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Register a new userDetection of extragalactic CF+ toward PKS1830-211 -- Chemical differentiation in the absorbing gas
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We report the first extragalactic detection of CF+, the fluoromethylidynium ion, in the z=0.89 absorber toward PKS1830-211. We estimate an abundance of ~3E-10 relative to H2 and that ~1% of fluorine is captured in CF+. The absorption line profile of CF+ is found to be markedly different from that of other species observed within the same tuning, and is notably anti-correlated with CH3OH. On the other hand, the CF+ profile resembles that of [C I]. Our results are consistent with expected fluorine chemistry and point to chemical differentiation in the column of absorbing gas.
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We report the detection of OH+ and H2O+ in the z=0.89 absorber toward the lensed quasar PKS1830-211. The abundance ratio of OH+ and H2O+ is used to quantify the molecular hydrogen fraction (fH2) and the cosmic-ray ionization rate of atomic hydrogen (zH) along two lines of sight, located at ~2 kpc and ~4 kpc to either side of the absorbers center. The molecular fraction decreases outwards, from ~0.04 to ~0.02, comparable to values measured in the Milky Way at similar galactocentric radii. For zH, we find values of ~2x10^-14 s^-1 and ~3x10^-15 s^-1, respectively, which are slightly higher than in the Milky Way at comparable galactocentric radii, possibly due to a higher average star formation activity in the z=0.89 absorber. The ALMA observations of OH+, H2O+, and other hydrides toward PKS1830-211 reveal the multi-phase composition of the absorbing gas. Taking the column density ratios along the southwest and northeast lines of sight as a proxy of molecular fraction, we classify the species ArH+, OH+, H2Cl+, H2O+, CH, and HF as tracing gases increasingly more molecular. Incidentally, our data allow us to improve the accuracy of H2O+ rest frequencies and thus refine the spectroscopic parameters.
The z=0.89 molecular absorber toward PKS1830-211 provides us with the opportunity to probe the chemical and physical properties of the interstellar medium in the disk of a galaxy at a look-back time of half the present age of the Universe. Recent ALMA observations of hydrides have unveiled the multi-phase composition of this sources interstellar medium along two absorbing sightlines. Here, we report ALMA observations of CH+ and SH+, and of their 13C- and 34S- isotopologues, as potential tracers of energetic processes in the interstellar medium. CH+ and 13CH+ are detected toward both images of PKS1830-211, CH+ showing the deepest and broadest absorption among all species observed so far. The [CH+]/[13CH+] abundance ratio is ~100 in the south-west line of sight. [...] Toward the north-east image, we find an even larger value of [CH+]/[13CH+], 146 +/- 43, although with a large uncertainty. This sightline intercepts the absorber at a larger galactocentric radius than the southwestern one, where material might be less processed in stellar nucleosynthesis. In contrast to CH+ and its 13C isotopologue, SH+ and 34SH+ are only detected on the south-west sightline. These are the first detections of extragalactic SH+ and interstellar 34SH+. The spectroscopic parameters of SH+ are reevaluated and improved rest frequencies of 34SH+ are obtained. The [CH+]/[SH+] column density ratios show a large difference between the two lines of sight: ~25 and >600 toward the SW and NE image, respectively. We are not able to shed light on the formation process of CH+ and SH+ with these data, but the differences in the two sightlines toward PKS1830-211 suggest that their absorptions arise from gas with molecular fraction gtrsim 10%, with SH+ tracing significantly higher molecular fractions than CH+.
Deuterium and lithium are light elements of high cosmological and astrophysical importance. In this work we report the first detection of deuterated molecules and a search for lithium hydride, 7LiH, at redshift z=0.89 in the spiral galaxy intercepting the line of sight to the quasar PKS1830-211. We used ALMA to observe several submillimeter lines of ND, NH2D, and HDO, and their related isotopomers NH2, NH3, and H2^18O, in absorption against the southwest image of the quasar, allowing us to derive XD/XH abundance ratios. The absorption spectra mainly consist of two distinct narrow velocity components for which we find remarkable differences. One velocity component shows XD/XH abundances that is about 10 times larger than the primordial elemental D/H ratio, and no variability of the absorption profile during the time span of our observations. [...] The second component has XD/XH abundances that are 100 times larger than the primordial D/H ratio, a deepening of the absorption by a factor of two within a few months, and a rich chemical composition, with relative enhancements of N2H+, CH3OH, SO2, and complex organic molecules. We therefore speculate that this component is associated with the analog of a Galactic dark cloud, while the first component is likely more diffuse. Our search for the 7LiH (1--0) line was unsuccessful and we derive an upper limit 7LiH/H2 = 4 x 10^-13 (3sigma) in the z=0.89 absorber toward PKS1830-211. Besides, with ALMA archival data, we could not confirm the previous tentative detections of this line in the z=0.68 absorber toward B0218+357; we derive an upper limit 7LiH/H2 = 5 x 10^-11 (3sigma), although this is less constraining than our limit toward PKS1830-211. We conclude that, as in the Milky Way, only a tiny fraction of lithium nuclei are possibly bound in LiH in these absorbers at intermediate redshift.
We report the first extragalactic detection of chloronium (H2Cl+), in the z=0.89 absorber in front of the lensed blazar PKS1830-211. The ion is detected through its 1_11-0_00 line along two independent lines of sight toward the North-East and South-West images of the blazar. The relative abundance of H2Cl+ is significantly higher (by a factor ~7) in the NE line of sight, which has a lower H2/H fraction, indicating that H2Cl+ preferably traces the diffuse gas component. From the ratio of the H2^35Cl+ and H2^37Cl+ absorptions toward the SW image, we measure a 35Cl/37Cl isotopic ratio of 3.1 (-0.2; +0.3) at z=0.89, similar to that observed in the Galaxy and the solar system.
We used the new IRAM 30-m FTS backend to perform an unbiased ~15 GHz wide survey at 3 mm toward the Pipe Nebula young diffuse starless cores. We found an unexpectedly rich chemistry. We propose a new observational classification based on the 3 mm molecular line emission normalized by the core visual extinction (Av). Based on this classification, we report a clear differentiation in terms of chemical composition and of line emission properties, which served to define three molecular core groups. The diffuse cores, Av<~15, show poor chemistry with mainly simple species (e.g. CS and CCH). The oxo-sulfurated cores, Av~15--22, appear to be abundant in species like SO and SO2, but also in HCO, which seem to disappear at higher densities. Finally, the deuterated cores, Av>~22, show typical evolved chemistry prior to the onset of the star formation process, with nitrogenated and deuterated species, as well as carbon chain molecules. Based on these categories, one of the diffuse cores (Core 47) has the spectral line properties of the oxo-sulfurated ones, which suggests that it is a possible failed core.
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