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Reflections on the photodissociation of CO in circumstellar envelopes

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 Added by Martin Groenewegen
 Publication date 2021
  fields Physics
and research's language is English




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Carbon monoxide (CO) is the most abundant molecule after molecular hydrogen and is important for the chemistry in circumstellar envelopes around evolved stars. When modelling the strength and shape of molecular lines, the size of the CO envelope is an input parameter and influences the derived mass-loss rates. In particular the low-J transition CO lines are sensitive to the CO photodissociation radius. Recently, new CO photodissociation radii have been published using different formalisms that differ considerably. One set of calculations is based on an escape-probability formalisms that uses numerical approximations derived in the early-eighties. The accuracy of these approximations is investigated and it is shown that they are less accurate than claimed. Improved formalism are derived. Nevertheless, the changes in CO envelope size are small to moderate, less than 2% for models with $10^{-7}< dot{M}< 10^{-4}$ msolyr and at most 7% for model with $dot{M} = 10^{-8}$ msolyr.



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67 - M.A.T. Groenewegen 2017
Carbon monoxide is the most abundant molecule after H$_2$ and is important for chemistry in circumstellar envelopes around late-type stars. The size of the envelope is important when modelling low-J transition lines and deriving mass-loss rates from such lines. Now that ALMA is coming to full power the extent of the CO emitting region can be measured directly for nearby asymptotic giant branch (AGB) stars. In parallel, it has become obvious in the past few years that the strength of the interstellar radiation field (ISRF) can have a significant impact on the interpretation of the emission lines. In this paper an update and extension of the classical Mamon et al. (1988; ApJ 328, 797) paper is presented; these authors provided the CO abundance profile, described by two parameters, as a function of mass-loss rate and expansion velocity. Following recent work an improved numerical method and updated H$_2$ and CO shielding functions are used and a larger grid is calculated that covers more parameter space, including the strength of the ISRF. The effect of changing the photodissociation radius on the low-J CO line intensities is illustrated in two cases.
Ultraviolet (UV) photodissociation of CO controls the abundances and distribution of CO and its photodissociation products. This significantly influences the gas-phase chemistry in the circumstellar envelope (CSE) around evolved stars. A better understanding of CO photodissociation in outflows also provides a more precise estimate of mass-loss rates. We aim to update the CO photodissociation rate in an expanding spherical envelope assuming that the interstellar radiation field (ISRF) photons penetrate through the envelope. This will allow us to precisely estimate the CO abundance distributions in CSEs around evolved stars. We used the most recent CO spectroscopic data to precisely calculate the depth dependency of the photodissociation rate of each CO dissociating line. We calculated the CO self- and mutual-shielding functions in an expanding envelope. We investigated the dependence of the CO profile on the five fundamental parameters mass-loss rate, the expansion velocity, the CO initial abundance, the CO excitation temperature, and the strength of the ISRF. Our derived CO envelope size is smaller than the commonly used radius derived by Mamon et al. 1988. The difference between results varies from 1% to 39% and depends on the H2 and CO densities of the envelope. We list two fitting parameters for a large grid of models to estimate the CO abundance distribution. We demonstrate that the CO envelope size can differ between outflows with the same effective content of CO, but different CO abundance, mass-loss rate, and the expansion velocity as a consequence of differing amounts of shielding by H2 and CO. We find that the abundance of CO close to the star and the outflow density both can have a significant effect on the size of the molecular envelope. We also demonstrate that modest variations in the ISRF can cause measurable differences in the envelope extent.
The recent detection of fullerene (C$_{60}$) in space and the positive assignment of five diffuse interstellar bands to C$_{60}^+$ reinforce the notion that fullerene-related compounds can be efficiently formed in circumstellar envelopes and be present in significant quantities in the interstellar medium. Experimental studies have shown that C$_{60}$ can be readily hydrogenated, raising the possibility that hydrogenated fullerenes (or fulleranes, C$_{60}$H$_m$, $m=1-60$) may be abundant in space. In this paper, we present theoretical studies of the vibrational modes of isomers of C$_{60}$H$_m$. Our results show that the four mid-infrared bands from the C$_{60}$ skeletal vibrations remain prominent in slightly hydrogenated C$_{60}$, but their strengths diminish in different degrees with increasing hydrogenation. It is therefore possible that the observed infrared bands assigned to C$_{60}$ could be due to a mixture of fullerenes and fulleranes. This provides a potential explanation for the observed scatter of the C$_{60}$ band ratios. Our calculations suggest that a feature around 15$mu$m due to the breathing mode of heavily hydrogenated C$_{60}$ may be detectable astronomically. A preliminary search for this feature in 35 C$_{60}$ sources is reported.
103 - P.N. Diep , D.T. Hoai , P.T. Nhung 2015
Studies of the CO and HI radio emission of some evolved stars are presented using data collected by the IRAM Plateau de Bure interferometer and Pico Veleta telescope, the Nanc{c}ay Radio Telescope and the JVLA and ALMA arrays. Approximate axial symmetry of the physical and kinematic properties of the circumstellar envelope (CSE) are observed in CO emission, in particular, from RS Cnc, EP Aqr and the Red Rectangle. A common feature is the presence of a bipolar outflow causing an enhanced wind velocity in the polar directions. HI emission extends to larger radial distances than probed by CO emission and displays features related to the interaction between the stellar outflow and interstellar matter. With its unprecedented sensitivity, FAST will open a new window on such studies. Its potential in this domain is briefly illustrated.
The small-scale bipolar jets having short dynamical ages from water fountain (WF) sources are regarded as an indication of the onset of circumstellar envelope morphological metamorphosis of intermediate-mass stars. Such process usually happens at the end of the asymptotic giant branch (AGB) phase. However, recent studies found that WFs could be AGB stars or even early planetary nebulae. This fact prompted the idea that WFs may not necessarily be objects at the beginning of the morphological transition process. In the present work, we show that WFs could have different envelope morphologies by studying their spectral energy distribution profiles. Some WFs have spherical envelopes that resembles usual AGB stars, while others have aspherical envelopes which are more common to post-AGB stars. The results imply that WFs may not represent the earliest stage of the morphological metamorphosis. We further argue that the dynamical age of a WF jet, which can be calculated from maser proper motions, may not be the real age of the jet. The dynamical age cannot be used to justify the moment when the envelope begins to become aspherical, nor to tell the concrete evolutionary status of the object. A WF jet could be the innermost part of a larger well-developed jet, which is not necessarily a young jet.
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