 and that ~1% of fluorine is captured in CF+. The absorption line profile of CF+ is found to be markedly different from that of other species observed within the same tuning, and is notably anti-correlated with CH3OH. On the other hand, the CF+ profile resembles that of [C I]. Our results are consistent with expected fluorine chemistry and point to chemical differentiation in the column of absorbing gas.