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Register a new userMagnetic glassy state at low spin state of Co3+ in EuBaCo2O5+{delta} ({delta} = 0.47) cobaltite
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The magnetic glassy state is a fascinating phenomenon, which results from the kinetic arrest of the first order magnetic phase transition. Interesting properties, such as metastable magnetization and nonequilibrium magnetic phases, are naturally developed in the magnetic glassy state. Here, we report magnetic glass property in the low spin state of Co3+ in EuBaCo2O5+{delta} ({delta} = 0.47) cobaltite at low temperature (T < 60 K). The measurements of magnetization under the cooling and heating in unequal fields, magnetization relaxation and thermal cycling of magnetization show the kinetic arrest of low magnetization state below 60 K. The kinetically arrested low temperature magnetic phase is further supported through the study of isothermal magnetic entropy, which shows the significant entropy change. The present results will open a new window to search the microscopic relation between the spin state transitions and the kinetic arrest induced magnetic glassy phenomena in complex materials.
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The structural, magnetic and transport properties of the layered RBaCo$_2$O$_{5.5}$ cobaltites are sensitive to the oxygen stoichiometry. In this present study, we report the presence of a low-temperature magnetic glassy state in electron-doped polycrystalline YBaCo$_2$O$_{5.5}$ cobaltite. The ac magnetization studies show the absence of conventional spin glass features, while the various dc magnetization studies demonstrate the presence of non-equilibrium magnetic glassy state at low temperature. The magnetic glassy state of this sample results from the kinetic arrest of the first order ferro (or ferri) to antiferromagnetic transition. The role of electron doping in the occurrence of magnetic glassy phenomena is discussed in terms of magnetic phase separation involving the Co3+/Co2+ clusters of the ferrimagnetic phase in the Co3+/Co3+ antiferromagnetic matrix.
Using an optimized bridge geometry we have been able to make accurate measurements of the properties of YBa2Cu3O7-delta grain boundaries above Tc. The results show a strong dependence of the change of resistance with temperature on grain boundary angle. Analysis of our results in the context of band-bending allows us to estimate the height of the potential barrier present at the grain boundary interface.
Secondary batteries are important energy storage devices for a mobile equipment, an electric car, and a large-scale energy storage. Nevertheless, variation of the local electronic state of the battery materials in the charge (or oxidization) process are still unclear. Here, we investigated the local electronic state of cobalt-hexacyanoferrate (Na$_x$Co[Fe(CN)$_6$]$_{0.9}$), by means of resonant inelastic X-ray scattering (RIXS) with high energy resolution (~100 meV). The L-edge RIXS is one of the most powerful spectroscopic technique with element- and valence-selectivity. We found that the local electronic state around Co$^{2+}$ in the partially-charged Na$_{1.1}$Co$^{2+}$$_{0.5}$Co$^{3+}$$_{0.5}$[Fe$^{2+}$(CN)$_6$]$_{0.9}$ film (x = 1.1) is the same as that of the discharged Na$_{1.6}$Co$^{2+}$[Fe$^{2+}$(CN)$_6$]$_{0.9}$ film (x = 1.6) within the energy resolution, indicating that the local electronic state around Co$^{2+}$ is invariant against the partial oxidization. In addition, the local electronic state around the oxidized Co$^{3+}$ is essentially the same as that of the fully-charged film Co$^{3+}$[Fe$^{2+}$(CN)$_6$]$_{0.3}$[Fe$^{3+}$(CN)$_6$]$_{0.6}$ (x = 0.0) film. Such a strong localization of the oxidized Co$^{3+}$ state is advantageous for the reversibility of the redox process, since the localization reduces extra reaction within the materials and resultant deterioration.
Ab-initio relativistic dynamical mean-field theory is applied to resolve the long-standing controversy between theory and experiment in the simple face-centered cubic phase of plutonium called delta-Pu. In agreement with experiment, neither static nor dynamical magnetic moments are predicted. In addition, the quasiparticle density of states reproduces not only the peak close to the Fermi level, which explains the large coefficient of electronic specific heat, but also main 5f features observed in photoelectron spectroscopy.
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