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Register a new userEfficiency at the maximum power output for simple two-level heat engine
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We introduce a simple two-level heat engine to study the efficiency in the condition of the maximum power output, depending on the energy levels from which the net work is extracted. In contrast to the quasi-statically operated Carnot engine whose efficiency reaches the theoretical maximum, recent research on more realistic engines operated in finite time has revealed other classes of efficiency such as the Curzon-Ahlborn efficiency maximizing the power output. We investigate yet another side with our heat engine model, which consists of pure relaxation and net work extraction processes from the population difference caused by different transition rates. Due to the nature of our model, the time-dependent part is completely decoupled from the other terms in the generated work. We derive analytically the optimal condition for transition rates maximizing the generated power output and discuss its implication on general premise of realistic heat engines. In particular, the optimal engine efficiency of our model is different from the Curzon-Ahlborn efficiency, although they share the universal linear and quadratic coefficients at the near-equilibrium limit. We further confirm our results by taking an alternative approach in terms of the entropy production at hot and cold reservoirs.
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Efficiency at maximum power (MP) output for an engine with a passive piston without mechanical controls between two reservoirs is theoretically studied. We enclose a hard core gas partitioned by a massive piston in a temperature-controlled container and analyze the efficiency at MP under a heating and cooling protocol without controlling the pressure acting on the piston from outside. We find the following three results: (i) The efficiency at MP for a dilute gas is close to the Chambadal-Novikov-Curzon-Ahlborn (CNCA) efficiency if we can ignore the side wall friction and the loss of energy between a gas particle and the piston, while (ii) the efficiency for a moderately dense gas becomes smaller than the CNCA efficiency even when the temperature difference of reservoirs is small. (iii) Introducing the Onsager matrix for an engine with a passive piston, we verify that the tight coupling condition for the matrix of the dilute gas is satisfied, while that of the moderately dense gas is not satisfied because of the inevitable heat leak. We confirm the validity of these results using the molecular dynamics simulation and introducing an effective mean-field-like model which we call stochastic mean field model.
We study a class of cyclic Brownian heat engines in the framework of finite-time thermodynamics. For infinitely long cycle times, the engine works at the Carnot efficiency limit producing, however, zero power. For the efficiency at maximum power, we find a universal expression, different from the endoreversible Curzon-Ahlborn efficiency. Our results are illustrated with a simple one-dimensional engine working in and with a time-dependent harmonic potential.
Molecular motors transduce chemical energy obtained from hydrolizing ATP into mechanical work exerted against an external force. We calculate their efficiency at maximum power output for two simple generic models and show that the qualitative behaviour depends crucially on the position of the transition state. Specifically, we find a transition state near the initial state (sometimes characterized as a power stroke) to be most favorable with respect to both high power output and high efficiency at maximum power. In this regime, driving the motor further out of equilibrium by applying higher chemical potential differences can even, counter-intuitively, increase the efficiency.
We present a unified perspective on nonequilibrium heat engines by generalizing nonlinear irreversible thermodynamics. For tight-coupling heat engines, a generic constitutive relation of nonlinear response accurate up to the quadratic order is derived from the symmetry argument and the stall condition. By applying this generic nonlinear constitutive relation to finite-time thermodynamics, we obtain the necessary and sufficient condition for the universality of efficiency at maximum power, which states that a tight-coupling heat engine takes the universal efficiency at maximum power up to the quadratic order if and only if either the engine symmetrically interacts with two heat reservoirs or the elementary thermal energy flowing through the engine matches the characteristic energy of the engine. As a result, we solve the following paradox: On the one hand, the universal quadratic term in the efficiency at maximum power for tight-coupling heat engines proved as a consequence of symmetry [M. Esposito, K. Lindenberg, and C. Van den Broeck, Phys. Rev. Lett. 102, 130602 (2009); S. Q. Sheng and Z. C. Tu, Phys. Rev. E 89, 012129 (2014)]; On the other hand, two typical heat engines including the Curzon-Ahlborn endoreversible heat engine [F. L. Curzon and B. Ahlborn, Am. J. Phys. 43, 22 (1975)] and the Feynman ratchet [Z. C. Tu, J. Phys. A 41, 312003 (2008)] recover the universal efficiency at maximum power regardless of any symmetry.
We investigate the efficiency of systems of molecular motors operating at maximum power. We consider two models of kinesin motors on a microtubule: for both the simplified and the detailed model, we find that the many-body exclusion effect enhances the efficiency at maximum power of the many-motor system, with respect to the single motor case. Remarkably, we find that this effect occurs in a limited region of the system parameters, compatible with the biologically relevant range.
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