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Brownian heat engine with active reservoirs

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 Added by Hyunggyu Park
 Publication date 2020
  fields Physics
and research's language is English




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Microorganisms such as bacteria are active matters which consume chemical energy and generate their unique run-and-tumble motion. A swarm of such microorganisms provide a nonequilibrium active environment whose noise characteristics are different from those of thermal equilibrium reservoirs. One important difference is a finite persistence time, which is considerably large compared to that of the equilibrium noise, that is, the active noise is colored. Here, we study a mesoscopic energy-harvesting device (engine) with active reservoirs harnessing this noise nature. For a simple linear model, we analytically show that the engine efficiency can surpass the conventional Carnot bound, thus the power-efficiency tradeoff constraint is released, and the efficiency at the maximum power can overcome the Curzon-Ahlborn efficiency. We find that the supremacy of the active engine critically depends on the time-scale symmetry of two active reservoirs.

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The Curzon-Ahlborn (CA) efficiency, as the efficiency at the maximum power (EMP) of the endoreversible Carnot engine, has significant impact in finite-time thermodynamics. In the past two decades, a lot of efforts have been made to seek a microscopic theory of the CA efficiency. It is generally believed that the CA efficiency is approached in the symmetric low-dissipation regime of dynamical models. Contrary to the general belief, without the low-dissipation assumption, we formulate a microscopic theory of the CA engine realized with an underdamped Brownian particle in a class of non-harmonic potentials. This microscopic theory not only explains the dynamical origin of all assumptions made by Curzon and Ahlborn, but also confirms that in the highly underdamped regime, the CA efficiency is always the EMP irrespective of the symmetry of the dissipation. The low-dissipation regime is included in the microscopic theory as a special case. Also, based on this theory, we obtain the control scheme associated with the maximum power for any given efficiency, as well as analytical expressions of the power and the efficiency statistics for the Brownian CA engine. Our research brings new perspectives to experimental study of finite-time microscopic heat engines featured with fluctuations.
The equilibrium properties of a system of passive diffusing particles in an external magnetic field are unaffected by the Lorentz force. In contrast, active Brownian particles exhibit steady-state phenomena that depend on both the strength and the polarity of the applied magnetic field. The intriguing effects of the Lorentz force, however, can only be observed when out-of-equilibrium density gradients are maintained in the system. To this end, we use the method of stochastic resetting on active Brownian particles in two dimensions by resetting them to the line $x=0$ at a constant rate and periodicity in the $y$ direction. Under stochastic resetting, an active system settles into a nontrivial stationary state which is characterized by an inhomogeneous density distribution, polarization and bulk fluxes perpendicular to the density gradients. We show that whereas for a uniform magnetic field the properties of the stationary state of the active system can be obtained from its passive counterpart, novel features emerge in the case of an inhomogeneous magnetic field which have no counterpart in passive systems. In particular, there exists an activity-dependent threshold rate such that for smaller resetting rates, the density distribution of active particles becomes non-monotonic. We also study the mean first-passage time to the $x$ axis and find a surprising result: it takes an active particle more time to reach the target from any given point for the case when the magnetic field increases away from the axis. The theoretical predictions are validated using Brownian dynamics simulations.
The Carnot cycle imposes a fundamental upper limit to the efficiency of a macroscopic motor operating between two thermal baths. However, this bound needs to be reinterpreted at microscopic scales, where molecular bio-motors and some artificial micro-engines operate. As described by stochastic thermodynamics, energy transfers in microscopic systems are random and thermal fluctuations induce transient decreases of entropy, allowing for possible violations of the Carnot limit. Despite its potential relevance for the development of a thermodynamics of small systems, an experimental study of microscopic Carnot engines is still lacking. Here we report on an experimental realization of a Carnot engine with a single optically trapped Brownian particle as working substance. We present an exhaustive study of the energetics of the engine and analyze the fluctuations of the finite-time efficiency, showing that the Carnot bound can be surpassed for a small number of non-equilibrium cycles. As its macroscopic counterpart, the energetics of our Carnot device exhibits basic properties that one would expect to observe in any microscopic energy transducer operating with baths at different temperatures. Our results characterize the sources of irreversibility in the engine and the statistical properties of the efficiency -an insight that could inspire novel strategies in the design of efficient nano-motors.
Active particles may happen to be confined in channels so narrow that they cannot overtake each other (Single File conditions). This interesting situation reveals nontrivial physical features as a consequence of the strong inter-particle correlations developed in collective rearrangements. We consider a minimal model for active Brownian particles with the aim of studying the modifications introduced by activity with respect to the classical (passive) Single File picture. Depending on whether their motion is dominated by translational or rotational diffusion, we find that active Brownian particles in Single File may arrange into clusters which are continuously merging and splitting ({it active clusters}) or merely reproduce passive-motion paradigms, respectively. We show that activity convey to self-propelled particles a strategic advantage for trespassing narrow channels against external biases (e.g., the gravitational field).
We study analytically the single-trajectory spectral density (STSD) of an active Brownian motion as exhibited, for example, by the dynamics of a chemically-active Janus colloid. We evaluate the standardly-defined spectral density, i.e. the STSD averaged over a statistical ensemble of trajectories in the limit of an infinitely long observation time $T$, and also go beyond the standard analysis by considering the coefficient of variation $gamma$ of the distribution of the STSD. Moreover, we analyse the finite-$T$ behaviour of the STSD and $gamma$, determine the cross-correlations between spatial components of the STSD, and address the effects of translational diffusion on the functional forms of spectral densities. The exact expressions that we obtain unveil many distinctive features of active Brownian motion compared to its passive counterpart, which allow to distinguish between these two classes based solely on the spectral content of individual trajectories.
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