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We report the detection of OH+ and H2O+ in the z=0.89 absorber toward the lensed quasar PKS1830-211. The abundance ratio of OH+ and H2O+ is used to quantify the molecular hydrogen fraction (fH2) and the cosmic-ray ionization rate of atomic hydrogen (zH) along two lines of sight, located at ~2 kpc and ~4 kpc to either side of the absorbers center. The molecular fraction decreases outwards, from ~0.04 to ~0.02, comparable to values measured in the Milky Way at similar galactocentric radii. For zH, we find values of ~2x10^-14 s^-1 and ~3x10^-15 s^-1, respectively, which are slightly higher than in the Milky Way at comparable galactocentric radii, possibly due to a higher average star formation activity in the z=0.89 absorber. The ALMA observations of OH+, H2O+, and other hydrides toward PKS1830-211 reveal the multi-phase composition of the absorbing gas. Taking the column density ratios along the southwest and northeast lines of sight as a proxy of molecular fraction, we classify the species ArH+, OH+, H2Cl+, H2O+, CH, and HF as tracing gases increasingly more molecular. Incidentally, our data allow us to improve the accuracy of H2O+ rest frequencies and thus refine the spectroscopic parameters.
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We present the first results of an ALMA spectral survey of strong absorption lines for common interstellar species in the z=0.89 molecular absorber toward the lensed blazar PKS1830-211. The dataset brings essential information on the structure and composition of the absorbing gas in the foreground galaxy. In particular, we find absorption over large velocity intervals (gtrsim 100 km/s) toward both lensed images of the blazar. This suggests either that the galaxy inclination is intermediate and that we sample velocity gradients or streaming motions in the disk plane, that the molecular gas has a large vertical distribution or extraplanar components, or that the absorber is not a simple spiral galaxy but might be a merger system. The number of detected species is now reaching a total of 42 different species plus 14 different rare isotopologues toward the SW image, and 14 species toward the NE line-of-sight. The abundances of CH, H2O, HCO+, HCN, and NH3 relative to H2 are found to be comparable to those in the Galactic diffuse medium. Of all the lines detected so far toward PKS1830-211, the ground-state line of ortho-water has the deepest absorption. We argue that ground-state lines of water have the best potential for detecting diffuse molecular gas in absorption at high redshift.
The Large Survey Project (LSP) MeerKAT Absorption Line Survey (MALS) is a blind HI 21-cm and OH 18-cm absorption line survey in the L- and UHF-bands, with the primary goal to better determine the occurrence of atomic and molecular gas in the circum-galactic and inter-galactic medium, and its redshift evolution. Here we present the first results using the UHF-band, obtained towards the strongly lensed radio source PKS1830, detecting absorption in the lens galaxy. With merely 90min of data acquired on-source for science verification and processed using the Automated Radio Telescope Imaging Pipeline (ARTIP), we detect in absorption the known HI 21-cm and OH 18-cm main lines at z=0.89 at an unprecedented signal-to-noise ratio (4000 in the continuum, with 6km/s channels). For the first time we report the detection at z=0.89 of OH satellite lines, so far not detected at z $>$ 0.25. We decompose the OH lines into a thermal and a stimulated contribution, where the 1612 and 1720MHz lines are conjugate. The total OH 1720MHz emission line luminosity is 6100Lsun. This is the most luminous known 1720MHz maser line. The absorption components of the different images of the background source sample different light paths in the lensing galaxy, and their weights in the total absorption spectrum are expected to vary in time, on daily and monthly time scales. We compare our normalized spectra with those obtained more than 20 yrs ago, and find no variation. We interpret the absorption spectra with the help of a lens galaxy model, derived from an N-body hydro-dynamical simulation, with a morphology similar to its optical HST image. It is possible to reproduce the observations without invoking any central gas outflows. There are, however, distinct and faint high-velocity features, most likely high-velocity clouds. These clouds may contribute to broaden the HI and OH spectra.
The z=0.89 molecular absorber toward PKS1830-211 provides us with the opportunity to probe the chemical and physical properties of the interstellar medium in the disk of a galaxy at a look-back time of half the present age of the Universe. Recent ALMA observations of hydrides have unveiled the multi-phase composition of this sources interstellar medium along two absorbing sightlines. Here, we report ALMA observations of CH+ and SH+, and of their 13C- and 34S- isotopologues, as potential tracers of energetic processes in the interstellar medium. CH+ and 13CH+ are detected toward both images of PKS1830-211, CH+ showing the deepest and broadest absorption among all species observed so far. The [CH+]/[13CH+] abundance ratio is ~100 in the south-west line of sight. [...] Toward the north-east image, we find an even larger value of [CH+]/[13CH+], 146 +/- 43, although with a large uncertainty. This sightline intercepts the absorber at a larger galactocentric radius than the southwestern one, where material might be less processed in stellar nucleosynthesis. In contrast to CH+ and its 13C isotopologue, SH+ and 34SH+ are only detected on the south-west sightline. These are the first detections of extragalactic SH+ and interstellar 34SH+. The spectroscopic parameters of SH+ are reevaluated and improved rest frequencies of 34SH+ are obtained. The [CH+]/[SH+] column density ratios show a large difference between the two lines of sight: ~25 and >600 toward the SW and NE image, respectively. We are not able to shed light on the formation process of CH+ and SH+ with these data, but the differences in the two sightlines toward PKS1830-211 suggest that their absorptions arise from gas with molecular fraction gtrsim 10%, with SH+ tracing significantly higher molecular fractions than CH+.
Methanol is an important tracer to probe physical and chemical conditions in the interstellar medium of galaxies. Methanol is also the most sensitive target molecule for probing potential space-time variations of the proton-electron mass ratio, mu, a dimensionless constant of nature. We present an extensive ALMA study of the strongest submillimeter absorption lines of methanol [...] in the z=0.89 molecular absorber toward PKS1830-211, the only high-redshift object in which methanol has been detected. Our goals are to constrain the excitation of the methanol lines and to investigate the cosmological invariance of mu based on their relative kinematics. [...] We explore methanol excitation by running the non local thermal equilibrium radiative transfer code RADEX [...] The excitation analysis points to a cool (~10-20 K) and dense (~10^{4-5} cm-3) methanol gas. [...] In addition, we measure an abundance ratio A/E = 1.0 +/- 0.1, an abundance ratio CH3OH/H2 ~ 2 x 10^{-8}, and a 12CH3OH/13CH3OH ratio 62 +/- 3. Our analysis shows that the bulk velocities of the different transitions are primarily correlated with the observing epoch due to morphological changes in the background quasars emission. There is a weaker correlation between bulk velocities and the lower level energies of the transitions, which could be a signature of temperature-velocity gradients in the absorbing gas. As a result, we do not find evidence for variations of mu, and we estimate Dmu/mu = (-1.8 +/- 1.2) x 10^{-7} at 1sigma from our multivariate linear regression. We set a robust upper limit | Dmu/mu | < 3.6 x 10^{-7} (3sigma) for the invariance of mu at a look-back time of half the present age of the Universe. Our analysis highlights that systematics need to be carefully taken into account in future radio molecular absorption studies aimed at testing Dmu/mu below the 10^{-7} horizon. (Abridged)
We have detected the J=4-3 rotational transition of 12CO in absorption at z=0.89 towards the quasar PKS1830-211, but not the 12CO 5-4 or the 3P1-3P0 fine structure line of neutral carbon. The intervening molecular medium thus has a total 12CO column density of N(CO)~2x10^18 cm^-2, which corresponds to the large column density of molecular hydrogen of N(H2)=2.5x10^22 cm^-2 and a reddening of Av=25 magnitudes. The 12CO excitation temperature is low, below 15 K. Comparison with the molecular absorption results of Wiklind and Combes (1996) shows that the absorbing material has similar molecular abundances to Galactic dark clouds. We find an upper limit for atomic carbon of N(CI)<10^18 cm^-2, which again would be the case for most Galactic dark clouds. We also report new observations of the absorbing system towards B0218+357 at z=0.68. We have tentatively detected the 13CO 4-3 line, but for H2O, although a feature is seen at the correct velocity, due to the inadequate signal to noise ratio we report only an upper limit for the fundamental line of ortho water vapor. The tentative detection of the 13CO J=4-3 line implies that the 13CO excitation temperature is lower than 20K and the column density is fairly large, N(13CO)~10^17 cm^-2, giving rise to saturated absorption in the J=2-1 transition. The total column density of molecular gas is again large in this source, N(H2)>2x10^22 cm^-2, corresponding to a reddening >20 magnitudes.
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