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Register a new userAtomic and molecular transitions induced by axions via oscillating nuclear moments
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The interaction of standard models particles with the axionic Dark Matter field may generate oscillating nuclear electric dipole moments (EDMs), oscillating nuclear Schiff moments and oscillating nuclear magnetic quadrupole moments (MQMs) with a frequency corresponding to the axions Compton frequency. Within an atom or a molecule an oscillating EDM, Schiff moment or MQM can drive transitions between atomic or molecular states. The excitation events can be detected, for example, via subsequent fluorescence or photoionization. Here we calculate the rates of such transitions. If the nucleus has octupole deformation or quadrupole deformation then the transition rate due to Schiff moment and MQM can be up to $10^{-16}$ transition per molecule per year. In addition, an MQM-induced transition may be of M2-type, which is useful for the elimination of background noise since M2-type transitions are suppressed for photons.
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According to the Schiff theorem nuclear electric dipole moment (EDM) is completely shielded in a neutral atom by electrons. This makes a static nuclear electric dipole moment (EDM) unobservable. Interaction with the axion dark matter field generates nuclear EDM $d=d_0 cos (omega t)$ oscillating with the frequency $omega= m_a c^2/hbar$ . This EDM generates atomic EDM proportional to $omega^2$. This effect is strongly enhanced in molecules since nuclei move slowly and do not produce as efficient screening of oscillating nuclear EDM as electrons do. An additional strong enhancement comes due to a small energy interval between rotational molecular levels. Finally, if the nuclear EDM oscillation frequency is in resonance with a molecular transition, there may be a significant resonance enhancement.
The molecular dipole moment ($boldsymbol{mu}$) is a central quantity in chemistry. It is essential in predicting infrared and sum-frequency generation spectra, as well as induction and long-range electrostatic interactions. Furthermore, it can be extracted directly from high-level quantum mechanical calculations, making it an ideal target for machine learning (ML). In this work, we choose to represent this quantity with a physically inspired ML model that captures two distinct physical effects: local atomic polarization is captured within the symmetry-adapted Gaussian process regression (SA-GPR) framework, which assigns a (vector) dipole moment to each atom, while movement of charge across the entire molecule is captured by assigning a partial (scalar) charge to each atom. The resulting MuML models are fitted together to reproduce molecular $boldsymbol{mu}$ computed using high-level coupled-cluster theory (CCSD) and density functional theory (DFT) on the QM7b dataset. The combined model shows excellent transferability when applied to a showcase dataset of larger and more complex molecules, approaching the accuracy of DFT at a small fraction of the computational cost. We also demonstrate that the uncertainty in the predictions can be estimated reliably using a calibrated committee model. The ultimate performance of the models depends, however, on the details of the system at hand, with the scalar model being clearly superior when describing large molecules whose dipole is almost entirely generated by charge separation. These observations point to the importance of simultaneously accounting for the local and non-local effects that contribute to $boldsymbol{mu}$; further, they define a challenging task to benchmark future models, particularly those aimed at the description of condensed phases.
The $mu$eV-mass axion is one of the most promising candidates for cold dark matter, and remains to be a well-motivated solution to the CP problem of Quantum Chromodynamics (QCD) via the Peccei-Quinn mechanism. In this paper, we propose a novel method to detect the dark-matter axions in our galaxy via the resonant emission $|{rm e}rangle to |{rm g}rangle + gamma + gamma^{prime}_{} + a$ (or absorption $a + |{rm e}rangle to |{rm g}rangle + gamma + gamma^{prime}_{}$) in an atomic system with superradiance, where $|{rm e}rangle$ and $|{rm g}rangle$ stand for the excited and ground energy levels of atoms, respectively. A similar process via $|{rm e}rangle to |{rm g}rangle + gamma + a$ (or $a + |{rm e}rangle to |{rm g}rangle + gamma$) is also put forward to probe the axion-electron coupling. For the nominal experimental setup assuming a background-free environment, most of the parameter space for typical QCD axion models can be covered with parahydrogen molecules or ytterbium atoms. However, the background in a realistic experimental setup remains to be a major issue that needs to be solved in future studies. Searching for better atomic or molecular candidates may be required for a bigger signal-to-noise ratio.
The equations of electrodynamics are altered in the presence of a classical coherent axion dark matter background field, changing the dispersion relation for electromagnetic waves. Careful measurements of the frequency stability in sensitive atomic clocks could in principle provide evidence for such a background for $f_a ge 10^7$ GeV. Turning on a background magnetic field might enhance these effects in a controllable way, and interferometric measurements might also be useful for probing the time-varying photon dispersion relation that results from a coherent cosmic axion background.
We investigate dynamics of atomic and molecular systems exposed to intense, shaped chaotic fields and a weak femtosecond laser pulse theoretically. As a prototype example, the photoionization of a hydrogen atom is considered in detail. The net photoionization undergoes an optimal enhancement when a broadband chaotic field is added to the weak laser pulse. The enhanced ionization is analyzed using time-resolved wavepacket evolution and the population dynamics of the atomic levels. We elucidate the enhancement produced by spectrally-shaped chaotic fields of two different classes, one with a tunable bandwidth and another with a narrow bandwidth centered at the first atomic transition. Motivated by the large bandwidth provided in the high harmonic generation, we also demonstrate the enhancement effect exploiting chaotic fields synthesized from discrete, phase randomized, odd-order and all-order high harmonics of the driving pulse. These findings are generic and can have applications to other atomic and simple molecular systems.
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