No Arabic abstract
Since the discovery of superconductivity in a high-entropy alloy (HEA) Ti-Zr-Nb-Hf-Ta in 2014, the community of superconductor science has explored new HEA superconductors to find the merit of the HEA states on superconducting properties. Since 2018, we have developed HEA-type compounds as superconductors or thermoelectric materials. As well known, compounds like intermetallic compounds or layered compounds are composed of multi crystallographic sites. In a HEA-type compounds, one or more sites are alloyed and total mixing entropy satisfies with the criterion of HEA. Herein, we summarize the synthesis methods, the crystal structural variation and superconducting properties of the HEA-type compounds, which include NaCl-type metal tellurides, CuAl2-type transition metal zirconides, high-Tc cuprates, and BiS2-based layered superconductors. The effects of the introduction of a HEA site in various kinds of complicated compounds are discussed from the structural-dimensionality viewpoint.
The out-of-plane intercalate phonons of superconducting YbC6 have been measured with inelastic x-ray scattering. Model fits to this data, and previously measured out-of-plane intercalate phonons in graphite intercalation compounds (GICs), reveal surprising trends with the superconducting transition temperature. These trends suggest that superconducting GICs should be viewed as electron-doped graphite.
We discovered a novel annealing method for Fe-chalcogenide superconductors. It was found that sulfur annealing deintercalated excess Fe via formation of FeS2. Due to its specifics, sulfur annealing is applicable when preparing Fe-chalcogenide-based wires or cables.
We report the discovery of superconductivity in pressurized CeRhGe3, until now the only remaining non-superconducting member of the isostructural family of non-centrosymmetric heavy-fermion compounds CeTX3 (T = Co, Rh, Ir and X = Si, Ge). Superconductivity appears in CeRhGe3 at a pressure of 19.6 GPa and the transition temperature Tc reaches a maximum value of 1.3 K at 21.5 GPa. This finding provides an opportunity to establish systematic correlations between superconductivity and materials properties within this family. Though ambient-pressure unit-cell volumes and critical pressures for superconductivity vary substantially across the series, all family members reach a maximum Tcmax at a common critical cell volume Vcrit, and Tcmax at Vcrit increases with increasing spin-orbit coupling strength of the d-electrons. These correlations show that substantial Kondo hybridization and spin-orbit coupling favor superconductivity in this family, the latter reflecting the role of broken centro-symmetry.
We succeeded in growing a single crystal of Ce2CoIn8 by the flux method. The results of specific heat and electrical resistivity measurements indicate that Ce2CoIn8 is a heavy-fermion superconductor below 0.4 K with an electronic specific heat coefficient gamma as large as 500 mJ/K^2mol-Ce.
On the basis of first-principles calculations, we propose a superconductivity of carbon compounds with a sodalite structure, which is similar to a hydrogen compound with a very high superconducting transition temperature, $T_{rm c}$. Our systematic calculation shows that some of these carbon compounds have a $T_{rm c}$ of up to about 100 K at a pressure of about 30 GPa, which is lower than that of superconducting hydrides (above 100 GPa). The obtained phonon dispersions appear to be similar to each other, and this suggests that the sodalite structure may be a key to generating phonon-mediated high-$T_{rm c}$ superconductivity.