No Arabic abstract
Heat engines used to output useful work have important practical significance, which, in general, operate between heat baths of infinite size and constant temperature. In this paper we study the efficiency of a heat engine operating between two finite-size heat sources with initial temperature differences. The total output work of such heat engine is limited due to the finite heat capacity of the sources. We investigate the effects of different heat capacity characteristics of the sources on the heat engines efficiency at maximum work (EMW) in the quasi-static limit. In addition, we study the efficiency of the engine working in finite-time with maximum power of each cycle is achieved and find the efficiency follows a simple universality as $eta=eta_{mathrm{C}}/4+Oleft(eta_{mathrm{C}}^{2}right)$. Remarkably, when the heat capacity of the heat source is negative, such as the black holes, we show that the heat engine efficiency during the operation can surpass the Carnot efficiency determined by the initial temperature of the heat sources. It is further argued that the heat engine between two black holes with vanishing initial temperature difference can be driven by the energy fluctuation. The corresponding EMW is proved to be $eta_{mathrm{EMW}}=2-sqrt{2}$, which is two time of the maximum energy release rate $mu=left(2-sqrt{2}right)/2approx0.29$ of two black hole emerging process obtained by S. W. Hawking.
The second law of thermodynamics constrains that the efficiency of heat engines, classical or quantum, cannot be greater than the universal Carnot efficiency. We discover another bound for the efficiency of a quantum Otto heat engine consisting of a harmonic oscillator. Dynamics of the engine is governed by the Lindblad equation for the density matrix, which is mapped to the Fokker-Planck equation for the quasi-probability distribution. Applying stochastic thermodynamics to the Fokker-Planck equation system, we obtain the $hbar$-dependent quantum mechanical bound for the efficiency. It turns out that the bound is tighter than the Carnot efficiency. The engine achieves the bound in the low temperature limit where quantum effects dominate. Our work demonstrates that quantum nature could suppress the performance of heat engines in terms of efficiency bound, work and power output.
The Curzon-Ahlborn (CA) efficiency, as the efficiency at the maximum power (EMP) of the endoreversible Carnot engine, has significant impact in finite-time thermodynamics. In the past two decades, a lot of efforts have been made to seek a microscopic theory of the CA efficiency. It is generally believed that the CA efficiency is approached in the symmetric low-dissipation regime of dynamical models. Contrary to the general belief, without the low-dissipation assumption, we formulate a microscopic theory of the CA engine realized with an underdamped Brownian particle in a class of non-harmonic potentials. This microscopic theory not only explains the dynamical origin of all assumptions made by Curzon and Ahlborn, but also confirms that in the highly underdamped regime, the CA efficiency is always the EMP irrespective of the symmetry of the dissipation. The low-dissipation regime is included in the microscopic theory as a special case. Also, based on this theory, we obtain the control scheme associated with the maximum power for any given efficiency, as well as analytical expressions of the power and the efficiency statistics for the Brownian CA engine. Our research brings new perspectives to experimental study of finite-time microscopic heat engines featured with fluctuations.
We introduce a simple two-level heat engine to study the efficiency in the condition of the maximum power output, depending on the energy levels from which the net work is extracted. In contrast to the quasi-statically operated Carnot engine whose efficiency reaches the theoretical maximum, recent research on more realistic engines operated in finite time has revealed other classes of efficiency such as the Curzon-Ahlborn efficiency maximizing the power output. We investigate yet another side with our heat engine model, which consists of pure relaxation and net work extraction processes from the population difference caused by different transition rates. Due to the nature of our model, the time-dependent part is completely decoupled from the other terms in the generated work. We derive analytically the optimal condition for transition rates maximizing the generated power output and discuss its implication on general premise of realistic heat engines. In particular, the optimal engine efficiency of our model is different from the Curzon-Ahlborn efficiency, although they share the universal linear and quadratic coefficients at the near-equilibrium limit. We further confirm our results by taking an alternative approach in terms of the entropy production at hot and cold reservoirs.
Microorganisms such as bacteria are active matters which consume chemical energy and generate their unique run-and-tumble motion. A swarm of such microorganisms provide a nonequilibrium active environment whose noise characteristics are different from those of thermal equilibrium reservoirs. One important difference is a finite persistence time, which is considerably large compared to that of the equilibrium noise, that is, the active noise is colored. Here, we study a mesoscopic energy-harvesting device (engine) with active reservoirs harnessing this noise nature. For a simple linear model, we analytically show that the engine efficiency can surpass the conventional Carnot bound, thus the power-efficiency tradeoff constraint is released, and the efficiency at the maximum power can overcome the Curzon-Ahlborn efficiency. We find that the supremacy of the active engine critically depends on the time-scale symmetry of two active reservoirs.