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Register a new userChemistry of Temperate Super-Earth and Mini-Neptune Atmospheric Hazes from Laboratory Experiments
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Very little experimental work has been done to explore the properties of photochemical hazes formed in atmospheres with very different compositions or temperatures than that of the outer solar system or of early Earth. With extrasolar planet discoveries now numbering thousands, this untapped phase space merits exploration. This study presents measured chemical properties of haze particles produced in laboratory analogues of exoplanet atmospheres. We used very high resolution mass spectrometry to measure the chemical components of solid particles produced in atmospheric chamber experiments. Many complex molecular species with general chemical formulas C$_w$H$_x$N$_y$O$_z$ were detected. We detect molecular formulas of prebiotic interest in the data, including those for the monosaccharide glyceraldehyde, a variety of amino acids and nucleotide bases, and several sugar derivatives. Additionally, the experimental exoplanetary haze analogues exhibit diverse solubility characteristics, which provide insight into the possibility of further chemical or physical alteration of photochemical hazes in super-Earth and mini-Neptune atmospheres. These exoplanet analogue particles can help us better understand chemical atmospheric processes and suggest a possible source of in situ atmospheric prebiotic chemistry on distant worlds.
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The atmospheric composition of exoplanets with masses between 2 and 10 M$_oplus$ is poorly understood. In that regard, the sub-Neptune K2-18b, which is subject to Earth-like stellar irradiation, offers a valuable opportunity for the characterisation of such atmospheres. Previous analyses of its transmission spectrum from the Kepler, Hubble (HST), and Spitzer space telescopes data using both retrieval algorithms and forward-modelling suggest the presence of H$_2$O and an H$_2$--He atmosphere, but have not detected other gases, such as CH$_4$. We present simulations of the atmosphere of K2-18 b using Exo-REM, our self-consistent 1D radiative-equilibrium model, using a large grid of atmospheric parameters to infer constraints on its chemical composition. We show that our simulations favour atmospheric metallicities between 40 and 500 times solar and indicate, in some cases, the formation of H$_2$O-ice clouds, but not liquid H$_2$O clouds. We also confirm the findings of our previous study, which showed that CH$_4$ absorption features nominally dominate the transmission spectrum in the HST spectral range. We compare our results with results from retrieval algorithms and find that the H$_2$O-dominated spectrum interpretation is either due to the omission of CH$_4$ absorptions or a strong overfitting of the data. Finally, we investigated different scenarios that would allow for a CH$_4$-depleted atmosphere. We were able to fit the data to those scenarios, finding, however, that it is very unlikely for K2-18b to have a high internal temperature. A low C/O ratio ($approx$ 0.01--0.1) allows for H$_2$O to dominate the transmission spectrum and can fit the data but so far, this set-up lacks a physical explanation. Simulations with a C/O ratio $<$ 0.01 are not able to fit the data satisfactorily.
HD3167 is a bright (V=8.9 mag) K0V star observed by the NASAs K2 space mission during its Campaign 8. It has been recently found to host two small transiting planets, namely, HD3167b, an ultra short period (0.96 d) super-Earth, and HD3167c, a mini-Neptune on a relatively long-period orbit (29.85 d). Here we present an intensive radial velocity follow-up of HD3167 performed with the FIES@NOT, [email protected], and HARPS-N@TNG spectrographs. We revise the system parameters and determine radii, masses, and densities of the two transiting planets by combining the K2 photometry with our spectroscopic data. With a mass of 5.69+/-0.44 MEarth, radius of 1.574+/-0.054 REarth, and mean density of 8.00(+1.0)(-0.98) g/cm^3, HD3167b joins the small group of ultra-short period planets known to have a rocky terrestrial composition. HD3167c has a mass of 8.33 (+1.79)(-1.85) MEarth and a radius of 2.740(+0.106)(-0.100) REarth, yielding a mean density of 2.21(+0.56)(-0.53) g/cm^3, indicative of a planet with a composition comprising a solid core surrounded by a thick atmospheric envelope. The rather large pressure scale height (about 350 km) and the brightness of the host star make HD3167c an ideal target for atmospheric characterization via transmission spectroscopy across a broad range of wavelengths. We found evidence of additional signals in the radial velocity measurements but the currently available data set does not allow us to draw any firm conclusion on the origin of the observed variation.
GJ1214b is thought to be either a mini-Neptune with a thick, hydrogen-rich atmosphere, or a planet with a composition dominated by water. In the case of a hydrogen-rich atmosphere, molecular absorption and scattering processes may result in detectable radius variations as a function of wavelength. The aim of this paper is to measure these variations. We have obtained observations of the transit of GJ1214b in the r- and I-band with the INT, in the g, r, i and z bands with the 2.2 meter MPI/ESO telescope, in the Ks-band with the NOT, and in the Kc-band with the WHT. By comparing the transit depth between the the different bands, which is a measure for the planet-to-star size ratio, the atmosphere is investigated. We do not detect clearly significant variations in the planet-to-star size ratio as function of wavelength. Although the ratio at the shortest measured wavelength, in g-band, is 2sigma larger than in the other bands. The uncertainties in the Ks and Kc bands are large, due to systematic features in the light curves. The tentative increase in the planet-to-star size ratio at the shortest wavelength could be a sign of an increase in the effective planet-size due to Rayleigh scattering, which would require GJ1214b to have a hydrogen-rich atmosphere. If true, then the atmosphere has to have both clouds, to suppress planet-size variations at red optical wavelengths, as well as a sub-solar metallicity, to suppress strong molecular features in the near- and mid-infrared. However, star spots, which are known to be present on the hoststars surface, can (partly) cancel out the expected variations in planet-to-star size ratio, due to the lower surface temperature of the spots . A hypothetical spot-fraction of 10% would be able to raise the infrared points sufficiently with respect to the optical measurements to be inconsistent with a water-dominated atmosphere. [abridged]
Precise atmospheric observations have been made for a growing sample of warm Neptunes. Here we investigate the correlations between these observations and a large number of system parameters to show that, at 95% confidence, the amplitude of a warm Neptunes spectral features in transmission correlates with either its equilibrium temperature (T_eq) or its bulk H/He mass fraction (f_HHe) --- in addition to the standard kT/mg scaling. These correlations could indicate either more optically-thick, photochemically-produced hazes at lower T_eq and/or higher-metallicity atmospheres for planets with smaller radii and lower f_HHe. %Since hazes must exist in some of these planets, we favor the former explanation. We derive an analytic relation to estimate the observing time needed with JWST/NIRISS to confidently distinguish a nominal gas giants transmission spectrum from a flat line. Using this tool, we show that these possible atmospheric trends could reduce the number of expected TESS planets accessible to JWST spectroscopy by up to a factor of eight. Additional observations of a larger sample of planets are required to confirm these trends in atmospheric properties as a function of planet or system quantities. If these trends can be confidently identified, the community will be well-positioned to prioritize new targets for atmospheric study and eventually break the complex degeneracies between atmospheric chemistry, composition, and cloud properties.
We detect Lyman $alpha$ absorption from the escaping atmosphere of HD 63433c, a $R=2.67 R_oplus$, $P=20.5$ d mini Neptune orbiting a young (440 Myr) solar analogue in the Ursa Major Moving Group. Using HST/STIS, we measure a transit depth of $11.1 pm 1.5$% in the blue wing and $8 pm 3$% in the red. This signal is unlikely to be due to stellar variability, but should be confirmed by an upcoming second visit with HST. We do not detect Lyman $alpha$ absorption from the inner planet, a smaller $R=2.15 R_oplus$ mini Neptune on a 7.1 d orbit. We use Keck/NIRSPEC to place an upper limit of 0.5% on helium absorption for both planets. We measure the host stars X-ray spectrum and FUV flux with XMM-Newton, and model the outflow from both planets using a 3D hydrodynamic code. This model provides a reasonable match to the light curve in the blue wing of the Lyman $alpha$ line and the helium non-detection for planet c, although it does not explain the tentative red wing absorption or reproduce the excess absorption spectrum in detail. Its predictions of strong Lyman $alpha$ and helium absorption from b are ruled out by the observations. This model predicts a much shorter mass loss timescale for planet b, suggesting that b and c are fundamentally different: while the latter still retains its hydrogen/helium envelope, the former has likely lost its primordial atmosphere.
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